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Progress in Chemistry 2009, Vol. 21 Issue (10): 2067-2076 Previous Articles   Next Articles

• Review •

The Combined Adsorption-Photocatalysis for the Removal of Indoor Volatile Organic Compounds

Sun Jian;  Li Xiaohui;  Liu Shouxin*   

  1. （Key Laboratory of Biological Materials of Ministry of Education, Northeast Forestry University, Harbin 150040, China）
  • Received: Revised: Online: Published:
  • Contact: Liu Shouxin E-mail:liushouxin@126.com
  • Supported by:

    National Natural Science Foundation of China

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Adsorption and TiO2 photocatalysis are widely used for the removal of indoor volatile organic compounds (VOCs). However, due to the limited adsorption capacity, saturated absorbent needs further regeneration or be replaced. In addition, the problems of low activity, deactivation and separation for TiO2 photocatalysis restrict its large scale application.For the combined adsorption-photocatalysis composite, TiO2 photocatalysis can realize in-situ regeneration of adsorbent then improve its adsorption capacity. Adsorbent can provide high organic concentration environment for loaded TiO2 photocatalyst, improve photocatalytic activity and retard catalyst deactivation, inhibite the competition adsorption of H2O for active sites. In this paper, recent progress of the combined adsorption-photocatalysis for the removal of indoor VOCs was reviewed. Type of adsorbents, methods of composite preparation and reactors were introduced. Effect of the combination of adsorption and photocatalysis on the structure and photocatalytic properties of TiO2 include surface characteristics, activity and deactivation were systematically investigated.

Contents
1 Introduction
2 Type of adsorbents
2.1 Zeolite
2.2 Activated Carbon
2.3 Silica
2.4 Activated Carbon Fiber
2.5 Carbon nanotubes
3 Effect of the combined adsorption-photocatalysis on the structure and photocatalytic activities of photocatalyst
3.1 Effect of the combined adsorption-photocatalysis on the surface area and interface
3.2 Effect of combined adsorption-photocatalysis on mass transfer
3.3 Effect of combined adsorption-photocatalysis on surface pH
3.4 Effect of the combined adsorption-photocatalysis on the deactivation
3.5 Effect of the combined adsorption-photocatalysis on the side effects of steam
4 The methods of composite preparation
4.1 Physical method
4.2 Chemical method
5 Reactor of the combined adsorption-photocatalysis process
6 Conclusions

Key words: adsorption, titanium dioxide photocatalysis, combined, volatile organic compounds(VOCs)

CLC Number: 

