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Molecular-Recognition and Thermo-Responsive Composite Smart Polymeric Materials

Xie Rui, Yang Mei, Cheng Changjing, Jiang Jing, Chu Liangyin*   

  1. School of Chemical Engineering, Sichuan University, Chengdu 610065, China
  • Received: Revised: Online: Published:
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Development of dual-stimuli-responsive and multi-stimuli-responsive smart polymeric materials becomes more and more important. The recent progresses in molecular-recognition and thermo-responsive composite smart linear polymers, smart microspheres and smart membranes based on poly(N-isopropylacrylamide) (PNIPAM) and β-cyclodextrin (β-CD) are reviewed in detail. The different kinds of smart materials are prepared by the same reaction mechanism, namely polymerization of N-isopropylacrylamide (NIPAM) with glycidyl methacrylate (GMA) into poly(N-isopropylacrylamide-co-glycidyl methacrylate) (PNG) polymer at first, followed by introduction of modified mono-6-deoxy-6-ethylenediamino-β-cyclodextrin (ECD) or mono-6-deoxy-6-hexanediamino-β-cyclodextrin (HCD) onto PNG polymer by virtue of reaction between primary amino groups and epoxy groups. The effects of preparation conditions, the molar ratio of NIPAM to GMA, grafting yields, the types and concentrations of guest molecules on the thermo-responsibility and molecular-recognition characteristics of different composite smart polymeric materials are discussed. Moreover, the applications of composite smart polymeric membranes in affinity separation, controlled release and chiral separation are also discussed. The significance and future of molecular-recognition and thermo-responsive composite polymeric materials are commented. Contents
1 Introduction
2 Molecular-recognition and thermo-responsive compo-site smart polymeric materials based on poly- (N-isopropylacrylamide) and β-cyclodextrin
2.1 Composite smart linear polymers
2.2 Composite smart microspheres
2.3 Composite smart membranes
3 Conclusions and Outlook
Key words: smart materials, poly(N-isopropylacrylamide), &beta, -cyclodextrin, linear polymers, microspheres, smart membranes

