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Progress in Chemistry 2017, Vol. 29 Issue (5): 524-529 DOI: 10.7536/PC161221 Previous Articles   Next Articles

• Review •

Preparation and Properties of Porous PDCPD-Based Materials

Zhen Yao, Zufei Wang, Yunfei Yu, Wenlong Yang, Kun Cao*   

  1. State Key Laboratory of Chemical Engineering, College of Chemical and Biological Engineering, Zhejiang University, Hangzhou 310027, China
  • Received: Revised: Online: Published:
  • Supported by:
    The work was supported by the National Key Research and Development Program of China (No.2016YFB0302202) and the National Natural Science Foundation of China (No.51473146).
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The porous polydicyclopentadiene(PDCPD)-based materials which inherit the high modulus of PDCPD have been greatly concerned in recent years. The major methods to prepare porous PDCPD-based materials include sol-gel & supercritical fluid drying,high internal phase emulsion, chemically induced phase separation and chemical foaming. The structure of porous PDCPD-based materials made by different methods determines their various applications. For example, the porous PDCPD-based materials with low-porosity and closed-cell structure that prepared by chemically induced phase separation and chemical foaming can be used as the structural materials. The PDCPD-based composite membrane fabricated by high internal phase emulsion is applied to catalytic reaction. The open-cell PDCPD aerogels made by sol-gel & supercritical fluid drying have high-porosity and low thermal conductivity (<20 mW/(m·K)), which is a good candidate for the thermal insulation materials. The development of the porous PDCPD-based materials are also prospected.
Contents
1 Introduction
2 Sol-gel & supercritical fluid drying
3 High internal phase emulsion
4 Chemically induced phase separation
5 Chemical foaming
6 Conclusion
Key words: polydicyclopentadiene(PDCPD), porous material, foam material, ROMP

CLC Number: 

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