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• Review •

Adsorption of Heavy Metal Ions by Chitosan and Its Derivatives

Hu Huiyuan, Zhu Hong   

  1. College of Chemistry and Chemical Engineering, Shenzhen University, Shenzhen 518060, China
  • Received: Revised: Online: Published:
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The structure of chitosan has abundent —NH2 and —OH, so it has good adsorption ability for heavy metal ions. As a kind of natural polymer, the adsorption properties of chitosan are affected by its physical form, the source of the raw materials, the degree of deacetylation and the pH value of the system. Therefore, to improve the adsorption properties and to expand its application range, it is an essential method to modify its physical and chemical properties of the natural chitosan. This paper reviews the progress in the modification methods of the chitosan and the adsorption behavior of its derivatives to the heavy metal ions. The future perspectives of the chitosan derivatives used in the treatment of heavy metal contaminated water is also discussed. Contents
1 Introduction
2 Physical modification of chitosan
3 Chemical modification of chitosan
3.1 Active groups modified chitosan
3.2 Crosslinked chitosan
3.3 Graft polymerization of chitosan
3.4 Molecular imprinted chitosan
3.5 Magnetic chitosan
3.6 Special modification method of chitosan
4 Chitosan composites
5 Adsorption mechanisms
5.1 Adsorption isotherms
5.2 Adsorption kinetics
5.3 Adsorption thermodynamics
6 Conclusion and outlook
Key words: chitosan, chitosan derivatives, metal ions, adsorption

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