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Progress in Chemistry 2015, Vol. 27 Issue (7): 831-840 DOI: 10.7536/PC150137 Previous Articles   Next Articles

• Review and comments •

Inorganic/Organic Core-Shell Composite Nanoparticles by Surface-Initiated Atom Transfer Radical Polymerization

Chen Siyuan, Dong Xu, Zha Liusheng*   

  1. State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, Donghua University, Shanghai 201620, China
  • Received: Revised: Online: Published:
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Atom transfer radical polymerization (ATRP) is by far one of the most promising living /controlled radical polymerization methods in industrial application. It is able to get the polymers with narrow molecular weight distribution and regular chain structure. Furthermore, many kinds of monomers can be polymerized by ATRP, and its reaction condition is mild and easy to control. Surface-initiated atom transfer radical polymerization (SI-ATRP) is a good method for grafting the polymers with regular structure on the surfaces of inorganic materials or synthesizing inorganic/organic composite materials. In recent years, SI-ATRP technique has attracted much attention from domestic and abroad researchers. In this paper, the reaction process and characteristics of SI-ATRP are elaborated, and then the progress in preparation of inorganic/organic core-shell structured composite nanoparticles based on non-metal oxide nanoparticles, metal oxide nanoparticles, metal nanoparticles, and other inorganic nanoparticle as core by SI-ATRP is highly reviewed. Finally, the outlook on future development of SI-ATRP for synthesizing inorganic/organic composite nanoparticles is presented.

Contents
1 Introduction
2 Reaction process and characteristics of SI-ATRP
3 Grafting polymer on different nanoparticles by SI-ATRP
3.1 Inorganic/organic core-shell structured composite nanoparticles based on non-metal oxide nanoparticle as core
3.2 Inorganic/organic core-shell structured composite nanoparticles based on metal oxide nanoparticle as core
3.3 Inorganic/organic core-shell structured composite nanoparticles based on metal nanoparticle as core
3.4 Inorganic/organic core-shell structured composite nanoparticles based on other inorganic nanoparticle as core
4 Conclusion and outlook

Key words: surface initiated atom transfer radical polymerization, controlled radical polymerization, inorganic/organic composite nanoparticles, core-shell structure

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