中文
Earlier issues
Announcement
More
Progress in Chemistry 2007, Vol. 19 Issue (10): 1460-1467 Previous Articles   Next Articles

• Review •

Sol-gel Synthesis of LiFePO4 Cathode

Le Hui**; Zilong Tang;Shaohua Luo;Zhongtai Zhang   

  1. State Key Lab. of New Ceramics and Fine Processing, Department of Materials Scinece and Engineering, Tsinghua University, Beijing 100084, China
  • Received: Revised: Online: Published:
PDF ( 2699 ) Cited
Export

EndNote

Ris

BibTeX

The principle of sol-gel synthesis of LiFePO4 cathode material is introduced. The progress of sol-gel synthesis of LiFePO4 in recent years is emphasized. Three modification strategies including car-bon-coating, doping and nano techniques, as well as their melioration of the performances of LiFePO4 cathode material are summarized. As a result, capacity enhancement, the decrease in particle size and carbon content, and the obvious shortening of heat treatment are achieved. Further, several problems related to deeper understanding of the synthesis procedure, production cost and environmental pollution are pointed out. Finally, the possibility of its commercialization is discussed.
Key words: Sol-gel, LiFePO4, Lithium-ion batterys, cathode materials

CLC Number: 

[1 ] Padhi A K, Nanjundaswamy K S , Goodenough J B. Journal of Electrochemical Society , 1997 , 144 (4) : 1188 —1194
[2 ] Hsu K F , Tsay S Y, Hwang B J . Materials Chemistry , 2004 , 14 :2690 —2695
[3 ] Yang J , Xu J J . Journal of the Electrochemical Society , 2006 ,153(4) : A716 —A723
[4 ] Hu Y, Doeff M M, Kostecki R , et al . Journal of Electrochemical Society , 2004 , 151 : A1279 —A1285
[5 ] Belharouak I , Johnson C , Amine K. Electrochemistry Communications , 2005 , 7 : 983 —988
[6 ] Yang M R , Ke W H , Wu S H. Journal of Power Sources , 2005 ,146 : 539 —543
[7 ] 张静(Zhang J) , 刘素琴(Liu S Q) , 黄可龙(Huang KL) 等.无机化学学报(Chinese Journal of Inorganic Chemistry) , 2005 ,21(3) : 433 —436
[8 ] Iriyama Y, Yokoyama M, Yada C , et al . Electrochemical and Solid State Letters , 2004 , 7(10) : A340 —A342
[9 ] Ma J , Qin Q Z. Journal of Power Sources , 2005 , 148 : 66 —71
[10] 李发喜(Li F X) , 仇卫华(Qiu W H) , 胡环宇(Hu H Y) 等.北京科技大学学报( Journal of University of Science and Technology Beijing) , 2005 , 27(1) : 86 —89
[11] Takeuchi T , Tabuchi M, Nakashima A , et al . Journal of Power Sources , 2005 , 146 : 575 —579
[12] Kosova N , Devyatkina E. Solid State Ionics , 2004 , 172 : 181 —184
[13] Fu L J , Liu H , Li C , et al . Progress in Materials Science , 2005 ,50 : 881 —928
[14] Spong A D , Vitins G, Owenz J R. Journal of the Electrochemical Society , 2005 , 152 (12) : A2376 —A2382
[15] 倪江锋(Ni J F) , 苏光耀(Su G Y) , 周恒辉(Zhou H H) 等.化学进展(Progress in Chemstry) , 2004 , 16(4) : 554 —560
[16] Komarneni S , Sakka S , Phule P P , et al . Sol-Gel Synthesis and Processing , 1st ed. Ohio : the American Ceramic Society , 1998.3 —16
[17] Lee B , Komarneni S. Chemical Processing of Ceramics , 2nd ed.Boca Raton : CRC Press , 2005. 304 —408
[18] Zhang L L. Preparation of Multi-Component Ceramic Nanoparticles. Ohio State University , 2004
[19] Hu Y Q , Doeff M M, Kostecki R , et al . Journal of Electrochemical Society , 2004 , 151 : A1279 —A1285
[20] Penchini M P. US 3 330 697 , 1967
[21] Tarascon J M, Delacourt C , Prakash A S , et al . Dalton Trans. ,2004 , 2988 —2994
[22] Croce F. Electrochemical and Solid State Letters , 2002 , 5 (3) ,A47 —A50
[23] Barker J , Saidi M Y, Swoyer J L. Electrochemical and Solid State Letters , 2003 , 6(3) : A53 —A55
[24] Gaberscek M, Dominkoa R , Bele M, et al . Solid State Ionics ,2005 , 176 : 1801 —1805
[25] Doeff M M, Hu Y Q , McLarnon F , et al . Electrochemical and Solid State Letters , 2003 , 6(10) : A207 —A209
[26] 丁燕怀(Ding Y H) , 苏光耀(Su G Y) , 高德淑(Gao D S) 等.电池(Battery Bimonthly) , 2006 , 36(1) : 52 —53
[27] Pierre A C. Introduction to Sol-Gel Processing. Kluwer Academic Publishers , 1998. Chap. 1 —2
[28] 余桂郁(Yu G Y) , 杨南如( Yang N R) . 硅酸盐学报, 1993 ,6 : 60 —66
[29] Wu S H , Hsiao K M, Liu W R. Journal of Power Sources , 2004 ,146 : 550 —554
