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Progress in Chemistry 2012, Vol. 24 Issue (05): 659-673   Next Articles

• Review •

Surface/Interfacial Properties and Structures of Ionic Liquids

Yan Yan, Yang Qiwei, Xing Huabin, Su Baogen, Ren Qilong   

  1. Key Laboratory of Biomass Chemical Engineering of Ministry of Education, Department of Chemical and Biological Engineering, Zhejiang University, Hangzhou 310027, China
  • Received: Revised: Online: Published:
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Heterogeneous systems containing ionic liquids (ILs) with gases and solvents extend the acpplications of ILs in absorption, extraction and heterogeneous catalysis. In recent years, the surface/interfacial properties and surface/interfacial structures of ionic liquids have been widely studied, because they are important due to their remarkable effects on heterogeneous reactions and separation efficiency. In this article, the surface/interfacial tension,as well as the surface/interfacial structures of ILs and their mixtures with water and organic solvents are summarized. The research methods, objectives and results are introduced. The relationship between surface/interfacial tension and surface/interfacial structures is elucidated. Finally, the exiting problems and development prospects of the studies on surface/interfacial properties and surface/interfacial structures of ILs are discussed.

Contents
1 Introduction
2 Surface tension of ionic liquids and their mixtures
2.1 Surface tension of ionic liquids
2.2 Surface tension of ionic liquid mixtures
3 Liquid/liquid interfacial tension of ionic liquids
4 Surface/interfacial structures of ionic liquids
4.1 Direct recoil spectroscopy
4.2 Neutron and X-ray reflectivity
4.3 Ultra-high vacuum systems
4.4 Non-linear spectroscopy
4.5 Molecular dynamic simulation
5 Conclusion and outlook

Key words: ionic liquids, surface/interfacial properties, surface/interfacial structures, molecular dynamic simulation, non-linear spectroscopy

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