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Progress in Chemistry 2009, Vol. 21 Issue (09): 1734-1741 Previous Articles   Next Articles

• Review •

Bismuth Oxyhalide Compounds as Photocatalysts

Wei Pingyu;   Yang Qinglin** ;  Guo Lin   

  1. (School of Chemistry and Environment, Beijing University of Aeronautics and Astronautics, 100191 Beijing, China)
  • Received: Revised: Online: Published:
  • Contact: Yang Qinglin E-mail:yangql@buaa.edu.cn
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Bismuth Oxyhalide Compounds, BiOX (X=Cl, Br, I) are new types of photocatalysts. They exhibit excellent photocatalytic properties due to layered crystal structure and suitable band gaps. In this paper, main preparation methods, morphologies, sizes and photocatalytic activities of micro-nanometer bismuth oxyhalides are reviewed. Bismuth oxyhalide compounds show better photocatalytic activities than TiO2 (P25). With the increasing of X atomic numbers, photocatalytic activities of BiOX are enhanced in sequence. Moreover, the stabilities of BiOX are high. Photocatalytic activities of bismuth oxyhalide compounds are improved by doping and modifications. By designing of the crystal structures and energy band gaps, highly efficient photocatalysts of bismuth oxyhalide compounds can be obtained. At last, the trend of research is prospected.

Contents
1 Introduction
2 Structure of BiOX (X=Cl, Br, I)
3 Preparation methods and morphologies of BiOX (X=Cl, Br, I)
3.1 Preparation methods
3.2 Morphologies of products
4 Photocatalytic activities of BiOX (X=Cl, Br, I)
4.1 BiOCl photocatalyst
4.2 BiOBr and BiOI photocatalysts
4.3 Other Bi based oxyhalides
5 Conclusion

Key words: bismuth oxyhalides, photocatalyst, preparation, photocatalytic activity

CLC Number: 

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