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• Review •

Metal-Organic Framework Materials and Their Applications in Catalysis

Li Qingyuan, Ji Shengfu, Hao Zhimou   

  1. State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029, China
  • Received: Revised: Online: Published:
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Metal-organic Framework (MOF) materials, which are synthesized by self-assembling of the metal ions and the organic ligands, are the special crystal materials with porous structure. Because of their diverse structures, tunable cavity and easy functionalization, MOFs have exhibited the attractive prospects in many fields, such as the gas adsorption and separation, the catalysts, the magnetism and the bio-medicine. In order to get comprehensive understanding of the MOFs’ catalytic properties, in this paper, the categories and common synthesis methods of MOF materials are introduced. The catalysis of the MOF materials, especially, the catalysis of the metal active sites and the active organic ligands in the frameworks of the MOF, and the catalytic active components supported in MOFs, are summarized and reviewed. The development trends of MOF materials in the catalytic applications are also prospected. Contents 1 Introduction
2 Categories and syntheses of MOFs materials
2.1 Categories of MOF materials
2.2 Syntheses of MOF materials
3 Applications of MOFs in catalysis
3.1 Catalytic reactions of MOFs with metal active sites
3.2 Catalytic reactions of MOFs with active organic ligands
3.3 Catalytic reactions of MOFs with loading active guests
4 Conclusion and outlook
Key words: metal-organic frameworks, categories, synthesis, catalysis, applications

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