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Progress in Chemistry 2016, Vol. 28 Issue (7): 1054-1061 DOI: 10.7536/PC160217 Previous Articles   Next Articles

• Review and comments •

Application of Stimuli-Responsive Polymer in Catalyst Systems of Gold Nanoparticles

Wang Yun, Feng Anchao, Yuan Jinying*   

  1. Key Lab of Organic Optoelectronic & Molecular Engineering of Ministry of Education, Department of Chemistry, Tsinghua University, Beijing 100084, China
  • Received: Revised: Online: Published:
  • Supported by:
    The work was supported by the National Natural Science Foundation of China (No.21374053).
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Stimuli-responsive polymer has attracted much attention in recent years. This kind of polymer can respond to external stimuli and switch their properties. Gold nanoparticles have excellent catalytic properties which means a bright application prospect. However, gold nanoparticles are easy to aggregate in the application, and it will result in a remarkable decrease of catalytic property. So different carriers are usually required to immobilize gold nanoparticles. The introduction of the stimuli-responsive polymer into the catalyst systems of gold nanoparticles is a way to prevent the aggregation similar to other normal carriers, and at the same time a fascinating approach to controllable catalyst. This paper reviews recent research progress on this kind of catalyst systems, followed by the discussion of their fabrication, sensitivity and applications. Moreover, the development potential of this field is also discussed.

Contents
1 Introduction
2 Fabrication of stimuli-responsive polymer & gold nanoparticles catalyst systems
2.1 Au-S bond
2.2 Supramolecular system
2.3 In-situ reduction
2.4 Indirect methods
3 Sensitivity and applications of stimuli-responsive polymer & gold nanoparticles catalyst systems
3.1 Thermoresponsive catalyst system
3.2 pH-responsive catalyst system
3.3 CO2-responsive catalyst system
3.4 Glucose-responsive catalyst system
4 Conclusion

Key words: gold nanoparticles, stimuli-responsive polymer, controlled catalyst

CLC Number: 

