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Progress in Chemistry 2012, Vol. 24 Issue (05): 823-833 Previous Articles   Next Articles

• Review •

Rhodamine-Based Fluorescent Probes for Cations

Li Junbo, Hu Qihui, Zeng Yang, Yu Xianglin, Pan Zhiquan   

  1. Key Laboratory for Green Chemical Process of Ministry of Education, Wuhan Institute of Technology, Wuhan 430073, China
  • Received: Revised: Online: Published:
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As one kind of the xanthenes, rhodamine dyes have excellent photophysical properties, such as long absorption and emission wavelengths elongated to visible region, high fluorescence quantum yield, and large absorption coefficient, etc. Therefore, rhodamine-based dyes have become one of the perfect chromophores for making fluorescent probes. In the paper, the recent progress in the studies on rhodamine-based fluorescent probes for metal cations are reviewed. Especially systematically discuss about the rhodamine-based fluorescent probes for copper ion, mercury ion and iron ion that are based on the mechanism of screw amide ring “off-on”, the mechanism of fluorescence resonance energy transfer and the mechanism of photoinduced electron transfer. The structure, detecting level and applications are discussed in detail. Moreover, the problems and developing trends with this kind of fluorescent probe have also been discussed.

Contents
1 Introduction
2 Selective probes for copper ion
3 Selective probes for mercury ion
3.1 Probe with sulfur atoms coordination
3.2 Probe without sulfur atoms coordination
3.3 Probe with mercury ion induced chemical reactions
4 Selective probes for iron ion
5 Selective probes for other metal ions
6 Conclusions and outlook

Key words: rhodamine, fluorescence, probes, metal cations

CLC Number: 

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