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• Review •

Solid Heteropolyacids (HPAs) in Hydrolytic Conversion of Biomass

Zhang Jianming, Zhai Shangru*, Huang Dezhi, Zhai Bin, An Qingda*   

  1. Faculty of Light Industry and Chemical Engineering, Dalian Polytechnic University, Dalian 116034, China
  • Received: Revised: Online: Published:
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With global oil production flattening out, attention is being increasingly paid to a kind of renewable clean energy-biomass. Heteropolyacids are important catalysts in the so-called clean technologies. They possess strong acidity, structural flexibility and fairly high thermal stability. It would be preferable to carry out the heteropolyacids-catalyzed reaction in biomass hydrolytic conversion. The performance of heteropolyacids towards hydrolysis of biomass in pure water, organic solvents and biphasic systems exhibit different advantages and limitations. In this paper, we reviewed the latest progress in the hydrolytic conversion of biomass into valuable chemicals using heteropolyacids in different catalytic systems. Highly effective utilization of biomass has positive effects on solving energy problems and achieving sustainable development of energy and chemical industry.Heteropolyacids used as excellent green catalyst will possess extensive application prospect in biomass conversion. Contents
1 Introduction
2 Characteristics and Utilization of Biomass
3 Structure features and current situation of HPAs
3.1 Pure HPAs
3.2 Salts of HPAs
3.3 Supported HPAs
4 Applications of HPAs in hydrolytic conversion of biomass
4.1 Water solvent
4.2 Organic solvents
4.3 Biphasic system
5 Conclusion and outlook
Key words: heteropolyacids(HPAs), biomass, hydrolysis, catalytic system, solvent

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