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化学进展 2014, Vol. 26 Issue (0203): 424-435 DOI: 10.7536/PC130832 前一篇   后一篇

• 综述与评论 •

核壳结构金属-有机骨架的研究

宋肖锴*1, 周雅静1, 李亮*2   

  1. 1. 常州出入境检验检疫局 常州 213003;
    2. 上海应用技术学院化学与环境工程学院 上海 201418
  • 收稿日期:2013-08-01 修回日期:2013-10-01 出版日期:2014-02-15 发布日期:2013-12-18
  • 通讯作者: 宋肖锴，e-mail：xksong1982@hotmail.com；李亮，e-mail：lilianglcx@sit.edu.cn E-mail:xksong1982@hotmail.com；lilianglcx@sit.edu.cn
  • 基金资助:

    上海高校青年教师培养计划项目（No. ZZyyy12006）和上海应用技术学院引进人才基金项目（No.YJ-2012-10）资助

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Synthesis of Core-Shell Metal-Organic Frameworks

Song Xiaokai*1, Zhou Yajing1, Li Liang*2   

  1. 1. Changzhou Entry-Exit Inspection and Quarantine Bureau, Changzhou 213003, China;
    2. School of Chemical and Environmental Engineering, Shanghai Institute of Technology, Shanghai 201418, China
  • Received:2013-08-01 Revised:2013-10-01 Online:2014-02-15 Published:2013-12-18
  • Supported by:

    This work was supported by the Funding Scheme for Training Young Teachers in Shanghai Colleges (No.ZZyyy12006) and the Talented Faculty Funds of Shanghai Institute of Technology (No.YJ-2012-10)

核壳结构（core-shell）金属-有机骨架（metal-organic frameworks，MOFs）是多功能MOFs复合材料中最为典型的一类构型，是由MOFs材料和另一种材料（如MOFs、碳材料、无机化合物、有机聚合物等）组装形成的核壳结构，其中MOFs既可作核，亦可作壳。因结合了核层和壳层两种材料，核壳结构MOFs展现出了优于核层或者壳层的独特性能，例如结构稳定、选择性分离、气体吸附等，为MOFs材料实现工业化应用带来了新的潜力。本文综述了近年来核壳结构MOFs材料的研究进展，介绍了各类构型核壳结构MOFs材料（例如MOF@MOF、MOF@carbon、metal oxide@MOF、polymer@MOF等）的合成方法及应用研究，并对其今后的发展进行了展望。

关键词： 金属-有机骨架, 核壳结构, 复合材料, 结构稳定性, 选择性分离

Core-shell metal-organic frameworks (MOFs) composed of MOFs as core (or shell) and another material, such as MOFs, carbon, inorganic compounds and organic polymers, as shell (or core), are a typical class of multifunctional MOFs composites. Because of the combination of the properties of core and shell materials, core-shell MOFs have better performances, such as increasing framework stability, selective separation and gas sorption, than the core or shell materials. Therefore, core-shell MOFs have high potentials for industrial applications. In this paper, the research progress of core-shell MOFs in recent years is reviewed. Synthesis methods and applications of variously structural core-shell MOFs, such as MOF@MOF, MOF@carbon, metal oxide@MOF, and polymer@MOF are introduced. Besides, the future development of core-shell MOFs is prospected.

Contents
1 Introduction
2 Synthesis methods and applications of variously structural core-shell MOFs
2.1 MOF@MOF
2.2 Core-shell structures of MOFs with carbon
2.3 Core-shell structures of MOFs with inorganic compounds
2.4 Core-shell structures of MOFs with organic polymers
3 Conclusion and outlook

Key words: metal-organic frameworks (MOFs), core-shell, composites, framework stability, selective separation

中图分类号: 

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摘要

核壳结构金属-有机骨架的研究