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Progress in Chemistry 2012, Vol. 24 Issue (07): 1353-1358 Previous Articles   Next Articles

• Review •

Self-Assembly of Rod-Coil Molecules with Poly(ethylene oxide) Chains and Phenylene Rods

Zhong Keli1,2, Chen Tie2, Jin Longyi2   

  1. 1. Food Safety Key Lab of Liaoning Province, Engineering and Technology Research Center of Food Preservation, Processing and Safety Control of Liaoning Province, College of Chemistry, Chemical Engineering and Food Safety, Bohai University, Jinzhou 121013, China;
    2. Key Laboratory for Organism Resources of the Changbai Mountain and Functional Molecules, Ministry of Education, Departent of Chemistry, College of Science, Yanbian University, Yanji, 133002,China
  • Received: Revised: Online: Published:
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The rod-coil molecules, containing the hydrophilic poly(ethylene oxide) (PEO) chains and multi-phenylene as a rod, are able to self-assemble into various supramolecular nanostructures in bulk and an aqueous solution, caused by strong π-π stacking of aromatic rod segments and microphase separation of rod and coil segments. One of the great fascinating research topics is the creation of supramolecular nano-objects to explore novel properties and functions of rod-coil molecules. The shapes of the rod block can dramatically influence on the fashion of molecular arrangement, self-organizing property and micro-structure of rod-coil molecular system. In this paper, the self-assembling behaviors of diverse rod-coil molecules are summarized including Y-shaped, T-shaped, O-shaped, K-shaped, n-shaped, propeller-like and dumbbell-like rods. Finally, the future research trend of this kind of rod-coil molecules is prospected. Contents
1 Introduction
2 Dumbbell-like molecule
3 K-shaped molecule
4 O-shaped molecule
5 T-shaped molecule
6 Propeller-like molecule
7 Y-shaped molecule
8 n-Shaped molecule
9 Outlook
Key words: rod-coil molecules, self-assembly, supramolecule, shape

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