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Progress in Chemistry 2010, Vol. 22 Issue (05): 796-802 Previous Articles   Next Articles

• Invited Article •

Applications of Supercritical Methanol in Chemical Reactions

Wang Lianyuan1; Xu Wenhao2; Yang Jichu2*   

  1. (1. Institute of Chemical Defence, Beijing 102205, China; 2. Department of Chemical Engineering, Tsinghua University, Beijing 100084, China)
  • Received: Revised: Online: Published:
  • Contact: Yang Jichu E-mail:yjc-dce@tsinghua.edu.cn
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One of the very promising and fast growing branches of green chemistry is the application of supercritical fluids for important chemical processes. Due to the unique properties of supercritical methanol, it has attracted much attention and widely used in the green chemical processes. In this paper, after the introduction of the properties of supercritical methanol, recent advances in chemical reactions, such as using supercritical methanol as both of reaction media and reactant for organic synthesis, biodiesel production, biomass transform and polymers decomposition, are reviewed. Details about these chemical reaction conditions and related results are presented. Finally, the outlook of supercritical methanol in the chemical synthesis based on methanol is also proposed.

Contents
1 Introduction
2 Properties of supercritical methanol
2.1 Critical properties of methanol
2.2 Ion-product constant
2.3 Hydrogen bonds
2.4 Electronegativity
2.5 Activated volume
2.6 As reaction medium and reactant
3 Chemical reactions in supercritical methanol
3.1 Organic synthesis
3.2 Biodiesel production
3.3 Transform of biomass
3.4 Decomposition of polymers
4 Conclusion

Key words: supercritical methanol, organic synthesis, biodiesel, biomass, polymers, decomposition

CLC Number: 

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