中文
Earlier issues
Announcement
More
Progress in Chemistry 2009, Vol. 21 Issue (10): 2053-2059 Previous Articles   Next Articles

• Review •

The Catalyst with the Superparamagnetic Nanoparticles as Its Supporter

Wang Zhifei1**; Yang Wen2; He Nongyue3   

  1.  (1. School of Chemistry and Chemical Engineering, Southeast University, Nanjing 211189, China; 2. Military Representation Office of Air Force in Hu-Ning District, Nanjing 210013, China; 3. State Key Laboratory of Bioelectronics, Southeast University, Nanjing 210096, China)
  • Received: Revised: Online: Published:
  • Contact: Wang Zhifei E-mail:zfwang@seu.edu.cn
  • Supported by:

    National Natural Science Foundation of China

PDF ( 1668 ) Cited
Export

EndNote

Ris

BibTeX

As far as the homogeneous catalyst or nano catalyst developed quickly in the past decade is concerned, it is one of the main research topics to find the new procedure to separate and recycle them out of the reaction mixture in combination with their preparation. Considering the above background, many related researches on the application of the superparamagnetic nanoparticle as the catalyst supporter have been conducted recently. Compared to their parent catalysts in solution, the magnetic nanoparticle-supported catalytic species not only allow facile seperation and recycling of the catalyst under the extern magnetic field, but also keep their previous dynamic performance such as high activity and selectivity due to the body size under the nano meter scale. In this paper, the preparation of the superparamagnetic particle as the catalyst supporter as well as the catalytic activity is reviewed, and the direction of the further research is suggested.

Contents
1 Introduction
2 Preparation of superparamagnetic nano supporter
2.1 Preparation of C/NiFe nanoparticle
2.2 Preparation of γ-Fe2O3、Fe3O4、NiFe2O3 nanoparticles and so on
2.3 Preparation of SiO2/Fe2O3 nanoparticle
2.4 Preparation of polymer/Fe2O3 nanoparticle
3 Preparation of catalyst and test of catalytic activity
3.1 Acid and base catalyst
3.2 Noble metal catalyst
3.3 Chiral catalyst
3.4 Transition metal coordination catalyst
3.5 Enzyme
3.6 Other catalysts
4 Conclusion and prospects

Key words: superparamagnetic, nanoparticle, catalyst supporter, separation and recycle

CLC Number: 

