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Progress in Chemistry 2019, Vol. 31 Issue (12): 1669-1680 DOI: 10.7536/PC190414 Previous Articles   Next Articles

Emerging Ion Exchange Membrane Process-Based Zero Liquid Discharge Technology for Saline Wastewater

Qingbai Chen, Yu Liu, Jinli Zhao, Pengfei Li, Jianyou Wang**()   

  1. Tianjin Key Laboratory of Environmental Technology for Complex Trans-Media Pollution, College of Environmental Science and Engineering, Nankai University, Tianjin 300350, China
  • Received: Online: Published:
  • Contact: Jianyou Wang
  • About author:
    ** E-mail:
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As a continuous ion exchange process, ion exchange membrane(IEM) process has many advantages in terms of green, sustainability, cost and pollution free. The latest applications and current progress of emerging ion exchange membrane process-based zero liquid discharge(ZLD) technology for saline wastewater, such as selectrodialysis, electrodialysis metathesis and reverse electrodialysis, are summarized from the view of some elementary factors(configurations, working mechanism, etc.), by considering the key issues of ZLD process, i.e., huge energy waste, easy scaling and difficult salts separating. The integrations with other separation technologies are introduced and summarized specifically. The review has made a generalization and summarization of the previous works in order to provide some reference for the future works in ZLD progress.

Key words: emerging ion exchange membrane process, saline wastewater, zero liquid discharge
Fig. 1 Specific energy consumption by RO, brine concentrator, and brine crystallizer[16]
Fig. 2 Schematic diagram of SED. SA-monoselectivity anion exchange membrane; C-conventional cation exchange membrane[35]
Fig. 3 Schematic diagram of EDM. A-Anion exchange membrane; C-cation exchange membrane[37]
Fig. 4 Schematic diagram of RED. A-Anion exchange membrane; C-cation exchange membrane[38]
Fig. 5 Structural diagram of the BMSED stack. BM-bipolar membrane; SA-monoselectivity anion exchange membrane; SC-monoselectivity cation exchange membrane[43]
Fig. 6 Schematic illustrations of “SED/Struvite reactor” integrated system[50]
Fig. 7 The schematic principle of ZLD based on EDM
Fig. 8 ZDD flow diagram used for modeling[62]
Fig. 9 Schematic flow diagram of the ED-RED integrated system[66]
Fig. 10 Schematic flow diagram of the “RO/RED” integrated desalination system(a) and “RO/MD/RED” integrated ZDD system(b)[72,73]
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