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Progress in Chemistry 2014, Vol. 26 Issue (0203): 424-435 DOI: 10.7536/PC130832 Previous Articles   Next Articles

• Review •

Synthesis of Core-Shell Metal-Organic Frameworks

Song Xiaokai*1, Zhou Yajing1, Li Liang*2   

  1. 1. Changzhou Entry-Exit Inspection and Quarantine Bureau, Changzhou 213003, China;
    2. School of Chemical and Environmental Engineering, Shanghai Institute of Technology, Shanghai 201418, China
  • Received: Revised: Online: Published:
  • Supported by:

    This work was supported by the Funding Scheme for Training Young Teachers in Shanghai Colleges (No.ZZyyy12006) and the Talented Faculty Funds of Shanghai Institute of Technology (No.YJ-2012-10)

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Core-shell metal-organic frameworks (MOFs) composed of MOFs as core (or shell) and another material, such as MOFs, carbon, inorganic compounds and organic polymers, as shell (or core), are a typical class of multifunctional MOFs composites. Because of the combination of the properties of core and shell materials, core-shell MOFs have better performances, such as increasing framework stability, selective separation and gas sorption, than the core or shell materials. Therefore, core-shell MOFs have high potentials for industrial applications. In this paper, the research progress of core-shell MOFs in recent years is reviewed. Synthesis methods and applications of variously structural core-shell MOFs, such as MOF@MOF, MOF@carbon, metal oxide@MOF, and polymer@MOF are introduced. Besides, the future development of core-shell MOFs is prospected.

Contents
1 Introduction
2 Synthesis methods and applications of variously structural core-shell MOFs
2.1 MOF@MOF
2.2 Core-shell structures of MOFs with carbon
2.3 Core-shell structures of MOFs with inorganic compounds
2.4 Core-shell structures of MOFs with organic polymers
3 Conclusion and outlook

Key words: metal-organic frameworks (MOFs), core-shell, composites, framework stability, selective separation

CLC Number: 

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