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Progress in Chemistry 2008, Vol. 20 Issue (0203): 221-226 Previous Articles   Next Articles

• Review •

Synthesis of Dimethyl Carbonate by Direct Vapor-phase Oxycarbonylation of Methanol

Song Yibing; Luo Aiguo; Du Yuhai; Fang Yiwen

  

  1. (Institute of Applied Catalysis, Shantou University, Shantou 515063, China)
  • Received: Revised: Online: Published:
  • Contact: Song Yibing
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Dimethyl carbonate (DMC) is a green chemical imtermediate of considerable importance in organic synthesis. There are several ways to the synthesis of dimethyl carbonate, in which vapor-phase method has many advantages, such as low erosion, relatively easier separation of products, attainable raw material etc. This paper reviews the research progress of the method, including reaction conditions, catalysts preparation, reaction mechanism and kinetic model. The co-product, water, in this reaction often causes catalyst deactivation and equipment corrosion. Considering the fact, the coupling of dimethyl ether (DME) hydrolysis with methanol carbonylation reaction, by using DME as a co-feed gas, is proposed to diminish the side effects from water and improve catalyst stability.
Key words: dimethyl carbonate, methanol, dimethyl ether, vapor-phase, oxycarbonylation

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