[ 1 ] 　US EPA , Characterizing air emission from indoor sources , EPA report : EPA/600/F-95/005 , US Environmental Protection Agency ,Washington DC ,1995
[ 2 ] 　Hong J G, Manguhn J , Freitag D , et al . Fresen. J . Anal . Chem. ,2001 , 371 : 961 —965
[ 3 ] 　Jutta B , Erich J , Türkan K, et al . Fresen. J . Anal . Chem. , 1999 ,363 : 399 —403
[ 4 ] 　Cornejo J J , Munoz F G, Ma C Y, et al . Ecotoxicology. , 1999 , 8 :311 —320
[ 5 ] 　Brown V M, Crump D R. Environ. Monit . Assess. , 1998 , 52 :43 —55
[ 6 ] 　Cárdenas L M, Brassington DJ , Allan B J , et al . J . Atmos Chem. ,2000 , 37 : 53 —80
[ 7 ] 　Ao C H , Lee S C. Chem. Eng. Sci . , 2005 , 60 (1) : 103 —109
[ 8 ] 　Rosana M A , Wilson F J . Appl . Catal . B : Environ. , 1997 , 14 (1/2) : 55 —68
[ 9 ] 　刘守新(Liu S X) , 刘鸿(Liu H) . 光催化及光电催化基础与应用(Basic and application of photocatalytic and photoelectrocatalytic) .北京: 化学工业出版社(Beijing : Chemical Industry Press) ,2006. 56 —57
[10 ] 　Liu H , Li X Z. J . Phys. Chem. B , 2003 , 107 : 8988 —8996
[11 ] 　Wang C , Zhang X H , Liu H , et al . J . Hazard. Mater. 2009 , 163 :1101 —1106
[12 ] 　Li X Z, Liu H. Environ. Sci . Technol . , 2003 , 37 : 3989 —3994
[13 ] 　Andrew M, Stephen L H. J . Photochem. Photobio A: Chem. ,1997 , 108 (1) : 1 —3
[14 ] 　Yoneyama H. J . Phys. Chem. , 1995 , 99 (21) : 9986 —9991
[15 ] 　Yoneyama H. Eviron. Sci . Technol . , 1996 , 30 (11) : 1275 —1281
[16 ] 　Takashi I. J . Mole. Catal . , 1994 , 88 (1) : 93 —102
[17 ] 　Tsukasa T, Norihiko T, Yoneyama H. J . Photobio. Photochem. A: Chem. , 1997 , 103 (3) : 153 —157
[18 ] 　Ollis D , ElAkabi H (eds. ) . The First Photo-catalysis International Conference. New York : Elsevier , 1993. 583 —585
[19 ] 　Suzuki M. JP 155125/96 , 1996
[20 ] 　Chiyoda K. EP 0725036A1 , 1996
[21 ] 　Yoneyama H , Okawa Y, Takenda N. J . Catal . , 1998 , 177 (2) :240 —246
[22 ] 　Srinivasan S , Yoneyama H. J . Catal . , 1994 , 149 (2) : 189 —194
[23 ] 　Monneyron P , Manero M H , Foussard J N , et al . Chem. Eng.Sci . , 2003 , 58 : 971 —978
[24 ] 　Teruaki H , Keiichi T. J . Hazard. Mater. B , 2002 , 93 : 331 —337
[25 ] 　Ichiura H , Kitaoka T, Tanaka H. Chemosphere. , 2003 , 50 : 79 —83
[26 ] 　蒋引珊(Jiang Y S) , 金为群(Jin W Q) , 张军(Zhang J ) . 无机材料学报(Journal of Inorganic Materials) , 2002 , 17 (6) : 1301 —1305
[27 ] 　陈孝云(Chen X Y) , 刘守新(Liu S X) , 陈曦(Chen X) . 物理化学学报(Acta Physico-Chimica Sinica) , 2006 , 22 (5) : 517 —522
[28 ] 　Cordero T, Chovelon J M, Duchamp C , et al . J . Appl . Catal . B :Environ. , 2007 , 73 : 227 —235
[29 ] 　Cordero T, Duchamp C , Chovelon J M, et al . J . Photochem.hotobio. A: Chem. , 2007 , 191 : 122 —131
[30 ] 　黄雯(Huang W) , 杨家宽(Yang J K) , 范双艳(Fan S Y) . 工业催化( Industrial Catalysis) , 2007 , 15 (10) : 55 —59
[31 ] 　孙和芳(Sun H F) , 张国栋(Zhang G D) , 郑光宇(Zheng G Y) .安徽工业大学学报(Journal of Anhui Industry University) , 2007 ,24 (1) : 39 —42
[32 ] 　耿晓云(Geng X Y) , 任宝山(Ren B S) , 杨贵荣(Yang G R) . 钛工业进展(Titanium Industry Progress) , 2006 , 23 (4) : 35 —36
[33 ] 　黄彪(Huang B) , 陈学榕(Chen X R) , 江茂生(Jiang M S) . 林产化学与工业(Chemistry and Industry of Forest Products) , 2005 , 25(3) : 38 —42.
[34 ] 　刘守新(Liu S X) , 陈曦(Chen X) . 催化学报(Chinese Journal of Catalysis) , 2008 , 29 (1) : 19 —24
[35 ] 　胡春(Hu C) , 王怡中(Wang Y Z) , 汤鸿霄(Tang H X) . 催化学报(Chinese Journal of Catalysis) , 2001 , 22 (2) : 185 —188
[36 ] 　杨骏(Yang J ) , 朱利伟(Zhu L W) , 唐渝(Tang Y) . 化学研究与应用(Chemical Research and Application) , 2008 , 20(6) : 714 —718
[37 ] 　Zou L D , Luo Y G, Hooper M M, et al . Chem. Engin. Proce. ,2006 , 45 : 959 —964
[38 ] 　于竹芹(Yu Z Q) , 李坚(Li J ) , 金毓　(Jin Y Q) . 工业催化( Industrial Catalysis) , 2008 , 16 (7) : 71 —74
[39 ] 　侯一宁(Hou Y N) , 王安(Wang A) , 王燕(Wang Y) . 四川大学学报(Journal of Sichuan University) , 2004 , 36 (4) : 41 —44
[40 ] 　梁世强(Liang S Q) , 穆筱梅(Mu X M) , 葛建芳(Ge J F) . 精细化工(Fine Chemicals) , 2006 , 23 (5) : 44 —47
