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化学进展 2013, Vol. 25 Issue (10): 1681-1690 DOI: 10.7536/PC121251 前一篇   后一篇

• 综述与评论 •

核壳结构纳米材料的创制及在催化化学中的应用

李雷1,2, 李彦兴1,3, 姚瑶1, 姚良宏1,3, 季伟捷1, 区泽棠3   

  1. 1. 南京大学化学化工学院 介观化学教育部重点实验室 南京210093;
    2. 吴江出入境检验检疫局 吴江 215200;
    3. 香港浸会大学化学系 香港九龙塘
  • 收稿日期:2012-12-01 修回日期:2013-04-01 出版日期:2013-11-12 发布日期:2013-07-18
  • 通讯作者: 季伟捷, 区泽棠 E-mail:jiwj@nju.edu.cn; pctau@hkbu.edu.hk
  • 基金资助:

    国家自然科学基金项目(No.21173118)、 江苏省自然科学基金项目(No.BK2011439)、 教育部博士点基金项目(No.20110091110023)和 RGC-HKSAR(RGC 200107)资助

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导出 被引次数 ( 12 | 4 )

Progress and Prospective in Fabrication and Application of Core-Shell Structured Nanomaterials in Catalytic Chemistry

Li Lei1,2, Li Yanxing1,3, Yao Yao1, Yao Lianghong1,3, Ji Weijie1, Au Chak-Tong3   

  1. 1. Key Laboratory of Mesoscopic Chemistry of MOE, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, China;
    2. Wujiang Inspection and Quarantine Bureau of Entry and Exit, Wujiang 215200, China;
    3. Department of Chemistry, Hong Kong Baptist University, Kowloon Tong, Hong Kong
  • Received:2012-12-01 Revised:2013-04-01 Online:2013-11-12 Published:2013-07-18

核壳结构纳米材料因其独特的结构及其多功能性,引起人们的广泛关注,具有广阔的应用前景。本文综述了近年来核壳结构纳米材料的创制,包括金属@金属,金属@氧化物,金属@碳材料,金属@高聚物,金属@分子筛等及其在不同催化过程中的催化行为,强调了特定的组装结构和表面电子性质对催化性能及稳定性的影响。依据具体实例对具有yolk/shell型核壳结构纳米反应器在催化反应中的作用与功能进行了评述。本文最后对核壳结构纳米材料在可控合成以及不同催化过程中的可能应用进行了展望与总结。

关键词： 核壳结构, 纳米材料, 催化化学

Owning to their unique structures and multi-functionalities, the core-shell structured nanomaterials are receiving great attention in recent years, and being widely used in various catalytic processes. The purpose of this review is to highlight the recent achievements in fabrication and application of core-shell nanostructures (i.e., metal core@metal shell, metal core@oxide shell, metal core@carbon shell, metal core@polymer, and metal core@zeolite shell) in catalytic chemistry. The influences of assembled structures and resulting electronic properties on catalytic performance as well as catalyst durability are discussed. In view of the new research findings, the concept of nanoreactor with the yolk/shell structure and its role in catalytic reactions are outlined. At the end of the article, a summary and outlook of these novel materials with respect to controlled synthesis and potential applications are provided.

Contents
1 Introduction
2 Progress in fabrication and application of core-shell structured nanomaterials in catalysis
2.1 Metal core@metal shell nanomaterials
2.2 Metal core@oxide shell nanomaterials
2.3 Metal core@carbon shell nanomaterials
2.4 Metal core@polymer shell nanomaterials
2.5 Metal core@zeolite shell nanomaterials
2.6 Yolk/shell structure nanomaterials

Key words: core-shell structure, nanomaterials, catalytic chemistry

中图分类号: 

