中文
Announcement
More
Progress in Chemistry 2007, Vol. 19 Issue (9): 1301-1312 Previous Articles   Next Articles

• Review •

Anode Electrocatalysts for Direct Methanol Fuel Cells

Tang Zhicheng 1,2;Lv Gongxuan1**   

  1. 1. State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou, 730000, China;

    2. Graduate School of the Chinese Academy of Sciences, Beijing, 100080, China

  • Received: Revised: Online: Published:
  • Contact: Lv Gongxuan
PDF ( 3090 ) Cited
Export

EndNote

Ris

BibTeX

Direct methanol fuel cell(DMFC) has attracted much attention for their potential applications as clean and mobile power sources due to its advantages of low operating temperature (<100℃), easy transportation and storage of the fuel, high energy efficiency and low exhaustion, and the fast start-up of fuel. Anode electrocatalysts are the main components of direct methanol fuel cell. The progress of anode electrocatalysts for direct methanol fuel cell in the recent three years is reviewed in this paper. The preparation methods of electrocatalysts, the preparation and application of the novel carbon materials, the kinds of electrocatalysts are described in detailed. The trend of future research in the area of anode electrocatalysts is suggested, the existed problem are pointed out.

CLC Number: 

[ 1 ] Hamnett A. Catal . Today , 1997 , 38 : 445 —457
[ 2 ] Burstein G T , Barnett C J , Kucernak A R , et al . Catal . Today ,1997 , 38 : 425 —437
[ 3 ] Iwasita T. Electrochim. Acta , 2002 , 47 : 3663 —3674
[ 4 ] Lamy C , Lima A , LeRhun V , et al . J . Power Sources , 2002 ,105 : 283 —296
[ 5 ] Liu H S , Song C J , Zhang J J , et al . J . Power Sources , 2006 ,155 : 95 —110
[ 6 ] Tang Z C , Geng D S , Lu G X. Mater. Lett . , 2005 , 59 : 1567 —1570
[ 7 ] Tang Z C , Geng D S , Lu G X. J . Colloid Interface Sci . , 2005 ,287 : 159 —166
[ 8 ] Tang Z C , Geng D S , Lu G X. Thin Solid Films , 2006 , 497 :309 —314
[ 9 ] Tang Z C , Lu G X. J . Power Sources , 2006 , 162 : 1067 —1072
[10] Tang Z C , Li Q Y, Lu G X, Carbon , 2007 , 45(1) : 41 —46.
[11] 耿东生(Geng D S) , 吕功煊(Lu G X) , 毕玉水(Bi Y S) . 化学学报(Acta Chim. Sin. ) , 2005 , 63 : 658 —662
[12] Geng D S , Chen L , Lu G X. J . Mol . Catal A , Chem. , 2007 ,265 : 42 —49
[13] Huang S Y, Chang C M, Yeh C T. J . Catal . , 2006 , 241 : 400 —406
[14] Guo J W, Zhao T S , Prabhuram J . J . Power Sources , 2006 , 156 :345 —354
[15] Xue X Z , Ge J J , Xing W, et al . Electrochem. Commun. ,2006 , 8 : 1280 —1286
[16] Yang B , Lu Q Y, Zhuang L , et al . Chem. Mater. , 2003 , 15 :3552 —3557
[17] Bai Y X, Wu J J , Qiu X P , et al . Electrochem. Commun. ,2005 , 7 : 1087 —1090
[18] Xu C W, Zeng R , Shen P K, et al . Electrochim. Acta , 2005 ,51 : 1031 —1035
[19] Xu C W, Shen P K, Ji X H , et al . Electrochem. Commun. ,2005 , 7 : 1305 —1308
[20] Liu Z L , Ling X Y, Su X D , et al . J . Phys. Chem. B , 2004 ,108 : 8234 —8240
[21] Mu Y Y, Liang H P , Wan L J , et al . J . Phys. Chem. B , 2005 ,109 : 22212 —22216
[22] Chen W F , Huang H Y, Kuo P L , et al . J . Phys. Chem. B ,2006 , 110 : 9822 —9830
[23] Park K W, Han D S , Sung Y E. J . Power Sources , 2006 , 163(1) : 82 —86
[24] Tu H C , Wang W L , Wan C C , et al . J . Phys. Chem. B , 2006 ,110 : 15988 —15993
[25] Zhou W J , Zhou Z H , Xin Q , et al . Appl . Catal . B , 2003 , 46 :273 —285
[26] Bock C , Paquet C , Couillard M, et al . J . Am. Chem. Soc. ,2004 , 126 : 8028 —8037
[27] Li W Z , Liang C H , Xin Q , et al . Carbon , 2002 , 40 : 783 —803