[41 ] 　胡俊生(Hu J S) , 徐文涛(Xu W T) , 黄宽(Huang K) . 辽宁化工(Liaoning Chemical Industry) , 2008 , 37 (7) : 453 —456
[42 ] 　胡将军(Hu J J ) , 李英柳(Li YL) , 彭卫华(Peng W H) . 化学与生物工程(Chemistry Bioengineering) , 2004 , 1 : 39 —41
[43 ] 　詹雪艳( Zhan X Y) , 宋丹丹( Song D D) . 化学研究与应用(Chemical Research and Application) , 2003 , 15 (4) : 471 —474
[44 ] 　Gao B , Peng C , Chen G Z, et al . Appl . Catal . B : Environ. ,2008 , 85 : 17 —23
[45 ] 　吴玉程(Wu Y C) , 刘晓璐(Liu X L) , 叶敏( Ye M) . 物理化学学报(Acta Physico2Chimica Sinica) , 2008 , 24 (1) : 97 —102
[46 ] 　Matos J , Laine J , Herrmann J M, et al . Journal of Catalysis , 2001 ,200 : 10 —20
[47 ] 　王勇(Wang Y) , 张军(Zhang J ) , 杨青林(Yang Q L) . 材料导报(Materials Review) , 2006 , 20 : 68 —82
[48 ] 　陆银兰(Lu YL) , 杨建忠(Yang J Z ) . 广西纺织科技( Guangxi Textile Science and Technology) , 2004 , 33 : 35 —37
[49 ] 　Araìa J . Appl . Catal . B : Environ. , 2003 , 44 : 161 —172
[50 ] 　Einage H , Futamura S , Ibusuki T. Appl . Catal . B : Environ. ,2002 , 38 (3) : 215 —225
[51 ] 　张前程(Zhang Q C) , 张凤宝(Zhang F B) , 张国亮(Zhang GL) .催化学报(Chinese Journal of Catalysis) , 2004 , 25 (1) : 39 —43
[52 ] 　Jardim W F , Alberici R M. Appl . Catal . B : Environ. , 1997 , 14(1) : 55 —68
[53 ] 　Augugliaro V , Coluccia S , LoddoV , et al . Appl . Catal . B :Environ. , 1999 , 20 (1) : 15 —27
[54 ] 　Rafael M R , Nelson C M. Catal . Today , 1998 , 40 (4) : 353 —365
[55 ] 　Cao L , Gao Z, Suib S L , et al . J . Catal . , 2000 , 196 (2) : 253 —261
[56 ] 　刘守新(Liu S X) , 刘正峰(Liu Z F) . 无机化学学报(Journal of Inorganic Chemistry) , 2009 , 24 (2) : 209 —214
[57 ] 　Araìa J , Doìa RJ M, Cabo C G, et al . Appl . Catal . B : Environ. ,2004 , 53 : 221 —232
[58 ] 　Ameen MM, Raupp GB. J . Catal . , 1999 , 184 (1) : 112 —122
[59 ] 　曾志雄( Zheng Z X) , 徐玉党( Xu Y D) . 制冷与空调(Refrigeration And Air-Conditioning) , 2003 , 4 : 36 —39
[60 ] 　张彭义(Zhang P Y) , 梁夫艳(Liang F Y) , 陈清(Chen Q) . 环境科学(Environmental Science) , 2003 , 24 (6) : 54 —58
[61 ] 　孙如宝(Sun R B) , 袭著革(Xi Z G) . 解放军预防医学杂志(Journal of Preventive Medicine Chinese PLA) , 2005 , 23 ( 6 ) :457 —459
[62 ] 　Philips L A , Raupp GB. J . Mole. Catal . , 1992 , 3 : 297 —311
[63 ] 　Ao C H , Lee S C. Appl . Catal . B : Environ. , 2003 , 44 : 191 —205
[64 ] 　Ao C H , Lee S C. J . Photochem. Photobio. A: Chem. , 2004 ,161 : 131 —140
[65 ] 　贺飞(He F) , 唐怀军(Tang HJ ) , 赵文宽(Zhao W K) . 环境污染治理技术与设备(Techniques and Equipment for Environmental Pollution Control) , 2001 , 2 (2) : 47 —58
[66 ] 　Yuan R S , Guan R B , Shen W Z, et al . J . Colloid. Interf . Sci . ,2005 , 282 : 87 —91
[67 ] 　李发堂(Li F T) , 赵地顺( Zhao D S) . 材料导报(Materials Review) , 2006 , 20 : 64 —66
[68 ] 　Waldner G, Pourmodji M, Bauer MM, et al . Chemosphere. , 2003 ,50 (8) : 989 —998
[69 ] 　赵文宽(Zhao W K) , 周磊(Zhou L) , 刘昌(Liu C) . 化学学报(Acta Chimica Sinica) , 2003 , 61 (5) : 699 —704
[70 ] 　张万忠(Zhang W Z) , 乔学亮(Qiao X L) , 陈建国(Chen J G) .化学通报(Chemistry) , 2005 , 11 : 839 —844
[71 ] 　胡昌义(Hu C Y) , 李靖华(Li J H) . 稀有金属(Chinese Journal of Rare Metals) , 2001 , 25 (5) : 364 —367
[72 ] 　范金山(Fan J S) . 人工晶体学报(Journal of Synthetic Crystals) ,2006 , 35 (2) : 347 —350
[73 ] 　文桂林(Wen G L) , 高原(Gao Y) , 刘惠涛(Liu H T) . 环境科学与技术( Environmental Science and Technology) , 2006 , 29 (9) :19 —21
[74 ] 　任成军(Ren C J ) , 钟本和(Zhong B H) , 周大利(Zhou D L) . 稀有金属(Chinese Journal of Rare Metals) , 2004 , 28 (5) : 903 —906
[75 ] 　Durgakumari V , SubrahmanyamM, Subba KV , et al . Appl . Catal .A: General . , 2002 , 234 : 155 —165
[76 ] 　Leung M K H , Tang SM, Lam R C W, et al . Solar Energy , 2006 ,80 : 949 —955
[77 ] 　Vincent G, Marquaire GM, Zahraa O. J . Photochem. Photobio. A:Chem. , 2008 , 197 : 177 —189
[78 ] 　陈爱平(Chen A P) , 古宏晨( Gu H C) , 戴智铭(Dai Z M) . CN 99115885. 2 ,1999
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