[30] Sanchez M, Brito G, Fantini M, et al . Solid State Ionics , 2006 ,177 : 497 —500
[31] Hsu K F , Tsay S Y, Hwang B J . Journal of Power Sources , 2005 ,146 : 529 —533
[32] Huang H , Yin S C , Nazarz L F. Electrochemical and Solid State Letters , 2001 , 4(10) : A170 —A172
[33] Zhao H C , Dahn J D. Journal of the Electrochemical Society ,2002 , 149 (9) : A1184 —A1189
[34] Dominko R , Bele M, Gaberscek M, et al . Journal of the Electrochemical Society , 2005 , 152 (3) : A607 —A610
[35] 卢俊彪(Lu J B) , 唐子龙(Tang Z L) , 张中太(Zhang Z T) . 物理化学学报(Acta Phys. 2Chim. Sin. ) , 2005 , 21(3) : 319-323
[36] Chung S Y, Bloking J , Chiang Y M. Nature Materails , 2002 , 1 :123 —128
[37] Wang G X, Bewlay S , Yao J , et al . Electrochemical and Solid State Letters , 2004 , 7(12) : A503 —A506
[38] Sides C R , Croce F , Young V Y, et al . Electrochemical and Solid State Letters , 2005 , 8(9) : A484 —A487
[39] Lu J B , Tang Z L , Zhang Z T , et al . Journal of the Electrochemical Society , 2005 , 152 (7) : A1441 —A1444
[40] Delacourt C , Poizot P , Levasseur S , et al . Electrochemical and Solid State Letters , 2006 , 9(7) : A352 —A355
[41] 肖卓炳(Xiao Z B) , 麻明友(Ma M Y) . 电源技术与设计(Chinese Journal of Power Sources) , 2006 , 30 (5) : 373 —375 ,379
[1] Jian Li, Enshuang Zhang, Yuanyuan Liu, Hongyan Huang, Yuefeng Su, Wenjing Li. Preparation of the Ultralow Density Aerogel and Its Application [J]. Progress in Chemistry, 2020, 32(6): 713-726.
[2] Jianwen Liu, Heyang Jiang, Chihang Sun, Wenbin Luo, Jing Mao, Kehua Dai. P2-Structure Layered Composite Metal Oxide Cathode Materials for Sodium Ion Batteries [J]. Progress in Chemistry, 2020, 32(6): 803-816.
[3] Guange Wang, Huaning Zhang, Tong Wu, Borui Liu, Qing Huang, Yuefeng Su. Recycling and Regeneration of Spent Lithium-Ion Battery Cathode Materials [J]. Progress in Chemistry, 2020, 32(12): 2064-2074.
[4] Zhiyuan Lu, Yanni Liu, Shijun Liao. Enhancing the Stability of Lithium-Rich Manganese-Based Layered Cathode Materials for Li-Ion Batteries Application [J]. Progress in Chemistry, 2020, 32(10): 1504-1514.
[5] Yijia Shao, Bin Huang, Quanbing Liu, Shijun Liao. Preparation and Modification of Ni-Co-Mn Ternary Cathode Materials [J]. Progress in Chemistry, 2018, 30(4): 410-419.
[6] Zhang Songtao, Zheng Mingbo, Cao Jieming, Pang Huan. Porous Carbon/Sulfur Composite Cathode Materials for Lithium-Sulfur Batteries [J]. Progress in Chemistry, 2016, 28(8): 1148-1155.
[7] Yi Luocai, Ci Suqin, Sun Chengli, Wen Zhenhai. Cathode Materials of Non-Aqueous Lithium-Oxygen Battery [J]. Progress in Chemistry, 2016, 28(8): 1251-1264.
[8] Chen Jun, Ding Nengwen, Li Zhifeng, Zhang Qian, Zhong Shengwen. Organic Cathode Material for Lithium Ion Battery [J]. Progress in Chemistry, 2015, 27(9): 1291-1301.
[9] Liu Yuping, Xie Jian, Li Tingting, Deng Ling, Chen Changguo, Zhang Dingfei. Development of Mg-Transition Metal Complex as Cathode Materials [J]. Progress in Chemistry, 2014, 26(09): 1596-1608.
[10] Bai Ying, Li Yu, Zhong Yunxia, Chen Shi, Wu Feng, Wu Chuan. Li-Rich Transition Metal Oxide xLi2MnO3·(1-x)LiMO2 (M=Ni, Co or Mn) for Lithium Ion Batteries [J]. Progress in Chemistry, 2014, 26(0203): 259-269.
[11] Wang Fuqing, Chen Jian, Zhang Feng, Yi Baolian. Polyanion-Type Cathode Materials for Li-Ion Batteries [J]. Progress in Chemistry, 2012, 24(08): 1456-1465.
[12] Li Yuejiao, Hong Liang, Wu Feng. Preparation of Li3V2(PO4)3 Cathode Material for Power Li-Ion Batteries [J]. Progress in Chemistry, 2012, 24(01): 47-53.
[13] Wang Zhaoxiang, Chen Liquan, Huang Xuejie. Structural Design and Modification of Cathode Materials for Lithium Ion Batteries [J]. Progress in Chemistry, 2011, 23(0203): 284-301.
[14] Dong Quanfeng, Wang Chong, Zheng Mingsen. Research Progress and Prospects of Lithium Sulfur Batteries [J]. Progress in Chemistry, 2011, 23(0203): 533-539.
[15] Wang Weikun, Yu Zhongbao, Yuan Keguo, Wang Anbang, Yang Yusheng. Key Materials of High Energy Lithium Sulfur Batteries [J]. Progress in Chemistry, 2011, 23(0203): 540-547.
Viewed
Full text


Abstract

Sol-gel Synthesis of LiFePO4 Cathode