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Progress in Chemistry 2019, Vol. 31 Issue (10): 1341-1349 DOI: 10.7536/PC190322 Previous Articles   Next Articles

Actinide-Heterobimetal Compounds

Xiaowang Chi1,2, Qunyan Wu2, Jipan Yu2, Qin Zhang1,**(), Zhifang Chai2,3, Weiqun Shi2,**()   

  1. 1. College of Mining, Guizhou University, Guiyang 550025, China
    2. Laboratory of Nuclear Energy Chemistry, Institute of High Energy Physics, Chinese Academy of Sciences, Beijing 100049, China
    3. Engineering Laboratory of Advanced Energy Materials, Ningbo Institute of Industrial Technology, Chinese Academy of Sciences, Ningbo 315201, China
  • Received: Online: Published:
  • Contact: Qin Zhang, Weiqun Shi
  • About author:
    ** E-mail: (Qin Zhang);
    (Weiqun Shi)
  • Supported by:
    National Natural Science Foundation of China(11875058); National Natural Science Foundation of China(U1867205); Project of High-Level Innovative Talents of Guizhou Province, China(黔科合人才[2015]4012号)
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The study of organoactinide compounds has become one of the hot fields in organometallic chemistry, which are extremely challenging on synthesis and separation, and the potential application of actinide-heterobimetal compounds lie in catalysis and small molecule activation. With the deep understanding of unique electronic structure and properties of actinide compounds, some progress has been made in actinide-heterobimetal compounds. This review summarizes the research results of actinide-heterobimetal compounds in the past 30 years, including experimental and theoretical studies on actinide-transition metal and actinide-main group metal systems.

Key words: actinide compound, transition metal, main-group metal, theoretical research
Fig. 1 Th-M(M=Ru, Ni, Pt) compounds[19, 21, 22]
Fig. 2 U-Re Compounds[23, 25, 26]
Fig. 3 U-Co Compound
Fig. 4 U-Ru compounds[28]
Fig. 5 U-Fe Compound[29]
Fig. 6 Th-Cu Compound[30]
Fig. 7 U-Co compounds[35]
Fig. 8 Synthesis of U/Th-Co compounds[34]. Copyright 2014, ACS.
Fig. 9 An-Mo compounds[37]
Fig. 10 U-Rh compound and its single crystal structure[38]. Copyright: WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Fig. 11 U-Ni compound[41]
Fig. 12 U-M(M=Sn, Al, Ga) compounds[42,43,44,45,46]
Fig. 13 U-Pn(Pn=P, As, Sb, Bi) and Th-Pn(Pn=P, As, Sb) compounds[47]
Fig. 14 Covalency in U-E(E=N, P, As, Sb, Bi) triple bonds[54]. Copyright 2015, ACS.
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Abstract

Actinide-Heterobimetal Compounds