[28] Liang Y M, Zhang H M, Zhong H X, et al . J . Catal . , 2006 ,238 : 468 —476
[29] Liao S , Holmes K A , Birss V I , et al . J . Am. Chem. Soc. ,2006 , 128 : 3504 —3505
[30] Yan S Y, Sun G Q , Tian J , et al . Electrochim. Acta , 2006 , 52 :1692 —1696
[31] Zhou Z H , Zhou W J , Xin Q , et al . Catal . Today , 2004 , 93P95 :523 —528
[32] Kim P , Joo J B , Yi J , et al . J . Power Sources , 2006 , 160 :987 —990
[33] Zhang X, Chan K Y. Chem. Mater. , 2003 , 15 : 451 —459
[34] Zhang X, Chan K Y. J . Mater. Chem. , 2002 , 12 : 1203 —1206
[35] Xu W L , Lu T H , Xing W, et al . J . Phys. Chem. B , 2005 ,109 : 14325 —14330
[36] Chen W X, Lee J Y, Liu Z. Chem. Commun. , 2002 , 21 :2588 —2589
[37] Tian Z Q , Jiang S P , Liang Y M, et al . J . Phys. Chem. B ,2006 , 110 : 5343 —5350
[38] Yang H , Alonso-Vante N , Lamy C , et al . J . Phys. Chem. B ,2004 , 108 : 1938 —1947
[39] Huang J C , Liu Z L , He C B , et al . J . Phys. Chem. B , 2005 ,109 : 16644 —16649
[40] Lin H Y, Cui X L , Yen C , et al . J . Phys. Chem. B , 2005 ,109 : 14410 —14415
[41] Prabhuram J , Zhao T S , Tang Z K, et al . J . Phys. Chem. B ,2006 , 110 : 5245 —5252
[42] Li W Z , Liang C H , Xin Q , et al . J . Phys. Chem. B , 2003 ,107 : 6292 —6299
[43] Frackowiak E , Lota G, Cacciaguerra T , et al . Electrochem.Commun. , 2006 , 8 : 129 —132
[44] Kongkanand A , Vinodgopal K, Kuwabata S , et al . J . Phys.Chem. B , 2006 , 110 : 16185 —16188
[45] Girishkumar G, Vinodgopal K, Kamat P V , et al . J . Phys.Chem. B , 2006 , 110 : 107 —114
[46] Li W Z , Wang X, Yan Y S , et al . J . Phys. Chem. B , 2006 ,110 : 15353 —15358
[47] Bessel C A , Laubernds K, Rodriguez N M, et al . J . Phys.Chem. B , 2001 , 105 : 1115 —1118
[48] Steigerwalt E S , Deluga G A , Lukehart C M, et al . J . Phys.Chem. B , 2001 , 105 : 8097 —8101
[49] Steigerwalt E S , Deluga G A , Lukehart C M. J . Phys. Chem. B ,2002 , 106 : 760 —766
[50] Tang H , Chen J H , Nie L H , et al . J . Colloid Interface Sci . ,2004 , 269 : 26 —31
[51] Guo J S , Sun G Q , Wang Q , et al . Carbon , 2006 , 44 : 152 —157
[52] Joo S H , Choi S J , Ryoo R , et al . Nature , 2001 , 412 : 469 —472
[53] Yu J S , Kang S , Yoon S B , et al . J . Am. Chem. Soc. , 2002 ,124 : 9382 —9383
[54] Joo S H , Pak C , You D J , et al . Electrochim. Acta , 2006 , 52 :1618 —1626
[55] Kim H , Kim P , Yi J , et al . J . Power Sources , 2006 , 157 :196 —200
[56] Su F B , Zeng J H , Zhao X S , et al . Chem. Mater. , 2005 , 17 :3960 —3967
[57] Su F B , Zeng J H , Zhao X S , et al . Carbon , 2005 , 43 : 2366 —2373
[58] Choi Y S , Joo S H , Pak C , et al . Macromolecules , 2006 , 39 :3275 —3282
[59] Zeng J H , Su F B , Lee J Y, et al . Carbon , 2006 , 9 : 1713 —1717
[60] Marie J , Berthon2Fabry S , Achard P , et al . J . Non-Crystal .Solids , 2004 , 350 : 88 —96
[61] Samant P V , Fernandes J B , Rangel C M, et al . Catal . Today ,2005 , 102/103 : 173 —176
[62] Babic B M, Vracar L M, Krstajic N V , et al . Electrochim. Acta ,2006 , 51 : 3820 —3826
[63] Xu B S , Yang X W, Wang X M, et al . J . Power Sources , 2006 ,162 : 160 —164
[64] Liu Y C , Qiu X P , Huang Y Q , et al . Carbon , 2002 , 40 :2375 —2380
[65] Vinodgopal K, Haria M, Kamat P , et al . Nano Lett . , 2004 , 4 :415 —418
[66] Park K W, Sung Y E. J . Phys. Chem. B , 2004 , 108 : 939 —944
[67] Yang R Z , Qiu X P , Zhang H R , et al . Carbon , 2005 , 43 : 11 —16
[68] Sun C L , Chen L C , Su M C , et al . Chem. Mater. , 2005 , 17 :3749 —3753
[69] Tang H , Chen J H , Ren Z F , et al . Mater. Chem. Phys. , 2005 ,92 : 548 —553
