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Progress in Chemistry 2012, Vol. 24 Issue (04): 456-462 Previous Articles   Next Articles

• Review •

Anionic Wormlike Micelles

Zhao Jianxi, Xie Danhua   

  1. Institute of Colloid and Interface Chemistry, College of Chemistry and Molecular Engineering, Fuzhou University, Fuzhou 350108, China
  • Received: Revised: Online: Published:
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The molecular geometry and the driving factor of Gibbs free energy are acted as the preconditions for wormlike micelle construction. Bearing this in mind, the formation and properties of the wormlike micelles by conventional anionic surfactants are summarized. The reasons restricting the wormlike micelle formation and high viscoelasticity in conventional anionic surfactant systems are illustrated. The molecular structure advantage of Gemini surfactant in forming wormlike micelles is introduced. Recent advances in anionic wormlike micelle construction, especially for those formed by anionic Gemini surfactants with long and rigid spacer are described in detail. Finally, as a conclusion, it is specially pointed out that based on the superiority of novel molecular structures, Gemini surfactants could become main candidates in constructing wormlike micelles.
Contents
1 Introduction
2 Mechanism of wormlike micelle formation
3 Wormlike micelle systems formed by conventional anionic surfactants
4 Advantage of Gemini surfactant in forming wormlike micelles
5 Wormlike micelle systems constructed by anionic Gemini surfactants
6 Conclusions
Key words: anionic wormlike micelles, Gemini surfactant, columnar-like molecule, high viscoelasticity

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Abstract

Anionic Wormlike Micelles