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[1] Bell A T. Science, 2003, 299: 1688—1691
[2] 汪洋(Wang Y), 颜志鹏(Yan Z P), 陈丰秋(Chen F Q), 詹晓力(Zhan X L). 化学进展(Progress in Chemistry), 2008, 20: 1263—1269
[3] Reiss P, Protiere M, Li L. Small, 2009, 5: 154—168
[4] Guerrero-Martínez A, Pérez-Juste J, Liz-Marzán L. Adv. Mater., 2010, 22: 1182—1195
[5] Burns A, Ow H, Wiesner U. Chem. Soc. Rev., 2006, 35: 1028—1042
[6] Chi F, Guo Y N, Liu J, Liu Y, Huo Q. J. Phys. Chem. C, 2010, 114: 2519—2523
[7] Jun Y W, Choi J S, Cheon J. Chem. Commun., 2007, 12: 1203—1214
[8] Zhou S, Varughese B, Eichhorn B, Jackson G, McIlwrath K. Angew. Chem. Int. Ed., 2005, 44: 4539—4543
[9] Alayoglu S, Eichhorn B. J. Am. Chem. Soc., 2008, 130: 17479—17486
[10] Alayoglu S, Nilekar A, Mavrikakis M, Eichhorn. B. Nat. Mater., 2008, 7: 333—338
[11] Bagot P A J, Marquis E A, Smith G D W, Tsang S C E. Nat. Nanotechnol., 2011, 6: 302—307
[12] Zeng J, Yang J, Lee J, Zhou W. J. Phys. Chem. B, 2006, 110: 24606—24611
[13] Huang R, Wen Y H, Zhu Z Z, Sun S G. J. Phys. Chem. C, 2012, 15: 8664—8671
[14] Zhang X, Yan J, Han S, Shioyama H, Xu Q. J. Am. Chem. Soc., 2009, 131: 2778—2779
[15] Chen Y, Yang F, Dai Y, Wang W, Chen S. J. Phys. Chem. C, 2008, 112: 1645—1649
[16] Jun C, Park Y, Yeon Y, Choi J, Lee W, Ko S, Cheon J. Chem. Commun., 2006, 1619—1621
[17] Pachón L, Thathagar M, Hartl F, Rothenberg G. Phys. Chem. Chem. Phys., 2006, 8: 151—157
[18] Massard R, Uzio D, Thomazeau C, Pichon C, Rousset J, Bertolini J. J. Catal., 2007, 245 : 133—143
[19] Sárkány A, Geszti O, Sáfrán G. Appl. Catal. A, 2008, 350: 157—163
[20] Marx S, Baiker A. J. Phys. Chem. C, 2009, 113: 6191—6201
[21] Zhang W, Li L, Du Y, Wang X, Yang P. Catal. Lett., 2009, 127: 429—436
[22] Joo S H, Park J Y, Tsung C K, Yamada Y, Yang P D, Somorjai G A. Nat. Mater., 2009, 8: 126—131
[23] Yu K M K, Yeung C M Y, Thompsett D, Tsang S C. J. Phys. Chem. B, 2003, 107: 4515—4526
[24] Park J, Forman A, Tang W, Cheng J, Hu Y, Lin H, McFarland E. Small, 2008, 4: 1694—1697
[25] Forman A J, Park J N, Tang W, Hu Y S, Stucky G D, McFarland E W. ChemCatChem., 2010, 2: 1318—1324
[26] Takenaka S, Orita Y, Umebayashi H, Matsune H, Kishida M. Appl. Catal. A, 2008, 351: 189—194
[27] Takenaka S, Umebayashi H, Tanabe E, Matsune H, Kishida M. J. Catal., 2007, 245: 392—400
[28] Yeung C M Y, Tsang S C, Catal. Lett., 2009, 128: 349—355
[29] Yeung C M Y, Tsang S C, J. Phys. Chem. C, 2009, 113: 6074—6087