[1] Tsitsilianis C. Soft Matter, 2010, 6:2372.
[2] Stuart M A C, Huck W T S, Genzer J, Müller M, Ober C, Stamm M, Sukhorukov G B, Szleifer I, Tsukruk V V, Urban M, Winnik F, Zauscher S, Luzinov I, Minko S. Nat. Mater., 2010, 9:101.
[3] Capadona J R, Shanmuganathan K, Tyler D J, Rowan S J, Weder C. Science, 2008, 319:1370.
[4] Yan Q, Yuan J Y, Yuan W Z, Zhou M, Yin Y W, Pan C Y. Chem. Commun., 2008, 46:6188.
[5] Liu X Y, Cheng F, Liu Y, Liu H J, Chen Y. J. Mater. Chem., 2010, 20:360.
[6] Li Y T, Lokitz B S, McCormick C L. Angew. Chem. Int. Ed., 2006, 45:5792.
[7] Lu Y, Proch S, Schrinner M, Drechsler M, Kempeb R, Ballauff M. J. Mater. Chem., 2009, 19:3955.
[8] Chiang Y T, Lo C L. Biomaterials, 2014, 35:5414.
[9] Lynn D M, Amiji M M, Langer R. Angew. Chem. Int. Ed., 2001, 40:1707.
[10] Li D X, He Q, Cui Y, Li J B. Chem. Mater., 2007, 19:412.
[11] Rodríguez-Hernández J, Lecommandoux S. J. Am. Chem. Soc., 2005, 127:2026.
[12] Du J Z, Tang Y Q, Lewis A L, Armes S P. J. Am. Chem. Soc., 2005, 127:17982.
[13] Yan Q, Zhou R, Fu C K, Zhang H J, Yin Y W, Yuan J Y. Angew. Chem. Int. Ed., 2011, 123:5025.
[14] Yan Q, Wang J B, Yin Y W, Yuan J Y. Angew. Chem. Int. Ed., 2013, 52:5070.
[15] Yan Q, Zhang H J, Zhao Y. ACS Macro Lett., 2014, 3:472.
[16] Feng A C, Zhan C B, Yan Q, Liu B W, Yuan J Y. Chem. Commun., 2014, 50:8958.
[17] Liu H B, Guo Z R, He S, Yin H Y, Fei C H, Feng Y J. Polym. Chem., 2014, 5:4756.
[18] Yan Q, Zhao Y. Angew. Chem., 2013, 125:10132.
[19] Peng L, Feng A C, Zhang H J, Wang H, Jian C M, Liu B W, Gao W P, Yuan J Y. Polym. Chem., 2014, 5:1751.
[20] Yan Q, Feng A C, Zhang H J, Yin Y W, Yuan J Y. Polym. Chem., 2013, 4:1216.
[21] Yan Q, Yuan J Y, Cai Z N, Xin Y, Kang Y, Yin Y W. J. Am. Chem. Soc., 2010, 132:9268.
[22] Du P, Liu J H, Chen G S, Jiang M. Langmuir, 2011, 27:9602.
[23] Yan Q, Hu J, Zhou R, Ju Y, Yin Y W, Yuan J Y. Chem. Commun., 2012, 48:1913.
[24] Liu X K, Jiang M. Angew. Chem., 2006, 118:3930.
[25] Hribar K C, Lee M H, Lee D, Burdick J A. ACS Nano, 2011, 5:2948.
[26] Zhang H J, Xin Y, Yan Q, Zhou L L, Peng L, Yuan J Y. Macromol. Rapid Commun., 2012, 33:1952.
[27] Klaikherd A, Nagamani C, Thayumanavan S. J. Am. Chem. Soc., 2009, 131:4830.
[28] Pietsch C, Hoogenboom R, Schubert U S. Angew. Chem. Int. Ed., 2009, 48:5653.
[29] Zou H, Yuan W Z. J. Mater. Chem. B, 2015, 3:260.
[30] Qiu Y, Park K. Adv. Drug Delive. Rev., 2001, 53:321.
[31] Schmaljohann D. Adv. Drug Delive. Rev., 2006, 58:1655.
[32] Bajpai A K, Shukla S K, Bhanu S, Kankane S. Prog. Polym. Sci., 2008, 33:1088.
[33] Ganta S, Devalapally H, Shahiwala A, Amiji M. J. Control. Release, 2008, 126:187.
[34] Gupta P, Vermani K, Garg S. Drug Discov. Today, 2002, 7:569.
[35] Kim E, Kim D, Jung H, Lee J, Paul S, Selvapalam N, Yang Y, Lim N, Park C G, Kim K. Angew. Chem. Int. Ed., 2010, 49:4405.
[36] Kumar S, Tong X, Dory Y L, Lepage M, Zhao Y. Chem. Commun., 2013, 49:90.
[37] Kuroki H, Tokarev I, Nykypanchuk D, Zhulina E, Minko S. Adv. Funct. Mater., 2013, 23:4593.
[38] Nakahata M, Takashima Y, Yamaguchi H, Harada A. Nat. Commun., 2012, 3:187.
[39] 江龙(Jiang L), 王清叶(Wang Q Y), 崔文娟(Cui W J). 化学进展(Progress in Chemistry), 2013, 25(10):1631.
[40] 罗春华(Luo C H), 董秋静(Dong Q J), 郑朝晖(Zheng Z H), 丁小斌(Ding X B), 彭宇行(Peng Y X). 化学进展(Progress in Chemistry), 2009, 21(12):2674.
[41] Zhu M J, Wang L Q, Exarhos G J, Li A D Q. J. Am. Chem. Soc., 2004, 126:2656.
[42] Chen A, Qi J J, Zhao Q S, Li Y, Zhang G L, Zhang F B, Fan X B. RSC Adv., 2013, 3:8973.
[43] Lv W P, Wang Y, Feng W Q, Qi J J, Zhang G L, Zhang F B, Fan X B. J. Mater. Chem., 2011, 21:6173.
[44] Li D X, He Q, Cui Y, Li J B. Chem. Mater., 2007, 19:412.
[45] Liu G Q, Wang D A, Zhou F, Liu W M. Small, 2015, 11:2807.
[46] Luo C H, Zuo F, Zheng Z H, Cheng X, Ding X B, Peng Y X. Macromol. Rapid Commun., 2008, 29:149.
[47] Liu B, Zhang D W, Wang J B, Chen C, Yang X L, Li C X. J. Phys. Chem. C, 2013, 117:6363.
[48] Chen Z, Cui Z M, Cao C Y, He W D, Jiang L, Song W G. Langmuir, 2012, 28:13452.
[49] Wu S, Dzubiella J, Kaiser J, Drechsler M, Guo X H, Ballauff M, Lu Y. Angew. Chem. Int. Ed., 2012, 51:2229.
[50] Ge J P, Huynh T, Hu Y X, Yin Y D. Nano Lett., 2008, 8:931.
[51] Chen J, Xiao P, Gu J C, Han D, Zhang J W, Sun A H, Wang W Q, Chen T. Chem. Commun., 2014, 50:1212.
[52] Xiao C F, Chen S M, Zhang L Y, Zhou S Q, Wu W T. Chem. Commun., 2012, 48:11751.
[53] 冯岸超(Feng A C), 闫强(Yan Q), 袁金颖(Yuan J Y). 化学进展(Progress in Chemistry), 2012, 24(10):1995.
[54] Zhang J M, Han D H, Zhang H J, Chaker M, Zhao Y, Ma D L. Chem. Commun., 2012, 48:11510.
[55] Wu Q S, Cheng H, Chang A P, Xu W T, Lu F, Wu W T. Chem. Commun., 2015, 51:16068.
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