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Improvement of Lower Detection Limit of Ion-Selective Electrodes Based on PVC Membrane

Huang Meirong, Ding Yongbo, Li Xingui   

  1. Institute of Materials Chemistry, Key Laboratory of Advanced Civil Engineering Materials of the Ministry of Education, College of Materials Science and Engineering, Tongji University, Shanghai 200092, China
  • Received: Revised: Online: Published:
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Ion-selective electrodes (ISEs) based on polymeric membranes are characterized by small size, portability, low-energy consumption, and low cost, which are attractive features concerning practical applications. However, the lower detection limit is biased by the ion flux through PVC membrane, which limits the further development of ion-selective electrode. Therefore, the principles and attractive strategies to suppress such an ion flux to improve the lower detection limit of PVC membrane-based ion-selective electrodes are elaborated in this article. According to large amounts of data collected, the improvement of the detection limit via optimization of sensing membrane composition, electrode assembly and conditioning, electrode rotation, as well as current-polarized treatment, is quantitatively discussed. Furthermore, the modification regulations for expanding the lower detection limit are systematically summarized. The significant superiority and problems are analyzed. It is pointed out that we have to break the conventional PVC composition formulation via reducing the dosages of plasticizer and ion exchanger in order to largely depress the transmembrane ion flux. External-current application to the electrode is also an effective approach, among which, the best improvement for the lower detection limit can reach up to 5 orders of magnitude. This review reveals the future direction for developing the PVC membrane-based ion-selective electrodes with high performance. Contents 1 Introduction
2 Composition optimization of sensing membrane
2.1 Dosage decrease of plasticizer
2.2 Dosage optimization of ionophore
2.3 Dosage decrease of ion exchanger
2.4 Incorporation of lipophilic silica gel microparticle
3 Thickness increase of sensing membrane
4 Optimization of condition solution
5 Agitating sample solution or rotating electrode
6 Application of external current
7 Conclusion and outlook
Key words: PVC sensing membrane, ion-selective electrode, sensor, lower detection limit, improvement

