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化学进展 2015, Vol. 27 Issue (8): 1057-1064 DOI: 10.7536/PC150140 前一篇   后一篇

• 综述与评论 •

种子生长法制备Au@Ag核壳纳米粒子

张东杰1, 张丛筠1, 卢亚1, 郝耀武*2, 刘亚青*1   

  1. 1. 中北大学材料科学与工程学院 太原 030051;
    2. 德克萨斯大学阿灵顿分校材料科学与工程系 阿灵顿 76019
  • 收稿日期:2015-01-01 修回日期:2015-04-01 出版日期:2015-08-15 发布日期:2015-04-21
  • 通讯作者: 郝耀武, 刘亚青 E-mail:lyq@nuc.edu.cn;yhao@uta.edu
  • 基金资助:
    山西省国际科技合作项目(No. 2014081006-2)资助
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Preparation of Au@Ag Core-Shell Nanoparticles through Seed-Mediated Growth Method

Zhang Dongjie1, Zhang Congyun1, Lu Ya1, Hao Yaowu*2, Liu Yaqing*1   

  1. 1. School of Materials Science and Engineering, North University of China, Taiyuan 030051, China;
    2. Department of Materials Science and Engineering, The University of Texas at Arlington, Arlington 76019, USA
  • Received:2015-01-01 Revised:2015-04-01 Online:2015-08-15 Published:2015-04-21
  • Supported by:
    The work was supported by the International Scientific and Technological Cooperation Projects in Shanxi Province (No. 2014081006?2).
Au@Ag核壳纳米粒子由于具有优异的局部等离子共振性质 (LSPR),近年来引起人们极大的关注,目前,在成像、催化、信息存储、生化传感等领域已经得到了广泛的应用。在制备Au@Ag核壳纳米粒子的方法中,种子生长法的应用最为广泛,因为它可以实现对Ag壳尺寸及形貌的有效控制。本文综述了影响Au@Ag核壳纳米粒子核壳结构尺寸、形貌、Ag壳厚度以及覆盖均匀程度的一些主要因素,包括Au种子的形貌和浓度、AgNO3浓度、封端剂、还原剂以及其他一些影响因素。研究发现,Au@Ag核壳纳米粒子在表面增强拉曼光谱 (SERS) 方面具有广泛的应用前景。
关键词： 核壳结构, 种子生长法, 纳米粒子
Au@Ag core-shell nanoparticles have received considerable attention for recent years because of the localized surface plasmon resonance (LSPR). At present, Au@Ag core-shell nanoparticles have been widely used in applications related to photonics, catalysis, information storage, chemical/biological sensing. Due to the well controlled size and morphology of Ag shell, seed-mediated growth method has become the most practical approach to synthesize Au@Ag core-shell nanoparticles. This review provides a short summary of some main factors, such as the morphology and concentration of Au seeds, concentration of AgNO3, capping agents, reductants and some other factors, which affect the size, morphology, the thickness and uniform coating of Ag shell during the seed-mediated growth of Au@Ag core-shell nanoparticles. Recent studies have shown that Au@Ag core-shell nanoparticles would benefit the further development of the surface-enhanced Raman scattering (SERS).

Contents
1 Introduction
2 Classification of Au@Ag core-shell nanoparticles
3 Preparation of Au@Ag core-shell nanoparticles by seed-mediated growth method
3.1 Precursors
3.2 Capping agents
3.3 Reductants
3.4 Some other factors
4 Conclusion

Key words: core-shell structure, seed-mediated growth method, nanoparticle

中图分类号: 

