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Progress in Chemistry 2012, Vol. 24 Issue (04): 483-491 Previous Articles   Next Articles

• Review •

Ionic Liquids-Mediated Formation of 5-Hydroxymethylfurfural

Hu Lei, Sun Yong, Lin Lu   

  1. School of Energy Research, Xiamen University, Xiamen 361005, China
  • Received: Revised: Online: Published:
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5-Hydroxymethylfurfural (5-HMF) is considered as a very important biomass-based platform compound that can be used to synthesize a broad range of liquid fuels and chemicals, which are mainly derived from fossil resources so far. The study of the production of 5-HMF in the presence of ionic liquids has increasingly attracted more attention. In this review, the recent achievements of ionic liquids-mediated formation of 5-HMF are systematically summarized, including applications of ionic liquids as reaction solvents and catalysts in the production of 5-HMF, influence factors and formation mechanisms in the ionic liquids-mediated formation of 5-HMF. The future research trends of ionic liquids-mediated formation of 5-HMF are suggested.
Contents
1 Introduction
2 Production of 5-HMF using ionic liquids as reaction solvents
2.1 Fructose as feedstock
2.2 Glucose as feedstock
2.3 Sucrose as feedstock
2.4 Cellulose, starch and inulin as feedstock
3 Production of 5-HMF using ionic liquids as catalysts
3.1 Ionic liquids as base catalysts
3.2 Ionic liquids as acid catalysts
4 Mechanisms of ionic liquids-mediated formation of 5-HMF
5 Influence factors of ionic liquids-mediated formation of 5-HMF
5.1 Reaction temperature
5.2 Heating method
5.3 Reaction time
5.4 Catalyst loading
5.5 Substrate loading
5.6 Water content
5.7 Co-solvent
5.8 Extraction method
6 Conclusions and perspectives
Key words: 5-hydroxymethylfurfural, ionic liquids, biomass, reaction solvents, catalysts, formation mechanisms, influence factors

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