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[1] 陈莉(Chen L). 智能高分子材料(Intelligent Polymer Materials). 北京:化学工业出版社(Beijing: Chemical Industry Press), 2004. 5-9
[2] Liu L, Wang W, Ju X J, Xie R, Chu L Y. Soft Matt., 2010, 6(16): 3759-3763
[3] Wang J Y, Jin Y, Xie R, Liu J Y, Ju X J, Meng T, Chu L Y. J. Colloid Interf. Sci., 2011, 353(1): 61-68
[4] Liu L, Yang J P, Ju X J, Xie R, Liu Y M, Wang W, Zhang J J, Niu C H, Chu L Y. Soft Matt., 2011, 7(10): 4821-4827
[5] Wei J, Ju X J, Xie R, Mou C L, Lin X, Chu L Y. J. Colloid Interf. Sci., 2011, 357(1): 101-108
[6] Anastasiadis S H, Lygeraki M I, Athanassiou A, Farsari M, Pisignano D. J. Adhes. Sci. Technol., 2008, 22(15): 1853-1868
[7] Liu G Q, Zhao X P. J. Macromol. Sci. Pure Appl. Chem., 2006, A43(2): 345-354
[8] Yoon S G, Kim I Y, Kim S I, Kim S J. Polym. Inter., 2005, 54(8): 1169-1174
[9] 朱小丽(Zhu X L), 谢锐(Xie R), 杨眉(Yang M), 褚良银(Chu L Y). 化工进展(Chemical Industry and Engineering Process), 2008, 27(6): 917-921
[10] Zhang S B, Chu L Y, Xu D, Zhang J, Ju X J, Xie R. Polym. Adv. Technol., 2008, 19(8): 937-743
[11] 戴亚妮(Dai Y N), 李平(Li P), 王爱勤(Wang A Q). 化学进展(Progress in Chemistry), 2007, 19(2/3): 362-369
[12] Dimitrova I, Trzebickab B, Muller A H E, Dworakb A, Tsvetanov C B. Prog. Polym. Sci., 2007, 32(11): 1275-1343
[13] Wang W, Liu L, Ju X J, Zerrouki D, Xie R, Yang L, Chu L Y. ChemPhysChem, 2009, 10(14): 2405-2409
[14] Yang W C, Xie R, Pang X Q, Ju X J, Chu L Y. J. Membrane Sci., 2008, 321(2): 324-330
[15] Wu H G, Ju X J, Xie R, Liu Y M, Deng J G, Niu C H, Chu L Y. Polym. Adv. Technol., 2011, 22(9): 1389-1394
[16] Pi S W, Ju X J, Wu H G, Xie R, Chu L Y. J. Colloid Interf. Sci., 2010, 349(2): 512-518
[17] 陈永朝(Chen Y C), 谢锐(Xie R), 李鹏飞(Li P F), 巨晓洁(Ju X J), 褚良银(Chu L Y). 化工学报(J. Chem. Ind. Eng. (China)), 2010, 61(7): 1866-1872
[18] Zhang J, Xie R, Zhang S B, Cheng C J, Ju X J, Chu L Y. Polymer, 2009, 50(11): 2516-2525
[19] 汪伟(Wang W), 李鹏飞(Li P F), 谢锐(Xie R), 巨晓洁(Ju X J), 杨眉(Yang M), 褚良银(Chu L Y). 高分子材料科学与工程(Polym. Mater. Sci. Eng.), 2009, 25(12):145-148
[20] Ju X J, Liu L, Xie R, Niu C H, Chu L Y. Polymer, 2009, 50(3): 922-929
[21] 褚良银(Chu L Y), 谢锐(Xie R), 巨晓洁(Ju X J). 化工进展(Chemical Industry and Engineering Process), 2011, 30(1):167-171
[22] 童林荟(Tong L H). 环糊精化学:基础与应用(Cyclodextrin Chemistry: Infrastructure and Application). 北京:科学出版社 (Beijing: Science Press), 2001. 10-14
[23] 刘育(Liu Y), 尤长城(You C C), 张衡益(Zhang H Y). 超分子化学--合成受体的分子识别与组装(Supramolecular Chemistry: Molecular Recognition and Assembly of Synthetic Receptors). 天津: 南开大学出版社(Tianjin: Nankai University Press), 2001. 166-171
[24] Koopmans C, Ritter H. J. Am. Chem. Soc., 2007, 129(12), 3502-3503
[25] Wang H D, Chu L Y, Yu X Q, Xie R, Yang M, Xu D, Zhang J, Hu L. Ind. Eng. Chem. Res., 2007, 46, 1511-1518
[26] Liu Y Y, Fan X D. Polymer, 2002, 43(18): 4997-5003
[27] Liu Y Y, Fan X D, Hu H, Tang Z H. Macromol. Biosci., 2004, 4(8): 729-736
[28] Zhang J T, Xue Y N, Gao F Z, Huang S W, Zhuo R X. J. Appl. Polym. Sci., 2008, 108(5): 3031-3037
[29] Yang M, Chu L Y, Xie R, Wang C. Macromol. Chem. Phys., 2008, 209(2): 204-211
[30] Liu Y Y, Fan X D, Gao L. Macromol. Biosci., 2003, 3(12): 715-719
[31] Liu Y Y, Fan X D, Zhao Y B. J. Polym. Sci. Part A: Polym. Chem., 2005, 43(16): 3516-3524
[32] 马光辉(Ma G H), 苏志国(Su Z G). 高分子微球材料(Polymer Microspheres Materials). 北京: 化学工业出版社(Beijing: Chemical Industry Press), 2005
[33] Liu Y Y, Yu Y, Wei T, Sun L, Fan X D. Macromol. Biosci., 2009, 9(5): 525-534
[34] 姜晶(Jiang J), 谢锐(Xie R), 巨晓洁(Ju X J), 程昌敬(Cheng C J), 褚良银(Chu L Y). 化工进展(Chemical Industry and Engineering Process), 2009, 28(10):1771-1776
[35] 程昌敬(Cheng C J). 四川大学博士学位论文(Doctoral Dissertation of Sichuan University), 2005
[36] 陈利(Chen L), 褚良银(Chu L Y). 过滤与分离(Journal of Filtration & Separation), 2007, 17(3): 1-3, 48
[37] 谢锐(Xie R), 褚良银(Chu L Y). 膜科学与技术(Membrane Science and Technology), 2007, 27(4): 1-7
[38] Xie R, Zhang S B, Wang H D, Yang M, Li P F, Zhu X L, Chu L Y. J. Membrane Sci., 2009, 326(2): 618-626
[39] Yanagioka M, Kurita H, Yamaguchi T, Nakao S. Ind. Eng. Chem. Res., 2003, 42(2): 380-385
[40] Yang M, Xie R, Wang J Y, Ju X J, Yang L, Chu L Y. J. Membrane Sci., 2010, 355(1/2): 142-150
[41] Yang M, Chu L Y, Wang H D, Xie R, Song H, Niu C H. Adv. Funct. Mater., 2008, 18(4): 652-663
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