[ 1 ] 　Yin YD , Rioux R M, Erdonmez C K, et al . Science , 2004 , 304 :711 —713
[ 2 ] 　Bell A T. Science , 2003 , 299 : 1688 —1691
[ 3 ] 　Astruc D , Lu F , Aranzaes J R. Angew. Chem. Int . Ed. , 2005 ,44 : 7852 —7872
[ 4 ] 　Thomas J M, Johnson B F G, Raja R , et al . Acc. Chem. Res. ,2003 , 36 : 20 —32
[ 5 ] 　Manas MM, Pleixats R. Acc. Chem. Res. , 2003 , 36 : 638 —643
[ 6 ] 　Cole-Hamilton D J . Science , 2003 , 299 : 1702 —1706
[ 7 ] 　Grêschel L R , Haidar A , Beyer K H , et al . Catal . Lett . , 2004 ,95 : 67 —75
[ 8 ] 　Vos D E , Dams M, Sels B F , et al . Chem. Rev. , 2002 , 102 :3615 —3640
[ 9 ] 　Kidambi S , Dai J H , Lin J , et al . J . Am. Chem. Soc. , 2004 ,126 : 2658 —2659
[10 ] 　Teunissen W, Bol A A , Geus J W. Catal . Today , 1999 , 48 : 329 —336
[11 ] 　Heerbeek R V , Kamer P C J , Leeuwen P W N M, et al . Chem.Rev. , 2002 , 102 : 3717 —3756
[12 ] 　Teunissen W, Groot F M F , Geus J , et al . J . Catal . , 2001 , 204 :169 —174
[13 ] 　[2008-5-21 ]http://www.magneticmicrosphere.com/meetings/meet-2008
[14 ] 　Tartaj P , Carreno T G, Serna CJ . Adv. Mater. , 2001 , 13 : 1620 —1624
[15 ] 　Frenkel J , Dorfman J . Nature , 1930 , 126 : 274 —275
[16 ] 　Tsang S C , Caps V , Paraskevas I , et al . Angew. Chem. Int . Ed. ,2004 , 43 : 5645 —5649
[17 ] 　Baruwati B , Guin D , Manorama S V. Org. Lett . , 2007 , 26 :5377 —5380
[18 ] 　Kang Y S , Risbud S , Rabolt J F , et al . Chem. Mater. , 1996 , 8 :2209 —2211
[19 ] 　Sun S H , Zeng H , Robinson D B , et al . J . Am. Chem. Soc. ,2004 , 126 : 273 —279
[20 ] 　Bruce I J , Taylor J , Todd M, et al . J . Mag. Mag. Mater. , 2004 ,284 : 145 —160
[21 ] 　Yoon T J , Lee W, Oh Y S , et al . New J . Chem. , 2003 , 27 :227 —229
[22 ] 　Hu A G, Yee G T, Lin W B. J . Am. Chem. Soc. , 2005 , 127 :12486 —12487
[23 ] 　Stevens P D , Li G F , Fan J D , et al . Chem. Comm. , 2005 ,4435 —4437
[24 ] 　Guin D , Baruwati B , Manorama S V. Org. Lett . , 2007 , 7 : 1419 —1421
[25 ] 　Wang Z F , Shen B , Zou A H , et al . Chem. Eng. J . , 2005 , 113 :27 —34
[26 ] 　Duanmu C , Saha I , Zheng Y, et al . Chem. Mater. , 2006 , 18 :5973 —5981
[27 ] 　Dong K Y, Su SL , Jackie Y Y. Chem. Mater. , 2006 , 18 : 2459 —2461
[28 ] 　Wang Z F , Xiao P F , He N Y, et al . Colloids and Surf . A: Physicochem. Eng. Aspects , 2006 , 276 : 116 —121
[29 ] 　Lee J , Lee YJ , Youn J K, et al . Small , 2008 , 4 : 143 —152
[30 ] 　Ge J P , Huynh T, Hu Y X, et al . Nano Lett . , 2008 , 8 : 931 —934
[31 ] 　Shokouhimehr M, Piao Y Z, Kim J , et al . Angew. Chem. Int .Ed. , 2007 , 46 : 7039 —7043
[32 ] 　Stevens P D , Fan J D , Gardimalla HM R , et al . Org. Lett . , 2005 ,7 : 2085 —2088
[33 ] 　Ko S , Jang J . Angew. Chem. Int . Ed. , 2006 , 45 : 7564 —7567
[34 ] 　Zhu Y H , Ship C P , Emi A , et al . Adv. Synth. Catal . , 2007 ,349 : 1917 —1922
[35 ] 　张冠东(Zhang G D) , 官月平( Guan Y P) , 单国彬(Shan G B)等. 过程工程学报(The Chinese Journal of Process Engineering) ,2002 , 2 : 319 —324
[36 ] 　张冠东(Zhang G D) , 单国彬(Shan G B) , 孟祥昆(Meng X K)等. 催化学报(Chinese Journal of Catalysis) , 2003 , 24 (11) :839 —844
[37 ] 　Kwon M S , Park I S , Jang J S , et al . Org. Lett . , 2007 , 17 :3417 —3419
[38 ] 　Mori K, Kanai S , Hara T, et al . Chem. Mater. , 2007 , 19 : 1249 —1256
[39 ] 　Lu A H , Schmidt W, Matoussevitch N , et al . Angew. Chem. Int .Ed. , 2004 , 43 : 4303 —4306
[40 ] 　Luo S Z, Zheng X X, Xu H , et al . Adv. Synth. Catal . , 2007 ,349 : 2431 —2434
[41 ] 　Phan N T S , Jones C W. J . Mol . Catal . A: Chem. , 2006 , 253 :123 —131
[42 ] 　Phan N T S , Gill C S , Nguyen J V , et al . Angew. Chem. Int .Ed. , 2006 , 45 : 2209 —2212
[43 ] 　Dalaigh C O , Corr S A , Ko Y G, et al . Angew. Chem. Int . Ed. ,2007 , 46 : 4329 —4332
[44 ] 　Wang J , Yang P P , Fan M Q , et al . Mater. Lett . , 2007 , 61 :2235 —2238
[45 ] 　Abu-Reziq R , Wang D S , Post M, et al . Adv. Synth. Catal . ,2007 , 349 : 2145 —2150
[46 ] 　Yoon H , Ko S , Jang J . Chem. Comm. , 2007 , 1468 —1470
[47 ] 　Liu J , Peng X, Sun W, et al . Org. Lett . , 2008 , 10 : 3933 —3036