[30] Cargnello M, Wieder N L, Montini T, Gorte R J, Fornasiero P. J. Am. Chem. Soc., 2010, 132: 1402—1409
[31] Zhang J, Li L, Huang X, Li G. J. Mater. Chem., 2012, 22: 10480—10487
[32] Zhang N, Fu X, Xu Y J, J. Mater. Chem., 2011, 21: 8152—8158
[33] Lu J, Fu B, Kung M C, Xiao G, Elam J W, Kung H H, Stair P C. Science, 2012, 335: 1205—1208
[34] Montini T, Condo A, Hickey N, Lovey F, De Rogatis L, Fornasiero P, Graziani M. Appl. Catal. B: Environ., 2007, 73: 84—97
[35] D'addato S, Grillo V, Altieri S, Frabboni S, Rossi F, Valeri S. J. Phys. Chem. C, 2011, 115: 14044—14049
[36] Bian Z, Zhu J, Cao F, Lu Y, Li H. Chem. Commun., 2009, 3789—3791
[37] Nair A S, Pradeep T, MacLaren I, J. Mater. Chem., 2004, 14: 857—862
[38] Oldfield G, Ung T, Mulvaney P. Adv. Mater., 2000, 12: 1519—1522
[39] Deng Y, Qi D, Deng C, Zhang X, Zhao D. J. Am. Chem. Soc., 2008, 130: 28—29
[40] Yang H, Chong Y, Li X, Ge H, Fan W, Wang J. J. Mater. Chem., 2012, 22: 9069—9076
[41] Barmatova M, Ivanchikova I, Kholdeeva O, Shmakov A, Zaikovskii V, Mel'gunov M. Catal. Lett., 2009, 127: 75—82
[42] Ng Y H, Ikeda S, Harada T, Higashida S, Sakata T, Mori H, Matsumura M. Adv. Mater., 2007, 19: 597—601
[43] Ikeda S, Ishino S, Harada T, Okamoto N, Sakata T, Mori H, Kuwabata S, Torimoto T, Matsumura M. Angew. Chem. Int. Ed., 2006, 45: 7063—7066
[44] Ng Y H, Ikeda S, Morita Y, Harada T, Ikeue K, Matsumura M. J. Phys. Chem. C, 2009, 113: 12799—12805
[45] Ng Y H, Ikeda S, Harada T, Sakata T, Mori H, Takaoka A, Matsumura M. Langmuir, 2008, 24: 6307—6312
[46] Harada T, Ikeda S, Ng Y H, Sakata T, Mori H, Matsumura M. Adv. Funct. Mater., 2008, 18: 2190—2196
[47] Song C, Du J, Zhao J, Feng S, Du G, Zhu Z. Chem. Mater., 2009, 21: 1524—1530
[48] Yu G, Sun B, Pei Y, Xie S, Yan S, Qiao M, Fan K, Zhang X, Zong B. J. Am. Chem. Soc., 2010, 132: 935—937
[49] 唐新德 (Tang X D), 张其震 (Zhang Q Z). 化学进展 (Progress in Chemistry), 2003, 15: 129—134
[50] Du Y, Zhang W, Wang X, Yang P. Catal. Lett., 2006, 107: 177—183
[51] Yang P, Zhang W, Du Y, Wang X. J. Mol. Catal. A: Chem., 2006, 260: 4—10
[52] Sun L, Ca D, Cox J. J. Solid. State. Electrochem., 2005, 9: 816—822
[53] Huang W, Kuhn J N, Tsung C K, Zhang Y, Habas S E, Yang P, Somorjai G A. Nano. Lett., 2008, 8: 2027—2034
[54] Toshima N. Macromol. Symp., 2008, 270: 27—39
[55] Xuan S, Wang Y, Yu J, Leung K. Langmuir, 2009, 25: 11835—11843
[56] Vande C R, Alfers A, Meeldijk J, Martinez-Viviente E, Pregosin P, Gebbink R, van Koten G. J. Am. Chem. Soc., 2006, 128: 12700—12713
