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Progress in Chemistry 2008, Vol. 20 Issue (0203): 208-211 Previous Articles   Next Articles

• Review •

Some developments of Geometric Phase Effects in Chemical Reactions

Yu Angyang   

  1. (School of Science, Liaoning University of Petroleum & Chemical Technology, Fushun 113001, China)
  • Received: Revised: Online: Published:
  • Contact: Yu Angyang
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Despite the central position of Born-Oppenheimer approximation in chemical theory, its breakdowns, electronically nonadiabatic processes are ubiquitous. On the ground state potential energy surface, a conical intersection produces the geometric phase effect. A conical intersection could influence the nuclear dynamics through the geometric phase effect. The origin of the geometric phase effect and some theoretical approaches including the geometric phase effect are reviewed. Some recent results concerned with the geometric phase effect in the reaction dynamics are demonstrated and there are explanation for these intriguing results. There are also some predictions for the future of the geometric phase effects in reaction dynamics. It is pointed that the geometric phase effect will play the most important role in nonadiabatic chemistry.

Key words: conical intersection, geometric phase effect, reaction dynamics, nonadiabatic chemistry

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