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Progress in Chemistry 2012, Vol. 24 Issue (01): 70-79 Previous Articles   Next Articles

• Review •

A Photo-Switched Supramolecular System Based on Cyclodextrins and Azo Compounds

Sun Tao, Li Yueming, Xin Feifei, Li Shangyang, Hou Yuehui, Hao Aiyou*   

  1. School of Chemistry and Chemical Engineering, Shandong University, Jinan 250100, China
  • Received: Revised: Online: Published:
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Supramolecular chemistry is a hot research topic in current chemistry. The photo-switched supramolecular system based on cyclodextrins and azo compounds is a new area which has been developed in supramolecular chemistry recently. Their complexation with good optical properties attracted great interest in the fields of chemical self-assembly, catalysis, molecular machine design and smart materials. Here, the development of photo-switched supramolecular system based on cyclodextrins and azo compounds is reviewed. Firstly, the background and principle of the system are introduced. Then, the different aggregates controlled by the supramolecular system, including vesicles, gels, rotaxanes, catalytic systems and molecule hands, are emphatically described. At last, combined with current development of the system, the prospects are pointed out.

Contents
1 Introduction
2 A photo-switched supramolecular system based on cyclodextrin and azo compounds
2.1 Vesicle systems controlled by photo-switched supramolecular system
2.2 Gel systems controlled by photo-switched supramolecular system
2.3 Rotaxane systems controlled by photo-switched supramolecular system
2.4 Catalytic systems controlled by photo-switched supramolecular system
2.5 Molecular hand systems controlled by photo-switched supramolecular system
3 Prospects

Key words: photo-switched supramolecular system, photo-response, cyclodextrin, azo compounds, reversible inclusion

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