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Progress in Chemistry 2014, Vol. 26 Issue (07): 1214-1222 DOI: 10.7536/PC131208 Previous Articles   Next Articles

• Review •

Advances in Structure Controls and Modifications of PIMs Membranes for Gas Separation

Wu Xinmei, Zhang Qiugen*, Zhu Aimei, Liu Qinglin   

  1. College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, China
  • Received: Revised: Online: Published:
  • Supported by:

    The work was supported by the National Natural Science Foundation of China(No. 21306155), the Research Fund for the Doctoral Program of Higher Education (No. 20120121120013) and the Fundamental Research Funds for the Central Universities (No. 2012121029)

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Polymers of intrinsic microporosity (PIMs), as novel microporous organic polymers polymerized by rigid monomers that have sites of contortion, have great application potential in homogeneous catalysis and hydrogen storage due to their high specific surface, chemical and physical stability and pore size controllability. Particularly, PIMs composed of polymer chains attract more attention in gas separation membranes due to their superior gas separation properties and good solubility. Here, the classification and applications of PIMs as well as the properties including stability, gas permeability and gas selectivity of PIMs gas membrane are introduced. The structure controls and modifications of PIMs gas membrane and the relationship between molecular structures and gas separation properties are described in detail. Finally, the problems existed in the present research are pointed out and a brief comment on the development is given.

Contents
1 Introduction
2 Summary of PIMs gas separation membranes
2.1 Classification of PIMs
2.2 Properties of PIMs gas separation membranes
3 Structure controls of PIMs gas separation membranes
3.1 Change of the rigidity of linking groups between benzene rings
3.2 Adjustment of the angles of spiro or twist centers and the lengths between the spirocentres
3.3 Introduce of different pendant substituents
4 Modifications of PIMs gas separation membranes
4.1 Cross-linking
4.2 Blending
5 Conclusions and outlook