[57] Graeser M, Pippel E, Greiner A, Wendorff J. Macromolecules, 2007, 40: 6032—6039
[58] Lu Y, Mei Y, Drechsler M, Ballauff M. Angew. Chem. Int. Ed., 2006, 45: 813—816
[59] Mei Y, Lu Y, Polzer F, Ballauff M, Drechsler M. Chem. Mater., 2007, 19: 1062—1069
[60] Lu Y, Mei Y, Ballauff M, Drechsler M. J. Phys. Chem. B, 2006, 110: 3930—3937
[61] Lu Y, Proch S, Schrinner M, Drechsler M, Kempe R, Ballauff M. J. Mater. Chem., 2009, 19: 3955—3961
[62] Zhang J, Zhang W, Wang Y, Zhang M. Adv. Synth. Catal., 2008, 350: 2065—2076
[63] Wen F, Zhang W, Wei G, Wang Y, Zhang J, Zhang M, Shi L. Chem. Mater., 2008, 20: 2144—2150
[64] Zheng P, Zhang W. J. Catal., 2007, 250: 324—330
[65] Wei G, Zhang W, Wen F, Wang Y, Zhang M. J. Phys. Chem. C, 2008, 112: 10827—10832
[66] Miyamoto M, Kamei T, Nishiyama N, Egashira Y, Ueyama K. Adv. Mater., 2005, 17: 1985—1988
[67] Nishiyama N, Miyamoto M, Egashira Y, Ueyama K. Chem. Commun., 2001, 1746—1747
[68] Nishiyama N, Ichioka K, Park D, Egashira Y, Ueyama K, Gora L, Zhu W, Kapteijn F, Moulijns J. Ind. Eng. Chem. Res., 2004, 43: 1211—1215
[69] Bao J, He J, Zhang Y, Yoneyama Y, Tsubaki N. Angew. Chem. Int. Ed., 2008, 47: 353—356
[70] He J, Liu Z, Yoneyama Y, Nishiyama N, Tsubaki N. Chem-Eur. J., 2006, 12: 8296—8304
[71] He J, Yoneyama Y, Xu B, Nishiyama N, Tsubaki N. Langmuir, 2005, 21: 1699—1702
[72] Li X, He J, Meng M, Yoneyama Y, Tsubaki N. J. Catal., 2009, 265: 26—34
[73] Yang G, He J, Yoneyama Y, Tan Y, Han Y, Tsubaki N. Appl. Catal. A, 2007, 329: 99—105
[74] Yang G, He J, Yoneyama Y, Tan Y, Han Y, Vitidsant T, Tsubaki N. Energy. Fuels, 2008, 22: 1463—1468
[75] Yang G, Tan Y, Han Y, Qiu J, Tsubaki N. Catal. Commun., 2008, 9: 2520—2524
[76] Yoneyama Y, He J, Morii Y, Azuma S, Tsubaki N. Catal. Today, 2005, 104: 37—40
[77] Sun B, Yu G, Lin J, Xu K, Pei Y, Yan S, Qiao M, Fan K, Zhang X, Zong B, Catal. Sci. Technol., 2012, 2: 1625—1629
[78] Ren N, Yang Y, Shen J, Zhang Y, Xu H, Gao Z, Tang Y. J. Catal., 2007, 251: 182—188
[79] Ren N, Yang Y, Zhang Y, Wang Q, Tang Y. J. Catal., 2007, 246: 215—222
[80] Khan E A, Hu E P, Lai Z P. Microporous. Mesoporous. Mater., 2009, 118: 210—217
[81] Van V D, Miyamoto M, Nishiyama N, Egashira Y, Ueyama K. J. Catal., 2006, 243: 389—394
[82] 孔德金(Kong D J), 童伟益(Tong W Y), 郑均林(Zheng J L), 刘志城(Liu Z C), 邹薇(Zou W), 祁晓岚(Qi X L), 房鼎业(Fang D Y). 化学通报(Chemistry), 2008, 71: 249—255
[83] Lu Y, Zhao Y, Yu L L, Shi C, Hu M, Xu Y, Wen L, Yu S. Adv. Mater., 2010, 22: 1407—1411
[84] Yuan X, Archer J. Adv. Mater., 2006, 18: 2325—2329
