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Progress in Chemistry 2014, Vol. 26 Issue (10): 1645-1654 DOI: 10.7536/PC140634 Previous Articles   Next Articles

• Review •

Preparation of Metal-Organic Frameworks and Application for CO2 Adsorption and Separation

Jiang Ning1,2, Deng Zhiyong*1, Wang Gongying*1, Liu Shaoying1   

  1. 1. Chengdu Organic Chemicals CO. LTD ( Chengdu Institute of Organic Chemistry), Chinese Academy of Sciences, Chengdu 610041, China;
    2. University of Chinese Academy of Sciences, Beijing 100049, China
  • Received: Revised: Online: Published:
  • Supported by:

    The work was supported by the National Key Technology R & D Program of China (No. 2013BAC11B05),the 1000 Talents Program of Sichuan and Talents Program of Chengdu

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Metal-organic frameworks (MOFs) is one of research hot topic in material area, has potential to become an important material for CO2 adsorption and separation.Three points are introduced,including development and characteristics of MOFs,breakthrough progress of MOFs in CO2 adsorption and separation,preparation of MOFs by traditional synthesis and green methods. Mechanism of MOFs for CO2 adsorption and some special characteristics and advantages of MOFs compared with traditional adsorption materials are discussed. MOFs modification and improvement methods are introduced. Moreover, adsorption capacity and selectivity of MOFs for single-component CO2, CO2/CH4, CO2/N2 are given. Conventional MOFs preparation techniques could not satisfy the large-scale production for CO2 capture, so mechanical chemical synthesis and wet mineral weathering methods are discussed,which have some distinguishing features, such as greenization, solvent-free, low-energy, simplification and so on. Both of them are valuable for research and potentially practical technologies. With global warming and non-renewable fossil fuels consuming problems becoming more and more serious, studying and developing a series of MOFs materials to meet the requirements of carbon capture and storage(CCS) technology are extremely urgent and still had a lot of work to do.

Contents
1 Introduction
2 Development of metal-organic framework materials
2.1 MOFs
2.2 Classification of MOFs
2.3 Characteristics of MOFs
2.4 The effect of moisture on MOFs
3 Studied of MOFs materials in the CO2 adsorption and separation
3.1 Adsorption and separation of CO2 in single component
3.2 Adsorption and separation of CO2 from multi-components
4 MOFs conventional synthesis and green preparation methods
4.1 Conventional synthesis methods
4.2 Low energy consumption and green preparation methods
5 Conclusion

Key words: metal-organic frameworks(MOFs), CO2, adsorption, separation

CLC Number: 

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