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Progress in Chemistry 2009, Vol. 21 Issue (04): 622-628 Previous Articles   Next Articles

• Review •

Effects of Noble Metal Promoter on Supported Cobalt-Based Fischer-Tropsch Catalysts

Zhang Hui;  Chu Wei **   

  1. (Department of Chemical Engineering, Sichuan University, Chengdu 610065, China)
  • Received: Revised: Online: Published:
  • Contact: Chu Wei E-mail:chuwei65@yahoo.com.cn
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Being of high activity and good selectivity in C5+ hydrocarbons, noble metal promoted cobalt Fischer-Tropsch catalysts are widely utilized in carbon monoxide hydrogenation to clean fuels or long chain hydrocarbons. The effects of noble metal promoter on the structure of Co active species are reviewed and discussed in this paper, as well as the reducibility, dispersion, the formation of bimetallic particles or alloy, and the influences on their catalytic performances.

Contents
1 Introduction
2 Effects of noble metal promoter on supported cobalt catalysts
2.1 Reducibility of FT cobalt catalysts promoted by noble metal
2.2 Dispersion of noble metal promoted nano-cobalt catalysts
2.3 Formation and effects of bimetallic cobalt-noble metal FT catalysts
3 Effects of noble metal on the deactivation behaviors of promoted FT cobalt catalysts
4 Effects of noble metal addition on the Fischer-Tropsch performances and product distribution
5 Summary

Key words: Fischer-Tropsch synthesis, cobalt catalysts, noble metal promoters, reducibility, dispersion

CLC Number: 

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