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Progress in Chemistry 2012, Vol. 24 Issue (05): 709-721 Previous Articles   Next Articles

• Review •

Spatiotemporal Dynamics of Photosensitive BZ Reaction

Lu Xingjie, Zhao Yuemin, Ren Lin, Yang Yingying, Gao Qingyu   

  1. College of Chemical Engineering, China University of Mining and Technology, Xuzhou 221008, China
  • Received: Revised: Online: Published:
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The Belousov-Zhabotinsky(BZ) reaction catalyzed by tris(2,2'-bipyridine)ruthenium(Ⅱ), one of the ideal chemical reaction system for studying nonlinear spatiotemporal dynamics, has unique photosensitive properties and can display rich spatiotemporal dynamical behaviors. Achievements of the photosensitive BZ reaction could help us to understand the complex dynamic phenomenon in physical, chemical and living systems. In this paper, the photo-effect on homogenous complex dynamics and reaction-diffusion chemical waves in ruthenium-catalyzed BZ reaction under different experiment conditions, as well as the complex dynamics in coupling system of the ruthenium-catalyzed BZ reaction with soft matter is reviewed. The photosensitive mechanisms and models are summarized. Finally, the existing questions and future directions of the research of photo-controlled BZ reaction systems are discussed.

Contents
1 Introduction
2 Complex spatiotemporal dynamic behavior of tris(2,2'-bipyridine)ruthenium(Ⅱ)-catalyzed BZ reaction
2.1 Homogenous oscillating reactions
2.2 Chemical waves in spatial reaction-diffusion systems
2.3 Ruthenium-catalyzed BZ reaction coupling with soft matter
3 Mechanism of photosensitive ruthenium-catalyzed BZ reaction
3.1 Mechanism of photoinhibition
3.2 Mechanism of photoinduction
4 Models
4.1 Models of photosensitive BZ reaction
4.2 gLSM model of photosensitive BZ reaction in responsive gel
5 Conclusions and outlook

Key words: Belousov-Zhabotinsky reaction, nonlinear dynamics, oscillations, chemical waves

CLC Number: 

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