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Progress in Chemistry 2012, Vol. 24 Issue (05): 747-756 Previous Articles   Next Articles

• Review •

Application of Metal-Organic Frameworks in Olefin Oxidation

Li Linqing1,2, Lv Ying1, Li Jun1, Dong Xiaoli2, Gao Shuang1*   

  1. 1. Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China;
    2. School of Chemical Engineering and Materials, Dalian Polytechnic University, Dalian 116034, China
  • Received: Revised: Online: Published:
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As a new class of porous solids, metal-organic frameworks (MOFs) have attracted a great deal of interests of chemists in the world due to their unique properties, such as the high specific surface area, tailoring structure properties and 100% utilization of exposed metal ions. The chemical and structural versatility of such materials makes them potentially candidates for applications in catalysis. In this review, we focus our attention on olefins oxidation using MOF as catalysts. Three classes of MOF catalysts are active site at the inorganic nodes on the MOF, active site at the organic or pseudo-organic linkers, and MOF-supported active specie. The applications of the three classes of MOF catalysts on the olefins oxidation are discussed in detail.

Contents
1 Introduction
2 Catalysis by metal nodes on the MOF
2.1 Catalysis by Fe-MOF
2.2 Catalysis by Cu-MOF
2.3 Catalysis by Ni-MOF
2.4 Catalysis by Ln-MOF
2.5 Catalysis by Co-MOF
2.6 Catalysis by V-MOF
3 Catalysis by homogeneous catalysts incorporated as MOF struts at the organic or pseudo-organic linkers
3.1 Metalloporphyrins
3.2 Salen complexes
4 Catalysis by MOF-supported metals or clusters
5 Conclusions and Outlook

Key words: metal-organic frameworks (MOFs), oxidation, olefin, epoxidation, catalysis

CLC Number: 

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