[48 ] 　Kotani M, Koike T, Yamaguchi K, et al . Green Chem. , 2006 , 8 :735 —741
[49 ] 　Luo S Z, Zheng X X, Cheng J P. Chem. Comm. , 2008 , 5719 —5721
[50 ] 　Rtu-Reid R , Alper H , Wang D S , et al . J . Am. Chem. Soc. ,2006 , 128 : 5279 —5282
[51 ] 　Ding S , Xing Y, Radosz M, et al . Macromolecules , 2006 , 39 :6399 —6405
[52 ] 　Chouhan G, Wang D , Alper H. Chem. Comm. , 2007 , 4809 —4811
[53 ] 　Yang H H , Zhang S Q , Chen X L , et al . Anal . Chem. , 2004 , 76 :1316 —1321
[54 ] 　Gardimalla HM R , Mandal D , Stevens P D , et al . Chem. Comm. ,2005 , 4432 —4434
[55 ] 　Schêtz A , Grass R N , Stark W J , et al . Chem. Eur. J . , 2008 , 14 :8262 —8266
[56 ] 　Zheng Y, Duanmu C , Gao Y. Org. Lett . , 2006 , 8 : 3215 —3217
[57 ] 　Kawamura M, Sato K. Chem. Comm. , 2006 , 4718 —4719
[58 ] 　Kawamura M, Sato K. Chem. Comm. , 2007 , 3404 —3405
[59 ] 　Shi F , Tse M K, Pohl MM, et al . Angew. Chem. Int . Ed. , 2007 ,46 : 4329 —4332
[60 ] 　Guin D , Baruwati B , Manorama S V. J . Mol . Catal . A: Chem. ,2005 , 242 : 26 —31
[61 ] 　Martnez R , Raman D J , Yusa M. Adv. Synth. Catal . , 2008 , 350 :1235 —1240
[1] Chunyi Ye, Yang Yang, Xuexian Wu, Ping Ding, Jingli Luo, Xianzhu Fu. Preparation and Application of Palladium-Copper Nano Electrocatalysts [J]. Progress in Chemistry, 2022, 34(9): 1896-1910.
[2] Hao Chen, Xu Xu, Chaonan Jiao, Hao Yang, Jing Wang, Yinxian Peng. Fabrication of Multifunctional Core-Shell Structured Nanoreactors and Their Catalytic Performances [J]. Progress in Chemistry, 2022, 34(9): 1911-1934.
[3] Feng Lu, Ting Zhao, Xiaojun Sun, Quli Fan, Wei Huang. Design of NIR-Ⅱ Emissive Rare-earth Nanoparticles and Their Applications for Bio-imaging [J]. Progress in Chemistry, 2022, 34(6): 1348-1358.
[4] Qin Zhong, Shuai Zhou, Xiangmei Wang, Wei Zhong, Chendi Ding, Jiajun Fu. Construction of Mesoporous Silica Based Smart Delivery System and its Therapeutic Application in Various Diseases [J]. Progress in Chemistry, 2022, 34(3): 696-716.
[5] Dandan Zhang, Qi Wu, Guangbo Qu, Jianbo Shi, Guibin Jiang. Quantitative Analysis of Metal Nanoparticles in Unicellular Aquatic Organisms [J]. Progress in Chemistry, 2022, 34(11): 2331-2339.
[6] Dong Yang, Keyi Gao, Baiqin Yang, Lei Lei, Lixia Wang, Chaohua Xue. Classification of Microfluidic System and Applications in Nanoparticles Synthesis [J]. Progress in Chemistry, 2021, 33(3): 368-379.
[7] Pingping Zhao, Junxing Yang, Jianhui Shi, Jingyi Zhu. Construction and Application of Dendrimer-Based SPECT Imaging Agent [J]. Progress in Chemistry, 2021, 33(3): 394-405.
[8] Chen Liu, Qiangxiang Li, Di Zhang, Yujie Li, Jinquan Liu, Xilin Xiao. Preparation and Application of MCM-41 Mesoporous Silica in the DNA Biosensors [J]. Progress in Chemistry, 2021, 33(11): 2085-2102.
[9] Ding Jingjing, Lili Huang, Haiyan Xie. Application of Nanoparticles-Based Chemiluminescence in Diagnosis and Treatment of Inflammation and Tumor [J]. Progress in Chemistry, 2020, 32(9): 1252-1263.
[10] Miao Qin, Mengjie Xu, Di Huang, Yan Wei, Yanfeng Meng, Weiyi Chen. Iron Oxide Nanoparticles in the Application of Magnetic Resonance Imaging [J]. Progress in Chemistry, 2020, 32(9): 1264-1273.
[11] Jianlin Shi, Zile Hua. Condensed State Chemistry in the Synthesis of Inorganic Nano- and Porous Materials [J]. Progress in Chemistry, 2020, 32(8): 1060-1075.
[12] Tianyou Chen, Zihao Wang, Zizheng Xu, Zushun Xu, Zheng Cao. Synthesis and Applications of Dendrimer-Based Inorganic Nanoparticles [J]. Progress in Chemistry, 2020, 32(2/3): 249-261.
[13] Rui Bai, Xiaochun Tian, Shuhua Wang, Weifu Yan, Haiyin Gang, Yong Xiao. Noble Metal Nanoparticles Produced by Microorganism [J]. Progress in Chemistry, 2019, 31(6): 872-881.
[14] Xinyi Lai, Zhiyong Wang, Yongtai Zheng, Yongming Chen. Nanoscale Metal Organic Frameworks for Drug Delivery [J]. Progress in Chemistry, 2019, 31(6): 783-790.
[15] Lingli Zhou, Ruigang Xie, Linjiang Wang. Application of Layered Double Hydroxides in Electrocatalysis [J]. Progress in Chemistry, 2019, 31(2/3): 275-282.