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化学进展 2023, Vol. 35 Issue (8): 1168-1176 DOI: 10.7536/PC221222 前一篇   后一篇

• 综述 •

手性等离子体核壳纳米结构的设计及应用

刘文亮, 王宇琦, 李晓晗, 张轩瑜, 王继乾*()   

  1. 中国石油大学(华东)重质油国家重点实验室 生物工程与技术中心 青岛 266580
  • 收稿日期:2022-12-28 修回日期:2023-05-26 出版日期:2023-08-24 发布日期:2023-07-18
  • 作者简介:

    王继乾 中国石油大学(华东)化学化工学院教授。近年来主要致力于生物分子自组装与相关表界面科学问题的基础理论与技术开发研究,包括短肽自组装机制及调控、DNA分子自组装、生物聚合物制备与应用、生物表面活性剂开发与应用等研究方向。累计在《美国化学会志》和《自然·通讯》等期刊发表100余篇学术论文,授权发明专利20余项。

  • 基金资助:
    国家自然科学基金项目(22072181); 中国石油大学(华东)研究生创新基金项目(23CX04031A); 中央高校基本科研业务费专项资金资助
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Design and Application of Chiral Plasmonic Core-Shell Nanostructures

Wenliang Liu, Yuqi Wang, Xiaohan Li, Xuanyu Zhang, Jiqian Wang()   

  1. State Key Laboratory of Heavy Oil Processing, Center for Bioengineering and Biotechnology, China University of Petroleum (East China),Qingdao 266580, China
  • Received:2022-12-28 Revised:2023-05-26 Online:2023-08-24 Published:2023-07-18
  • Contact: *e-mail: jqwang@upc.edu.cn
  • Supported by:
    National Natural Science Foundation of China(22072181); Innovation Fund Project for Graduate Student of China University of Petroleum(23CX04031A); Fundamental Research Funds for the Central Universities.

手性描述了一个物体不能与其镜像重叠的几何性质,自19世纪以来一直是化学和生物学中的一个关键概念。随着纳米技术的发展,手性等离子体纳米材料凭借其特殊的手性光学性质和良好的生物相容性已经成为科学家们的研究重点和手性功能材料开发的热点。然而,较弱的手性响应信号限制了其应用和发展。将手性等离子体纳米材料和核壳结构结合得到的手性等离子体核壳纳米结构是一种放大手性响应信号的有效策略。核壳纳米结构整合了内外两种材料的性质,互相补充各自的不足,能够进一步改善材料的物理化学性质,提升材料在各个领域的性能。本文依据手性分子的空间分布对手性等离子体核壳纳米结构的设计策略进行了总结,并综述了其在超灵敏传感和手性催化领域的应用,分析了目前尚存在的问题和可能的解决方式,对其未来的发展作了进一步展望。

关键词： 手性等离子体纳米材料, 核壳结构, 手性催化, 超灵敏传感

Chirality describes the geometrical feature of an object that cannot overlap with its mirror image and has been a crucial concept in chemistry and biology since the 19th century. With the development of nanotechnology, chiral plasmonic nanomaterials are becoming the research focuses for scientists to develop chiral functional materials due to the special chiral optical properties and good biocompatibility. However, the relatively weak chiral signals limit their applications. Chiral plasmonic core-shell nanostructures combine the chiral plasmonic properties and core-shell structures, which is an effective strategy to amplify chiral signals. In addition, the core-shell nanostructure integrates the properties of both internal and external materials to complement each other, which can further improve the physicochemical properties and enhance the performance in various fields. This paper summarizes the design strategies of chiral plasmonic core-shell nanostructures based on the spatial distribution of chiral molecules, and reviews their applications in the fields of ultrasensitive sensing and chiral catalysis. We analyze the existing problems and their possible solutions, and make an outlook on their future development.