[85] Kim J, Kim H, Lee N, Kim T, Kim H, Yu T, Song I, Moon W, Hyeon T. Angew. Chem. Int. Ed., 2008, 47: 8438—8441
[86] Zhu Y F, Shi J L, Shen W H, Dong X P, Feng J W, Ruan M L, Li Y S. Angew. Chem. Int. Ed., 2005, 44: 5083—5087
[87] Gao J, Liang G, Zhang B, Kuang Y, Zhang X, Xu B. J. Am. Chem. Soc., 2007, 129: 1428—1433
[88] Kamata K, Lu Y, Xia Y N. J. Am. Chem. Soc., 2003, 125: 2384—2385
[89] Wu X, Xu D. J. Am. Chem. Soc., 2009, 131: 2774—2775
[90] Wu S H, Tseng C T, Lin Y S, Lin C H, Hung Y, Mou C Y. J. Mater. Chem., 2011, 21: 789—794
[91] Arnal P, Comotti M, Schüth F, Angew. Chem. Int. Ed., 2006, 45: 8224—8227
[92] Güttel R, Paul M, Ferdi S, Chem. Commun., 2010, 46: 895—897
[93] Huang X, Guo C, Zuo J, Zheng N, Stucky G D. Small, 2009, 5: 361—365
[94] Yin Y D, Rioux R M, Erdonmez C K, Hughes S, Somorjai G A, Alivisatos A P. Science, 2004, 304: 711—714
[95] Sun Y, Wiley B, Li Z Y, Xia Y N. J. Am. Chem. Soc., 2004, 126 : 9399—9406
[96] Park J C, Bang J U, Lee J, Ko C H, Song H. J. Mater. Chem., 2010, 20: 1239—1246
[97] Lee J, Park J C, Bang J U, Song H. Chem. Mater., 2008, 20: 5839—5844
[98] Lee J, Park J C, Song H. Adv. Mater., 2008, 20: 1523—1528
[99] Chen Y, Chen H, Guo L, He Q, Chen F, Zhou J, Feng J, Shi J. ACS Nano, 2010, 4: 529—539
[100] Chen D, Li L, Tang F, Qi S. Adv. Mater., 2009, 21: 3804—3807
[101] Fang X, Chen C, Liu Z, Liu P, Zheng N. Nanoscale, 2011, 3: 1632—1639
[102] Zhang T, Ge J, Hu Y, Zhang Q, Aloni S, Yin Y. Angew. Chem. Int. Ed., 2008, 47: 5806—5811
[103] Li Y X, Liu S Q, Yao L H, Ji W J, Au C T. Catal. Commun., 2010, 11: 368—372
[104] Yao L H, Li Y X, Zhao J, Ji W J, Au C T. Catal. Today, 2010, 158: 401—408
[105] Yao L H, Shi T B, Li Y X, Zhao J, Ji W J, Au C T. Catal. Today, 2011, 164: 112—119
[106] Li Y X, Yao L H, Liu S Q, Zhao J, Ji W J, Au C T. Catal. Today, 2011, 160: 79—86
[107] Li Y X, Yao L H, Song Y Y, Liu S Q, Zhao J, Ji W J, Au C T. Chem. Commun., 2010, 46: 5298—5300
[108] Li L, He S C, Song Y Y, Zhao J, Ji W J, Au C T. J. Catal., 2012, 288: 54—64
[109] Li L, Lu P, Yao Y, Ji W J. Catal. Commun., 2012, 26: 72—77
[110] Li L, Sun B, Fei Z Y, Yao Y, Zhao J, Ji W J, Au C T. ChemCatChem, 2013, DOI:10.1002/cctc.201300537
[111] Park J C, Lee H J, Jung H S, Kim M, Kim H J, Park K H, Song H. ChemCatChem., 2011, 3: 755—760
[112] Kim S H, Yin Y D, Alivisatos A P, Somorjai G A, Yates J T. J. Am. Chem. Soc., 2007, 129: 9510—9513
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