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Progress in Chemistry 2019, Vol. 31 Issue (9): 1213-1220 DOI: 10.7536/PC190132 Previous Articles   Next Articles

Preparation of the Controllable Core-Shell Structured Electrospun Polymer Fibers and Their Application

Liang Ma, Xuejuan Shi, Xiaoxiao Zhang, Lili Li**()   

  1. Key Laboratory of Automobile Materials, Ministry of Education, College of Materials Science and Engineering, Jilin University, Changchun 130025, China
  • Received: Online: Published:
  • Contact: Lili Li
  • About author:
    ** E-mail:
  • Supported by:
    The National Natural Science Foundation of China(No.51103058)
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Core-shell structured fiber, as a functional composite fiber, has the excellent properties of both core and shell layers. Its special structure and properties greatly broaden the application field of the fibers. Therefore, core-shell structured fiber has become a research hotspot. Electrospinning is an efficient and facile technique for the fabrication of polymer nanofibers, which has attracted much attention in recent years. The method for preparing core-shell structured fibers with controllable structure and morphology is especially useful for guiding its application. The preparation methods of core/shell nanofibers are presented in this review. The methods mainly include single nozzle through phase separation, coaxial electrospinning, emulsion electrospinning, and template method. The major factors for forming the core/shell structure and the effect on the properties of the fibers are discussed in detail. The new research progress of electrospinning core-shell structured fibers in recent years is summarized. The various potential applications in drug controlled release system, tissue engineering scaffold, multifunctional wound dressing, wastewater treatment material, superhydrophobic material, and other fields are also reviewed.

Key words: core-shell structure, electrospinning, composite nanofiber
Fig. 1 Electrospinning facility[1]
Fig. 2 Core/shell nanofibers
Fig. 3 Schematic representation of the electrospinning setup[6]
Fig. 4 Schematic of the core/shell nanofiber electrospinning setup[8]
Fig. 5 TEM images of PAN/PVP core/shell structure nanfibers:(a) PAN∶PVP=2∶1;(b) PAN∶PVP=1∶1;(c) PAN∶PVP=1∶2;(d) PAN∶PVP=1∶1;(e) PAN∶PVP=1∶1 without vapor[8]
Fig. 6 Coaxial electrospinning operation:(a) diagram of the coaxial nozzle;(b) core-sheath droplet without bias; and(c)Taylor cone and coaxial jet formation at 12.5 kV[13]
Fig. 7 The proposed mechanism for fiber structural formation[34]
Fig. 8 Schematic figure of core-shell fiber[51]
Fig. 9 Contact angles for PPFEMA-coated PCL mats. From left to right in the inset are representative droplet images on five samples[52]
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