Qian Renyuan,Wu Liheng. Single-Chain Glasses and Single Crystals of Flexible Chain Polymers[J]. Progress in Chemistry, 1996, 8(03): 177-.
A review is presented on the methods of preparation of single-chain particles, including atomizer spraying, surface film spreading, freeze-drying of very dilute solutions and microemulsion polymerization. The properties of single-chain and pauci-chain polystyrene microspheres and recent results on the electron microscopy and selected area electron diffraction of single-chain monocrystals of polyethylene oxide, isotactic polystyrene, cis-1, 4-polybutadiene and guttapercha are presented and discussed.