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• Review •

Applications of Transition Metallates in Catalysis

Wang Sasa1, Sun Hui2, Chen Shengjie1, You Hongxing1, Liu Ye* 1   

  1. 1. Shanghai Key Laboratory of Green Chemistry and Chemical Processes, East China Normal University, Shanghai 20006;
    2. Kunshan Research Institute of Chemical Co., Ltd, Kunshan 215337, China
  • Received: Revised: Online: Published:
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Transition metallates have attracted much attention as one important kind of transition metal containing catalysts with the advantages of low cost, commercial availability, less toxicity, and good stability. Metallate is the name given to any complex anion containing a metal ligated to several atoms or small groups. Typically, the metal will be one of the transition elements and the ligand will be oxygen (oxometallate: WO42-, PMo12O403-, etc.), other chalcogenide (thiometallate: MoS42-, etc.), or halogen (halometallate: PtCl62-, TiF62-, etc.). The properties of metallates can be controlled by transition metal substitution and the counter-cations alteration at molecular levels. However, most of the research on applications of metallates in catalysis is focused on oxometallates. In this review, besides oxometallates, the other kinds of transition metallates such as thiometallates, cyanometallates, and halometallates as the efficient catalysts in catalytic reactions are also summarized. Furthermore, the use of metallates in combination with ionic liquids is emphasized herein, which is regarded as a promising method to guarantee the recyclability of metallate catalysts. Contents
1 Introduction
2 Application of transition metallates in catalysis
2.1 Application of transition metallates as catalysts in oxidations
2.2 Application of transition metallates in acid catalyzed reactions
2.3 Application of transition metallates as catalysts in other reactions
3 Conclusion and outlook
Key words: metallates, oxometallates, halometallates, thiometallates, catalysis, ionic liquids

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