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Fabrication, Formation Mechanisms and Potential Applications of Magnetic Metal Nanotubes

Li Xiangzi1,2, Wei Xianwen1*   

  1. 1. College of Chemistry and Materials Science, Anhui Key Laboratory of Functional Molecular Solids, Anhui Normal University, Wuhu 241000, China;
    2. Department of Chemistry, Wannan Medical College, Wuhu 241002, China) Abstract Magnetic metal nanotubes (MMNTs
  • Received: Revised: Online: Published:
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Magnetic metal nanotubes (MMNTs) have novel hollow structures with inner and outer active surface and special properties of catalysis, magnetism and easier modification, which gradually become an important sort of one-dimension functional nanomaterials. MMNTs exhibit potential applications in the fields of molecular devices, magnetic materials, biomedicine, etc, and have drawn wide attention during last decade. In this paper, the main strategies for fabricating MMNTs via hard templates have been summarized, including electrodeposition, chemical deposition, template wetting, atomic layer deposition and hydrothermal processing technology. The special fabricating technologies for MMNTs based on hard-template, such as channels chemical modification, multistep template replication, high current, mercury cathode, precursor, sensitization, activation and other processing parameters, etc. are emphasized. Simultaneously, a formation mechanism for fabricating MMNTs via hard templates has been established, which contains three main aspects: substrates properties, nucleation environments and growth environments. The formation mechanisms of MMNTs under the different fabricating strategies, such as high-current-assisted-annular-substrate tubular growth, current-directed tubular growth, gas assistant tubular growth and so on, have been compared. Moreover, some other factors including the hydration layer, the mobilities of metal ions, the complexation of metal ions and current modes, also play important roles in the formation of nanotubes. Finally, the magnetic properties, the potential applications, and developing trends of MMNTs are discussed in brief. Contents
1 Introduction
2 Fabrication strategies of the magnetic metal nanotubes(MMNTs)
2.1 Hard-template-based technologies
2.2 Solution phase synthesize with soft template assistance
3 Formation mechanisms for fabrication MMNTs via hard templates
3.1 Substrates
3.2 Nucleation environments
3.3 Growth environments
4 Properties and potential applications of MMNTs
4.1 Magnetic properties
4.2 Biological applications
5 Outlooks
Key words: magnetic metal nanotubes, formation mechanisms, hard templates

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