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[1] Huang M R, Ma X L, Li X G. Chin. Sci. Bull., 2008, 53(21): 3255-3266
[2] Huang M R, Rao X W, Li X G. Chin. J. Anal. Chem., 2008, 36(12): 1735-1741
[3] Ion I, Culetu A, Costa J, Luca C, Ion A C. Desalination, 2010, 259 (1/3): 38-43
[4] Szigeti Z, Malon A, Vigassy T, Csokai V, Grün A, Wygladacz K, Ye N, Xu C, Chebny V J, Bitter I, Rathore R, Bakker E, Pretsch E. Anal. Chim. Acta, 2006, 572(1): 1-10
[5] Bedlechowicz I, Maj-Zurawska M, Sokalski T, Hulanicki A. J. Electroanal. Chem., 2002, 537(1/2): 111-118
[6] 张军(Zhang J), 赵月前(Zhao Y Q), 丁家旺(Ding J W), 秦伟(Qing W). 分析测试学报(J. Instrumental Anal. ), 2011, 30(2): 207-212
[7] Mahajan R K, Sood P. Int. J. Electrochem. Sci., 2007, 2: 832-847
[8] Ceresa A, Sokalski T, Pretsch E. J. Electroanal. Chem., 2001, 501(1/2): 70-76
[9] Li X G, Ma X L, Huang M R. Talanta, 2009, 78(2): 498-505
[10] Mashhadizadeh M H. Taheri E P, Sheikhshoaie I. Talanta, 2007, 72 (3): 1088-1092
[11] 吕鉴泉(Lv J Q), 曾宪顺(Zeng X S), 艾娟(Ai J), 庞代文(Pang D W). 高等学校化学学报(Chem. J. Chin. Univ. ), 2005, 26(2): 238-240
[12] 薛富(Xue F), 李民君(Li M J), 季玉祥(Ji Y X), 张军(Zhang J). 化学试剂, 2011, 33(9): 837-840
[13] Wilson D, Arada M A, Alegret S, Valle M. J. Hazard. Mater., 2010, 181(1/3): 140-146
[14] Bochenska M, Guzinski M, Kulesza J. Electroanalysis, 2009, 21 (17/18): 2054-2060
[15] Long R, Bakker E. Anal. Chim. Acta, 2004, 511 (1): 91-95
[16] Arvand M, Asadollahzadeh S A. Talanta, 2008, 75(4): 1046-1054
[17] Zanjanchi M A, Arvand M, Islamnezhad A, Mahmoodi N O. Talanta, 2007, 74 (1): 125-131
[18] Ganjali M R, Hosseini M, Basiripour F, Javanbakht M, Hashemi O R, Rastegar M F, Shamsipur M, Buchanen G W. Anal. Chim. Acta, 2002, 464(2): 181-186
[19] Huang M R, Rao X W, Li X G, Ding Y B. Talanta, 2011, 85(3): 1575-1584
[20] Alizadeh N, Ershad S, Naeimi H, Sharghi H, Shamsipur M. Fresenius J. Anal. Chem., 1999, 365 (6): 511-515
[21] 李光华(Li G H), 丁国华(Ding G H). 化学通报(Chem. Bull. ), 2011, 74(9): 853-856
[22] Elmosallamy M A F, Fathy A M, Ghoneim A K. Electroanalysis, 2008, 20(11): 1241-1245
[23] Kazemia S Y, Shamsipur M, Sharghi H. J. Hazard. Mater., 2009, 172(1): 68-73
[24] Rizk N M H, Abbas S S, Hamza S M, EL-Karem Y M A. Sensors, 2009, 9(3): 1860-1875
[25] Mittal S K, Kumar A, Gupta N, Kaur S, Kumar S. Anal. Chim. Acta, 2007, 585(1): 161-170
[26] Bakker E, Pretsch E. Anal. Chim. Acta, 1995, 309(1/3): 7-17
[27] Zwickl T, Sokalski T, Pretsch E. Electroanalysis, 1999, 11 (10/11): 673-680
[28] Radu A, Peper S, Bakker E, Diamond D. Electroanalysis, 2007, 19(2/3): 144-154
[29] Telting-Diaz M, Bakker E. Anal. Chem., 2001, 73 (22): 5582-5589
[30] Sokalski T, Bedlechowicz I, Maj-Zurawska M, Hulanicki A. Fresenius J. Anal. Chem., 2001, 370 (4): 367-370
[31] 颜振宁(Yan Z N), 李利勤(Li L Q), 赵邦屯(Zhao B T). 分析化学(Chin. J. Anal. Chem. ), 2008, 36 (3): 339-342
[32] Bakker E, Buhlmann P, Pretsch E. Chem. Rev., 1997, 97 (8): 3083-3132
[33] Peper S, Qin Y, Almond P, McKee M, Telting-Diaz M, Albrecht-Schmitt T, Bakker E. Anal. Chem., 2003, 75 (9): 2131-2139
[34] Vigassy T, Gyurcsányi R E, Pretsch E. Electroanalysis, 2003, 15(5/6): 375-382
[35] Thurer R, Vigassy T, Hirayama M, Pretsch E. Chem. Anal., 2006, 51 (6): 869-878
[36] Michalska A, Ocypa M, Maksymiuk K. Electroanalysis, 2005, 17(4): 327-333
[37] Lindner E, Gyurcsányi R E, Buck R P. Electroanalysis, 1999, 11(10/11): 695-702
[38] Radu A, Telting-Diaz M, Bakker E. Anal. Chem., 2003, 75 (24): 6922-6931
[39] Vigassy T, Gyurcsányi R E, Pretsch E. Electroanalysis, 2003, 15 (15/16): 1270-1275
[40] Pergel E, Gyurcsányi R E, Tóth K, Lindner E. Anal. Chem., 2001, 73(17): 4249-4253
[41] Peshkova M A, Mikhel'son K N. Russ. J. Electrochem., 2010, 46 (11): 1331-1337
[42] Bedlechowicz I, Sokalski T, Lewenstam A, Maj-zurawska M. Sensors and Actuators B, 2005, 108 (1/2): 836-839
[43] Peshkova M A, Sokalski T, Mikhelson K N, Lewenstam A. Anal. Chem., 2008, 80 (23): 9181-9187
[44] Hofler L, Bedlechowicz I, Vigassy T, Gyurcsnyi R E, Bakker E, Pretsch E. Anal. Chem., 2009, 81 (9): 3592-3599
[45] Michalska A. Electroanalysis, 2005, 17(5/6): 400-407
[46] Pawowski P, Kisiel A, Michalska A, Maksymiuk K. Talanta, 2011, 84(3): 814-819
[47] Pawlowski P, Michalska A, Maksymiuk K. Electroanalysis, 2006, 18(13/14): 1339-1346
[48] Zook J M, Lindner E. Anal. Chem., 2009, 81 (13): 5146-5154
[49] Zook J M, Lindner E. Anal. Chem., 2009, 81 (13): 5155-5164
[50] Ding J W, Qin W. J. Am. Chem. Soc., 2009, 131 (41): 14640-14641
[51] Li X G, Feng H, Huang M R, Gu G L, Moloney M G. Anal. Chem., 2012, 84(1): 134-140
[52] Coldur F, Andac M, Isildak I, Saka T. J. Electroanal. Chem., 2009, 626(1/2): 30-35
[53] Huang M R, Gu G L, Shi F Y, Li X G. Chin. J. Anal. Chem., 2012, 40(1): 50-58
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