[70] Wang Z B , Yin G P , Shi P F. Carbon , 2006 , 44 : 133 —140
[71] Wang C H , Shih H C , Chen K H , et al . Electrochim. Acta ,2006 , 52 : 1612 —1617
[72] Shioyama H , Honjo K, Kiuchi M, et al . J . Power Sources ,2006 , 161 : 836 —838
[73] Huang J E , Guo D J , Li H L , et al . J . Electroanal . Chem. ,2005 , 577 : 93 —97
[74] De la Fuente J L G, Martinez-Huerta M V , Rojas S , et al .Carbon , 2005 , 43 : 3002 —3005
[75] De la Fuente J L G, Martinez2Huerta MV , Rojas S , et al . Catal .Today , 2006 , 116 : 422 —432
[76] Wang HJ , Yu H , Peng F , et al . Electrochem. Commun. , 2006 ,8 : 499 —504
[77] Kim Y T , Mitani T. J . Catal . , 2006 , 238 : 394 —401
[78] Pan D W, Chen J H , Tao W Y, et al . Langmuir , 2006 , 22 :5872 —5876
[79] Gasterger H A , Markovic N , Ross P N , et al . J . Phys. Chem. ,1993 , 97 : 12020 —12029
[80] Solla-Gullon J , Vidal-Iglesias FJ , Montiel A , et al . Electrochim.Acta , 2004 , 49 : 5079 —5088
[81] Spinace E V , Neto A O , Vasconcelos T R R , et al . J . Power Sources , 2004 , 137 : 17 —23
[82] Park I S , Choi B , Sung Y E , et al . Electrochim. Acta , 2006 ,52 : 1683 —1687
[83] Jiang L H , Sun G Q , Xin Q , et al . Electrochim. Acta , 2005 ,50 : 2371 —2376
[84] Liu Z L , Lee J Y, Chen W X, et al . Langmuir , 2004 , 20 :181 —187
[85] Chen Z G, Qiu X P , Lu B , et al . Electrochem. Commun. ,2005 , 7 : 593 —596
[86] Villullas H M, Mattos-Costa F I , Bulhoes L O S. J . Phys. Chem.B , 2004 , 108 : 12898 —12903
[87] Colmati F , Antolini E , Gonzalez E R. Electrochim. Acta , 2005 ,50 : 5496 —5503
[88] Parinyaswan A , Pongstabodee S , Luengnaruemitchai A. Int . J .Hydrogen Energy , 2006 , 31 : 1942 —1949
[89] Qiao B T , Deng Y Q. Appl . Catal . B , 2006 , 66 : 241 —248
[90] Sarkar A D , Khanra B C. J . Mol . Catal . A , Chem. , 2005 ,229 : 5 —29
[91] Luo J , Maye M M, Zhong C J , et al . Catal . Today , 2005 , 99 :291 —297
[92] Luo J , Njoki P N , Zhong C J , et al . Langmuir , 2006 , 22 :2892 —2898
[93] Solla-Gullon J , Rodes A , Montiel V , et al . J . Electroanal .Chem. , 2003 , 554/555 : 273 —284
[94] Anderson B , Grantscharava E. J . Electrochem. Soc. , 1996 ,143 : 2075 —2082
[95] Deivaraj T C , Chen W, Lee J Y. J . Mater. Chem. , 2003 , 13 :2555 —2560
[96] Moore J T , Chu D , Lukehart C M, et al . Chem. Mater. , 2003 ,15 : 1119 —1124
[97] Choi J S , Chung W S , Lee H I , et al . J . Power Sources , 2006 ,156 : 466 —471
[98] Zhang L T , Xia D G. Appl . Surf . Sci . , 2006 , 158 : 524 —528
[99] Roychowdhury C , Matsumoto F , DiSalvo F J , et al . Chem.Mater. , 2005 , 17 : 5871 —5876
[100] De Oliveira M B , Profeti L P R , Olivi P. Electrochem.Commun. , 2005 , 7 : 703 —709
[101] Lasch K, Jorissen L , Garche J . J . Power Sources , 1999 , 84 :225 —230
[102] ShimJ , Lee C R , Lee H K, et al . J . Power Sources , 2001 , 102 :172 —177
[103] Park K W, Sung Y E , Toney M F. Electrochem. Commun. ,2006 , 8 : 359 —363
[104] Ganesan R , Lee J S. J . Power Sources , 2006 , 157 : 217 —221
[105] Martinez-Huerta M V , Rojas S , de la Fuente J L G, et al . Appl .Catal . B , 2006 , 69 : 75 —84
[106] Wang Z B , Yin G P , Zhang J , et al . J . Power Sources , 2006 ,160 : 37 —43
[107] Liang Y M, Zhang H M, Tian Z Q , et al . J . Phys. Chem. B ,2006 , 110 : 7828 —7834
[108] Casado-Rivera E , Volpe D J , DiSalvo F J , et al . J . Am. Chem.Soc. , 2004 , 106 : 4043 —4049
[109] Xu C W, Shen P K. Chem. Commun. , 2004 , 19 : 2238 —2239
[110] 陈玲(Chen L) , 王新东(Wang X D) , 郭敏( Guo M) . 物理化学学报(Acta Phys. Chim. Sin. ) , 2006 , 22 : 141 —145

