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Characteristics and Formation Mechanisms of Atmospheric Organosulfates

Ma Ye1, Chen Jianmin1, Wang Lin1,2**   

  1. 1. Department of Environmental Science & Engineering, Fudan University, Shanghai 200433, China;
    2. Jiangsu Key Laboratory of Atmospheric Environment Monitoring and Pollution Control, Nanjing University of Information Science & Technology, Nanjing 210044, China
  • Received: Revised: Online: Published:
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Atmospheric organosulfates refer to sulfate esters and their derivatives that have been identified in ambient secondary organic aerosol(SOA) samples. Recent laboratory and field studies show that organosulfates are derived from the reactions of particulate sulfates or sulfuric acid with compounds formed from hydroxyl radical(OH)/nitrate radical(NO3)/ozone(O3)-initiated reactions of isoprene, α-/β-pinene, and other monoterpenes and sesquiterpenes. Organosulfates can also be formed through reactive uptake of carbonyls such as glyoxal by particulate sulfates or sulfuric acid. Enhanced acidity of the sulfate seed particles favors the production of organosulfate. Hydrolysis of organosulfates is slow unless in a highly acidic solution. Offline electrospray ionization mass spectrometry(ESI-MS) and online aerosol mass spectrometry(AMS) are useful methods to detect atmospheric organosulfates. Contents
1 Introduction
2 Identification of atmospheric organosulfates
2.1 Organosulfates observed in the atmosphere
2.2 Temporal profiles of organosulfates
3 Laboratory studies of organosulfates
3.1 Organosulfates derived from isoprene
3.2 Organosulfates derived from α-/β-pinene
3.3 Organosulfates derived from other monoterpenes and sesquiterpenes
3.4 Organosulfates formation via reactive uptake of carbonyls
3.5 Hydrolysis of organosulfates and organonitrates
4 Analytical methods of organosulfates
5 Outlook
Key words: organosulfates, formation mechanism, secondary organic aerosol(SOA)

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