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Ion Sensor Based on Fluorous Liquid Phase Sensing Membrane with High Selectivity

Huang Meirong1, Ding Yongbo1, Shi Fengying2, Li Xingui1*   

  1. 1. Institute of Materials Chemistry, Key Laboratory of Advanced Civil Engineering Materials of the Ministry of Education, College of Materials Science and Engineering, Tongji University, Shanghai 20009;
    2. Architectural Engineering College, Shanghai Normal University,Shanghai, 201418, China
  • Received: Revised: Online: Published:
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New fluorous liquid sensing membranes for the fabrication of potentiometric sensors are systematically summarized based on the latest literatures. Fluorous solvents, fluorophilic ion-exchangers and fluorophilic ionophores doped in the fluorous solvents, as well as inert fluorous porous supports, are reviewed thoroughly. The influence of the four factors on the performance of potentiometric sensors is concentrated. It is pointed out that both the fluorophilic ion-exchangers and ionophores used so far contain 2—8 perfluoroalkyl chains which are composed of 6—10 carbon atoms in each chain. Such a fluorous liquid phase sensing membrane possesses a superior lower detection limit compared with conventional poly(vinyl chloride)(PVC) membranes. For Ag(Ⅰ) potentiometric sensor based on the fluorous liquid membrane with solid contact through three-dimensionally ordered macroporous (3DOM) carbon, the lower detection limit can achieve 3.8×10-11 mol/L. Moreover, the potentiometric sensors based on the fluorous membranes demonstrate excellent selectivity. Logarithmic selectivity coefficient log Ki,Jpot of a blank fluorous membrane without ionophore spans a remarkably wide range of more than 16—18 orders of magnitude, which is 8 orders of magnitude wider than that of conventional PVC membrane without ionophore. The unique new potentiometric sensors based on fluorous liquid phase sensing membranes could play an important role in many areas such as environmental monitoring, food safety, especially in medical diagnosis and detection for biomaterials. Contents
1 Introduction
2 Fluorous liquid phase sensing membrane
2.1 Fluorous solvent
2.2 Fluorophilic ion-exchanger
2.3 Fluorophilic ionophore
3 Inert fluorous porous support membrane
4 Performance of fluorous membrane
4.1 Low detection limit
4.2 High selectivity
4.3 Strong ability of anti-contamination
5 Outlook
Key words: fluorous liquid phase, sensing membrane, selectivity, potentiometric sensor, ion selective electrode

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