Contents

1 Introduction

2 Design strategies for chiral plasmonic core-shell nanostructures

2.1 Chiral molecules distributed on the shell

2.2 Chiral molecules distributed on the core

2.3 Chiral molecules distributed in the core-shell gap

3 Application of chiral plasmonic core-shell nanostructures

3.1 Ultra-sensitive sensing

3.2 Chiral catalysis

4 Conclusion and outlook

Key words: chiral plasmonic nanostructures, core-shell structure, chiral catalysis, ultra-sensitive sensing
()
图1 (a)Au@DNA修饰的Ag的示意图;(b)Au@DNA修饰的Ag的制备示意图;(c)Au@DNA修饰的Ag的TEM图;(d)DNA以及Au@DNA修饰的Ag的紫外-可见吸收光谱;(e)DNA、Au@Ag、Au@DNA修饰的Ag的圆二色光谱[38]
Fig.1 (a)Schematic diagram of Au@DNA modified Ag. (b)Schematic diagram of the preparation of Au@DNA modified Ag. (c)TEM image of Au@DNA modified Ag. (d)UV-vis absorption spectra of DNA and Au@DNA modified Ag. (e)CD spectra of DNA, Au@Ag, and Au@DNA modified Ag[38]
图2 (a)DNA桥联的Au@AgAu的示意图;(b)DNA桥联的Au@AgAu的制备示意图;(c)DNA桥联的Au@AgAu的TEM图;(d)DNA桥联的Au@AgAu的圆二色光谱[39]
Fig.2 (a)Schematic diagram of DNA bridged Au@AgAu. (b)Schematic diagram of the preparation of DNA bridged Au@AgAu. (c)TEM images of DNA bridged Au@AgAu. (d)CD spectra of DNA bridged Au@AgAu[39]
图3 (a)Au@半胱氨酸修饰的Ag的示意图;(b)Au@半胱氨酸修饰的Ag的TEM图;(c)Au@半胱氨酸修饰的Ag的圆二色光谱;(d~f)Au@半胱氨酸修饰的Ag的手性响应信号放大策略[43]
Fig.3 (a)Schematic diagram of Au@cysteine modified Ag. (b)TEM images of Au@cysteine modified Ag(c)CD spectra of Au@cysteine modified Ag. (d~f)Chiral response signal amplification strategy for Au@cysteine modified Ag[43]
图4 (a)手性分子修饰的Au@Ag的示意图;(b)DNA修饰的Au@Ag的制备示意图;(c)DNA修饰的Au@Ag的TEM图[44] ;(d)半胱氨酸修饰的Au@Ag的制备示意图;(e)半胱氨酸修饰的Au@Ag的TEM图[45]
Fig.4 (a)Schematic diagram of chiral molecules modified Au@Ag. (b)Schematic diagram of the preparation of DNA modified Au@Ag.(c)TEM images of DNA modified Au@Ag[44]. (d)Schematic diagram of the preparation of cysteine modified Au@Ag.(e)TEM images of cysteine modified Au@Ag[45]
图5 (a)半胱氨酸修饰的Au@Ag的示意图;(b)半胱氨酸修饰的Au@Ag的制备示意图;(c)Au@半胱氨酸修饰的Ag的圆二色光谱;(d~f)Au@半胱氨酸修饰的Ag的手性响应信号放大策略[46]
Fig.5 (a)Schematic diagram of cysteine modified Au@Ag. (b)TEM image of cysteine modified Au@Ag.(c)CD spectra of cysteine modified Au@Ag. (d~f)Chiral response signal amplification strategy for cysteine modified Au@Ag[46]
图6 (a)青霉胺修饰的Au@AgAu的示意图;(b)青霉胺修饰的Au@AgAu的TEM图;(c)青霉胺修饰的Au@AgAu的制备示意图[47]
Fig.6 (a)Schematic diagram of penicillamine modified Au@AgAu. (b)TEM images of penicillamine modified Au@AgAu.(c)Schematic diagram of the preparation of penicillamine modified Au@AgAu[47]
表1 手性等离子体核壳纳米结构中手性分子的空间分布及其不对称因子
Table 1 Spatial distribution of chiral molecules in chiral plasmonic core-shell nanostructures and their g factors
Spatial distribution of chiral molecules Materials g-factors ref
Chiral molecules
distributed on the
shell		 Au@DNA modified Ag 4.4×10-3 38
DNA bridged Au@AgAu 1.21×10-2 39
Au@cysteine modified Ag 1.45×10-3 43
Chiral molecules
distributed on the
core		 DNA modified Au@Ag 1.93×10-2 44
cysteine modified Au@Ag 1×10-2 45
cysteine modified Au@Ag 1.3×10-3 46
Chiral molecules
distributed in the
core-shell gap		 penicillamine modified Au@AgAu 2.1×10-2 47
图7 (a)DNA桥联的Au@AgAu应用于仄普托摩尔级别DNA检测传感[39] ;(b)青霉胺修饰的Au@AgAu应用于活体细胞中Zn2+检测[47]
Fig.7 (a)DNA bridged Au@AgAu for zeptomolar DNA detection and sensing[39] ;(b)penicillamine-modified Au@AgAu for Zn2+ detection and sensing in living cells[47]
图8 半胱氨酸修饰的Au@Ag应用于不对称催化[45]
Fig.8 Cysteine modified Au@Ag for asymmetric catalysis[45]
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