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Progress in Chemistry 2016, Vol. 28 Issue (4): 450-458 DOI: 10.7536/PC151026 Previous Articles   Next Articles

• Review and comments •

Pore Confinement Effects of Catalysts

Xue Lijun, Zhang Di, Wei Jie, Liu Xinmei*   

  1. State Key Laboratory of Heavy Oil Processing, Key Laboratory of Catalysis, China National Petroleum Corporation, China University of Petroleum, Qingdao 266580, China
  • Received: Revised: Online: Published:
  • Supported by:
    The work was supported by the National Natural Science Foundation of China(No. 21376267), the Shandong Province Natural Science Foundation of China(No. 2013ZRE28069)and the Fundamental Research Funds for the Central Universities(No. 14CX06106A).
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The surface electronic distribution and geometric construction of catalysts can be regulated by confined pore canals, which will affect the activity, selectivity and stability of catalysts. Combined with theoretical calculations and experimental methods, from the perspectives of thermodynamics, kinetics, geometric effect and electron transfer, this review illustrates the differences of the active components of catalysts and the characteristics of reaction molecules in different confined systems, and reveals the influence of confined pore canals on the diffusion, adsorption and reaction of reaction species. It aims to provide a reference for the microstructure design and performance control of catalysts.

Contents
1 Introduction
2 Pore confinement effects on diffusion
3 Pore confinement effects on adsorption
4 Pore confinement effects on catalytic reaction
5 Conclusion

Key words: catalysts, pore confinement effects, diffusion, adsorption, catalytic reaction

CLC Number: 

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Abstract

Pore Confinement Effects of Catalysts