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Progress in Chemistry 2012, Vol. 24 Issue (05): 769-775 Previous Articles   Next Articles

• Review •

Coordination Polymers Constructed from Triazole and Carboxylate Mixed Ligands

Ren Hong1*, Zhang Ping2, Wu Ping1, Lu Fei1   

  1. 1. School of Chemistry and Pharmaceutical Engineering, Jilin Institute of Chemical Technology, Jilin 13202;
    2. Department of Chemistry, Jilin University, Changchun 130012, China
  • Received: Revised: Online: Published:
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The research of coordination polymers remain an extremely active field of material chemistry, coordination chemistry and crystal engineering in recent years due to their various network topologies and their potential applications in many aspects such as guest exchange/separation, gas storage, chiral resolution, selective catalysis, molecular recognition, fluorescence and magnetism. This paper summarizes the recent advancement on the structure of coordination polymer containing triazolate-carboxylate mixed ligands, which focuses chiefly on the role of carboxylate ligand in the crystal structure. The future research and development of coordination polymer constructed from triazole and carboxylate are also prospcted.

Contents
1 Introduction
2 The M/trz layer pillared by carboxylate ligand to construct the 3D structure
2.1 The pillared-layer structure in the M/trz/aromatic carboxylate system
2.2 The pillared-layer structure in the M/trz/aliphatic carboxylate system
3 The network built by carboxylate ligand and M/trz through coordinative covalent bonding
3.1 The typical topological structure constructed by carboxylate ligand and M/trz
3.2 The novel topological structure constructed by carboxylate ligand and M/trz
4 The network built by carboxylate ligand and M/trz through weak intermolecular interactions
5 The properties of coordination polymers constructed from triazolate and carboxylate mixed ligands
6 Conclusion and outlook

Key words: triazole, aliphatic carboxylate, aromatic carboxylate, crystal structure

CLC Number: 

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