[1] Jing He, Jia Chen, Hongdeng Qiu. Synthesis of Traditional Chinese Medicines-Derived Carbon Dots for Bioimaging and Therapeutics [J]. Progress in Chemistry, 2023, 35(5): 655-682.
[2] Hao Chen, Xu Xu, Chaonan Jiao, Hao Yang, Jing Wang, Yinxian Peng. Fabrication of Multifunctional Core-Shell Structured Nanoreactors and Their Catalytic Performances [J]. Progress in Chemistry, 2022, 34(9): 1911-1934.
[3] Feng Lu, Ting Zhao, Xiaojun Sun, Quli Fan, Wei Huang. Design of NIR-Ⅱ Emissive Rare-earth Nanoparticles and Their Applications for Bio-imaging [J]. Progress in Chemistry, 2022, 34(6): 1348-1358.
[4] Qin Zhong, Shuai Zhou, Xiangmei Wang, Wei Zhong, Chendi Ding, Jiajun Fu. Construction of Mesoporous Silica Based Smart Delivery System and its Therapeutic Application in Various Diseases [J]. Progress in Chemistry, 2022, 34(3): 696-716.
[5] Dandan Zhang, Qi Wu, Guangbo Qu, Jianbo Shi, Guibin Jiang. Quantitative Analysis of Metal Nanoparticles in Unicellular Aquatic Organisms [J]. Progress in Chemistry, 2022, 34(11): 2331-2339.
[6] Yubing Wang, Jie Chen, Wei Yan, Jianwen Cui. Preparation and Application of Conjugated Microporous Polymers [J]. Progress in Chemistry, 2021, 33(5): 838-854.
[7] Dong Yang, Keyi Gao, Baiqin Yang, Lei Lei, Lixia Wang, Chaohua Xue. Classification of Microfluidic System and Applications in Nanoparticles Synthesis [J]. Progress in Chemistry, 2021, 33(3): 368-379.
[8] Chen Liu, Qiangxiang Li, Di Zhang, Yujie Li, Jinquan Liu, Xilin Xiao. Preparation and Application of MCM-41 Mesoporous Silica in the DNA Biosensors [J]. Progress in Chemistry, 2021, 33(11): 2085-2102.
[9] Ding Jingjing, Lili Huang, Haiyan Xie. Application of Nanoparticles-Based Chemiluminescence in Diagnosis and Treatment of Inflammation and Tumor [J]. Progress in Chemistry, 2020, 32(9): 1252-1263.
[10] Miao Qin, Mengjie Xu, Di Huang, Yan Wei, Yanfeng Meng, Weiyi Chen. Iron Oxide Nanoparticles in the Application of Magnetic Resonance Imaging [J]. Progress in Chemistry, 2020, 32(9): 1264-1273.
[11] Jianlin Shi, Zile Hua. Condensed State Chemistry in the Synthesis of Inorganic Nano- and Porous Materials [J]. Progress in Chemistry, 2020, 32(8): 1060-1075.
[12] Rui Bai, Xiaochun Tian, Shuhua Wang, Weifu Yan, Haiyin Gang, Yong Xiao. Noble Metal Nanoparticles Produced by Microorganism [J]. Progress in Chemistry, 2019, 31(6): 872-881.
[13] Depei Liu, Jing Tian, Jingsha Li, Zheng Tang, Haiyan Wang, Yougen Tang. Preparation and Applications of Mn-Ce Binary Oxides [J]. Progress in Chemistry, 2019, 31(6): 811-830.
[14] Yihuan Liu, Xin Hu, Ning Zhu, Kai Guo. Microfluidic Synthesis of Micro-and Nanoparticles [J]. Progress in Chemistry, 2018, 30(8): 1133-1142.
[15] Dongdong Zhang, Jingmin Liu, Yaoyao Liu, Meng Dang, Guozhen Fang, Shuo Wang. The Application of Nanoparticles in Drug Delivery [J]. Progress in Chemistry, 2018, 30(12): 1908-1919.