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化学进展 2015, Vol. 27 Issue (7): 831-840 DOI: 10.7536/PC150137 前一篇   后一篇

• 综述与评论 •

表面引发原子转移自由基聚合法合成无机/有机核壳复合纳米粒子

陈思远, 董旭, 查刘生*   

  1. 东华大学纤维材料改性国家重点实验室 上海 201620
  • 收稿日期:2015-01-01 修回日期:2015-03-01 出版日期:2015-07-15 发布日期:2015-06-15
  • 通讯作者: 查刘生 E-mail:lszha@dhu.edu.cn
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Inorganic/Organic Core-Shell Composite Nanoparticles by Surface-Initiated Atom Transfer Radical Polymerization

Chen Siyuan, Dong Xu, Zha Liusheng*   

  1. State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, Donghua University, Shanghai 201620, China
  • Received:2015-01-01 Revised:2015-03-01 Online:2015-07-15 Published:2015-06-15
原子转移自由基聚合(ATRP)是目前为止最具工业化应用前景的活性/可控自由基聚合方法之一,其最大特点是可以得到分子量分布窄、链结构规整的聚合物,而且可聚合的单体种类多,反应条件温和并易控制。表面引发ATRP(SI-ATRP)特别适合于无机材料表面接枝聚合物或无机/有机复合材料的制备,近年来引起了国内外研究者的高度关注。本文首先对SI-ATRP的反应过程与特点做了阐述,然后重点述评了用SI-ATRP法合成以非金属氧化物纳米粒子、金属氧化物纳米粒子、金属纳米粒子或其他无机纳米粒子为核的无机/有机复合纳米粒子的研究进展,最后对未来用SI-ATRP法合成无机/有机复合纳米粒子的发展方向和研究前景进行展望。
关键词： 表面引发原子转移自由基聚合, 可控自由基聚合, 无机/有机复合纳米粒子, 核壳结构
Atom transfer radical polymerization (ATRP) is by far one of the most promising living /controlled radical polymerization methods in industrial application. It is able to get the polymers with narrow molecular weight distribution and regular chain structure. Furthermore, many kinds of monomers can be polymerized by ATRP, and its reaction condition is mild and easy to control. Surface-initiated atom transfer radical polymerization (SI-ATRP) is a good method for grafting the polymers with regular structure on the surfaces of inorganic materials or synthesizing inorganic/organic composite materials. In recent years, SI-ATRP technique has attracted much attention from domestic and abroad researchers. In this paper, the reaction process and characteristics of SI-ATRP are elaborated, and then the progress in preparation of inorganic/organic core-shell structured composite nanoparticles based on non-metal oxide nanoparticles, metal oxide nanoparticles, metal nanoparticles, and other inorganic nanoparticle as core by SI-ATRP is highly reviewed. Finally, the outlook on future development of SI-ATRP for synthesizing inorganic/organic composite nanoparticles is presented.

Contents
1 Introduction
2 Reaction process and characteristics of SI-ATRP
3 Grafting polymer on different nanoparticles by SI-ATRP
3.1 Inorganic/organic core-shell structured composite nanoparticles based on non-metal oxide nanoparticle as core
3.2 Inorganic/organic core-shell structured composite nanoparticles based on metal oxide nanoparticle as core
3.3 Inorganic/organic core-shell structured composite nanoparticles based on metal nanoparticle as core
3.4 Inorganic/organic core-shell structured composite nanoparticles based on other inorganic nanoparticle as core
4 Conclusion and outlook

Key words: surface initiated atom transfer radical polymerization, controlled radical polymerization, inorganic/organic composite nanoparticles, core-shell structure

中图分类号: 

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