Key words: PIMs, gas separation, polymer membrane, microporous organic materials

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[1] Bernardo P, Drioli E, Golemme G. Industrial & Engineering Chemistry Research, 2009, 48: 4638.
[2] Chiappetta G, Clarizia G, Drioli E. Chemical Engineering Journal, 2006, 124: 29.
[3] Xiao Y, Chung T S. Energy & Environmental Science, 2011, 4: 201.
[4] 朱春(Zhu C), 徐安厚(Xu A H), 宗传永(Zong C Y), 李辉(Li H), 张炉青(Zhang L Q), 张书香(Zhang S X). 有机氟工业(Organo-Flurine Industry), 2012, 39(1): 24.
[5] Robeson L M. Journal of Membrane Science, 1991, 62: 165.
[6] 谭婷婷(Tan T T), 展侠(Zhan X), 冯旭东(Feng X D), 李继定(Li J D). 化工新型材料(New Chemical Materials), 2012, 40(10): 4.
[7] Carta M, Malpass-Evans R, Croad M, Rogan Y, Jansen J C, Bernardo P, Bazzarelli F, McKeown N B. Science, 2013, 339: 303.
[8] 梁丽芸(Liang L Y), 李步怡(Li B Y), 陈冰(Chen B), 周壁(Zhou B), 陈可平(Chen K P), 谭必恩(Tan B E). 高分子通报(Polymer Bulletin), 2008,(10): 6.
[9] 宁乐(Ning L), 刘嘉川(Liu J C), 鹿瑞敏(Lu R M), 李桃桃(Li T T), 熊兴泉(Xiong X Q), 程琳(Cheng L). 华侨大学学报(自然科学版)(Journal of Huaqiao University)(Natural science), 2011, 32(4): 361.
[10] McKeown N B, Budd P M. Chemical Society Reviews, 2006, 35: 675.
[11] Du N, Park H B, Dal-Cin M M, Guiver M D. Energy & Environmental Science, 2012, 5: 7306.
[12] 徐叔军(Xu S J), 梁丽芸(Liang L Y), 李步怡(Li B Y), 罗亚莉(Luo Y L), 刘承美(Liu C M), 谭必恩(Tan B E). 化学进展(Progress in Chemistry), 2011, 23(10): 2085.
[13] 赵彦超(Zhao Y C), 陈琦(Chen Q), 韩宝航(Han B H). 中国科学:物理学 力学 天文学(Science Sinica Phys., Mech.＆Astron.), 2011, 41(9): 1029.
[14] 李步怡(Li B Y). 华中科技大学博士论文 (Doctoral Dissertation of Huazhong University of Science and Technology), 2012.
[15] 张步峰(Zhang B F).大连理工大学博士论文(Doctoral Dissertation of Dalian University of Technology), 2011.
[16] 秦墨林(Qin M L), 郭成海(Guo C H), 杨柳(Yang L), 杨杰(Yang J), 曹丙庆(Cao B Q). 生命科学仪器(Life Science Instruments), 2013, 11(10): 22.
[17] McKeown N B, Makhseed S, Budd P M. Chemical Communications, 2002, 2780.
[18] McKeown N B, Hanif S, Msayib K, Tattershall C E, Budd P M. Chemical Communications, 2002, 2782.
[19] Budd P M, Ghanem B, Msayib K, McKeown N B, Tattershall C. Journal of Materials Chemistry, 2003, 13: 2721.
[20] McKeown N B, Gahnem B, Msayib K J, Budd P M, Tattershall C E, Mahmood K, Tan S, Book D, Langmi H W, Walton A. Angewandte Chemie International Edition, 2006, 118: 1836.
[21] Ghanem B S, Msayib K J, McKeown N B, Harris K D, Pan Z, Budd P M, Butler A, Selbie J, Book D, Walton A. Chemical Communications, 2007, 67.
[22] Vile J, Carta M, Bezzu C G, McKeown N B. Polymer Chemistry, 2011, 2: 2257.
[23] Vile J, Carta M, Bezzu C G, Kariuki B M, McKeown N B. Polymer, 2014, 55: 326.
[24] Budd P M, Ghanem B S, Makhseed S, McKeown N B, Msayib K J, Tattershall C E. Chemical Communications, 2004, 230.
[25] Budd P M, Msayib K J, Tattershall C E, Ghanem B S, Reynolds K J, McKeown N B, Fritsch D. Journal of Membrane Science, 2005, 251: 263.
[26] Du N, Robertson G P, Dal-Cin M M, Scoles L, Guiver M D. Polymer, 2012, 53: 4367.
[27] Weber J, Su Q, Antonietti M, Thomas A. Macromolecular Rapid Communications, 2007, 28: 1871.
[28] Zhang Q, Chen G, Zhang S. Polymer, 2007, 48: 2250.
[29] Ghanem B S, McKeown N B, Budd P M, Selbie J D, Fritsch D. Advanced Materials, 2008, 20: 2766.
[30] Ghanem B S, McKeown N B, Budd P M, Al-Harbi N M, Fritsch D, Heinrich K, Starannikova L, Tokarev A, Yampolskii Y. Macromolecules, 2009, 42: 7881.
[31] Budd P M, Elabas E S, Ghanem B S, Makhseed S, McKeown N B, Msayib K J, Tattershall C E, Wang D. Advanced Materials, 2004, 16: 456.
[32] Madkour T M, Mark J E. Journal of Membrane Science, 2012, 437: 37.
[33] Robeson L M. Journal of Membrane Science, 2008, 320: 390.
[34] Heuchel M, Fritsch D, Budd P M, McKeown N B, Hofmann D. Journal of Membrane Science, 2008, 318: 84.
[35] Bezzu C G, Carta M, Tonkins A, Jansen J C, Bernardo P, Bazzarelli F, McKeown N B. Advanced Materials, 2012, 24: 5930.
[36] Du N, Robertson G P, Pinnau I, Guiver M D. Macromolecules, 2010, 43: 8580.
[37] Hart K E, Abbott L J, McKeown N B, Colina C M. Macromolecules, 2013, 46: 5371.
[38] Du N, Robertson G P, Song J, Pinnau I, Thomas S, Guiver M D. Macromolecules, 2008, 41: 9656.
[39] Du N, Robertson G P, Song J, Pinnau I, Guiver M D. Macromolecules, 2009, 42: 6038.
[40] Shao L, Low B T, Chung T S, Greenberg A R. Journal of Membrane Science, 2009, 327: 18.
[41] Du N, Park H B, Robertson G P, Dal-Cin M M, Visser T, Scoles L, Guiver M D. Nature Materials, 2011, 10: 372.
[42] Fang W, Zhang L, Jiang J. The Journal of Physical Chemistry C, 2011, 115: 14123.
[43] Li F Y, Xiao Y, Ong Y K, Chung T S. Advanced Energy Materials, 2012, 2: 1456.
[44] Song Q, Cao S, Zavala-Rivera P, Lu L P, Li W, Ji Y, Al-Muhtaseb S A, Cheetham A K, Sivaniah E. Nature Communications, 2013, 4: 1918.
[45] Du N, Cin M M D, Pinnau I, Nicalek A, Robertson G P, Guiver M D. Macromolecular Rapid Communications, 2011, 32: 631.
[46] Li F Y, Xiao Y, Chung T S, Kawi S. Macromolecules, 2012, 45: 1427.
[47] Du N, Dal-Cin M M, Robertson G P, Guiver M D. Macromolecules, 2012, 45: 5134.
[48] Yong W, Li F, Xiao Y, Li P, Pramoda K, Tong Y, Chung T. Journal of Membrane Science, 2012, 407: 47.
[49] Ahn J, Chung W J, Pinnau I, Song J, Du N, Robertson G P, Guiver M D. Journal of Membrane Science, 2010, 346: 280.
[50] Bushell A F, Budd P M, Attfield M P, Jones J T, Hasell T, Cooper A I, Bernardo P, Bazzarelli F, Clarizia G, Jansen J C. Angewandte Chemie International Edition, 2013, 52: 1253.
[51] Munir Khan M, Filiz V, Bengtson G, Shishatskiy S, Rahman M M, Lillepaerg J, Abetz V. Journal of Membrane Science, 2013, 436: 109.
[52] Bushell A F, Attfield M P, Mason C R, Budd P M, Yampolskii Y, Starannikova L, Rebrov A, Bazzarelli F, Bernardo P, Carolus Jansen J. Journal of Membrane Science, 2012, 427: 48.
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