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Progress in Chemistry 2016, Vol. 28 Issue (7): 1076-1083 DOI: 10.7536/PC160139 Previous Articles   Next Articles

• Review and comments •

Organic/Inorganic Nanocomposites Prepared by Miniemulsion Polymerization

Gao Dangge*, Liang Zhiyang, Lyu Bin, Ma Jianzhong   

  1. College of Resources and Environment, Shaanxi University of Science & Technology, Xi'an 710021, China
  • Received: Revised: Online: Published:
  • Supported by:
    The work was supported by the National Natural Science Foundation for Young Scholars of China (No.21406135),the Natural Science Foundation of Shaanxi Province,China (No.2015JM2061),the Youth Science and Technology New Star Project of Shaanxi Province (No.2016KJXX-02),and the Scientific Research Innovation Team of Shaanxi University of Science and Technology (No.TD12-03).
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The introduction of inorganic nanoparticles can make the polymer materials many characteristics, such as antibacterial, conductive, anti-ultraviolet. However, the inorganic nanoparticles are easy to agglomerate and less content of nanoparticles is introduced in polymer, so it is difficult to demonstrate advantage of nano material. Based on its unique droplet nucleation mechanism, miniemulsion polymerization can improve the inorganic nanoparticles’ dispersity and amount of introduction in polymer matrix, and control the morphology of the composites easily. It is an effective method to obtain the special morphology of organic/inorganic nanocomposites. This paper introduces the preparation process of organic/inorganic nanocomposite miniemulsion, and reviews the recent progress of different inorganic nanoparticles with organic matrix composites, such as nano-SiO2, nano-ZnO, metal nanoparticles, nano-graphene oxide, etc. At last, some suggestions on the present development situation are given.

Contents
1 Introduction
2 Preparation and polymerization of organic/inorganic composite miniemulsion
3 The composite of different inorganic nanoparticles and organic matrix
3.1 The composite of nano-SiO2 with organic matrix
3.2 The composite of nano-ZnO with organic matrix
3.3 The composite of metal nanoparticles with organic matrix
3.4 The composite of GO with organic matrix
3.5 The composite of other inorganic nanoparticles with organic matrix
4 Conclusion

Key words: miniemulsion, polymerization, inorganic nanoparticles, nanocomposites

CLC Number: 

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