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[1] Chaudhuri R G, Paria S. Chem. Rev., 2012, 112: 2373.
[2] Wang A, Peng Q, Li Y D. Chem. Mater., 2011, 23 (13): 3217.
[3] Li Q, Jiang R, Ming T, Fang C H, Wang J F. Nanoscale, 2012, 4: 7070.
[4] Li J, Zheng Y, Zeng J, Xia Y N. Chemistry-A European Journal, 2012, 18(26): 8150.
[5] Zhang K, Xiang Y, Wu X, Feng L L, He W W, Liu J B, Zhou W Y, Xie S S. Langmuir, 2009, 25: 1162.
[6] Yancey D F, Carino E V, Crooks R M. J. Am. Chem. Soc., 2010, 132: 10988.
[7] Corthey G, Giovanetti L J, Ramallo-López J M, Salvarezza R C. ACS Nano, 2010, 4(6): 3413.
[8] Zhang W Q, Goh H Y, Firdoz S, Lu X M. Chem. Eur. J., 2013, 19: 12732.
[9] Hsu C, Huang C W, Hao Y W, Liu F Q. Electrochem. Commun., 2012, 23: 133.
[10] Hsu C, Huang C W, Hao Y W, Liu F Q. Nanoscale Res. Lett., 2013, 8: 113.
[11] Sun L, Li Q H, Tang W J, Di J W, Wu Y. Microchim. Acta, 2014, 181: 1991.
[12] Tsao Y C, Rej S, Chiu C Y, Huang M H. J. Am. Chem. Soc., 2014, 136 (1): 396.
[13] Hao J R, Xiong B, Cheng X D, He Y, Yeung E S. Anal. Chem., 2014, 86: 4663.
[14] Tsuji M, Maeda Y, Hikino S, Kumagae H, Matsunaga M, Tang X L, Matsuo R, Ogino M, Jiang P. Cryst. Growth. Des., 2009, 9: 4700.
[15] Wu Y, Jiang P, Jiang M, Wang W T, Guo C F, Xie S S, Wang Z L. Nanotechnology, 2009, 20: 305602.
[16] Cho E C, Camargo P H C, Xia Y N. Adv. Mater., 2010, 22: 744.
[17] Snchez-Iglesias A, Carbó-Argibay E, Glaria A, Rodríguez-Gonzlez B, Pérez-Juste J, Pastoriza-Santo I, Liz-Marzn L M. Chem. Eur. J., 2010, 16: 5558.
[18] Wu H L, Chen C H, Huang M H. Chem. Mater., 2009, 21 (1): 110.
[19] Li N, Zhao P X, Astruc D. Angew. Chem. Int. Ed., 2014, 53: 1756.
[20] Ma Y Y, Li W Y, Cho E C, Li Z Y, Yu T, Zeng J, Xie Z X, Xia Y N. ACS Nano, 2010, 4(11): 6725.
[21] Gong J X, Zhou F, Li Z Y, Tang Z Y. Langmuir, 2012, 28: 8959.
[22] Hong S, Choi Y, Park S. Chem. Mater., 2011, 23: 5375.
[23] Zhu J, Zhang F, Li J J, Zhao J W. Gold Bull., 2014, 47: 47.
[24] Khlebtsov B N, Khanadeev V A, Tsvetkov M Y, Bagratashvili V N, Khlebtsov N G. J. Phys. Chem. C, 2013, 117: 23162.
[25] Zheng Y Q, Zhong X L, Li Z Y, Xia Y N. Part. Part. Syst. Char., 2014, 31: 266.
[26] Wang Y C, Black K L, Luehmann H, Li W Y, Zhang Y, Cai X, Wan D H, Liu S Y, Li M, Kim P, Li Z Y, Wang L V, Liu Y J, Xia Y N. ACS Nano, 2013, 7 (3): 2068.
[27] Ma Y Y, Zeng J, Li W Y, McKiernan M, Xie Z X, Xia Y N. Adv. Mater., 2010, 22: 1930.
[28] Chung P J, Lyu L M, Huang M H. Chem. Eur. J., 2011, 17: 9746.
[29] Wu H L, Kuo C H, Huang M H. Langmuir, 2010, 26(14): 12307.
[30] Yu K, You G J, Polavarapu L, Xu Q H. J. Phys. Chem. C, 2011, 115: 14000.
[31] Tsuru Y, Nakashima N, Niidome Y. Optics Commun., 2012, 285: 3419.
[32] Tsuji M, Nishio M, Jiang P, Miyamae N, Lima S, Matsumoto K, Ueyama D, Tang X L. Colloids and Surfaces A: Physicochemical Engineering Aspects, 2008, 317: 247.
[33] Tsuji M, Ogino M, Matsunaga M, Miyamae N, Matsuo R, Nishio M, Alam M J. Crystal Growth & Design, 2010, 10: 4085.
[34] Park G, Seo D, Jung J, Ryu S, Song H. J. Phys. Chem. C, 2011, 115: 9417.
[35] Samal A K, Polavarapu L, Rodal C S, Liz L M, Pérez-Juste J, Pastoriza I. Langmuir, 2013, 29: 15076.
[36] Shankar C, Dao A T N, Singh P, Higashimine K, Mott D M, Maenosono S. Nanotechnology, 2012, 23: 245704.
[37] Khlebtsov B, Khanadeev V, Pylaev T, Khlebtsov N. J. Phys. Chem. C, 2011, 115: 6317.
[38] Ko F H, Tai M R, Liu F K, Chang Y C. Sensors and Actuators B, 2015, 211: 283.
[39] Tsuji M, Nakamura N, Ogino M, Ikedo K, Matsunaga M. CrystEngComm, 2012, 14: 7639.
[40] Lu L, Burkey G, Halaciuga I, Goia D V. Journal of Colloid and Interface Science, 2013, 392: 90.
[41] Okuno Y, Nishioka K, Kiya A, Nakashima N, Ishibashi A, Niidome Y. Nanoscale, 2010, 2: 1489.
[42] Banerjee M, Sharma S, Chattopadhyay A, Ghosh S S. Nanoscale, 2011, 3: 5120.
[43] Huo D, He J, Li H, Yu H P, Shi T T, Feng Y H, Zhou Z Y, Hu Y. Colloids and Surfaces B: Biointerfaces, 2014, 117: 29.
[44] Wang H, Liu J, Wu X, Tong Z H, Deng Z X. Nanotechnology, 2013, 24: 205102.
[45] Yang X, Wang Y, Liu Y W, Jiang X. Electrochim. Acta, 2013, 108: 39.
[46] Banerjee M, Dey B, Talukdar J, Kalita M C. Energy, 2014, 69: 695.
[47] Baek S, Park G, Noh J, Cho C, Lee C H, Seo M K, Song H, Lee J Y. ACS Nano, 2014, 8: 3302.
[48] Guo P Z, Sikdar D, Huang X Q, Si K J, Xiong X, Gong S, Yap L W, Premaratne M, Cheng W L. Nanoscale, 2015, 7: 2862.
[49] Contreras C R, Dawson C, Formanek P, Fischer D, Simon F, Janke A, Uhlmann P, Stamm M. Chem. Mater., 2013, 25: 158.
[50] Yang Y, Liu J Y, Fu Z W, Qin D. J. Am. Chem. Soc., 2014, 136: 8153.
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