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Progress in Chemistry 2012, Vol. 24 Issue (01): 47-53 Previous Articles   Next Articles

Special Issue: 锂离子电池

• Review •

Preparation of Li3V2(PO4)3 Cathode Material for Power Li-Ion Batteries

Li Yuejiao1,2, Hong Liang1, Wu Feng1,2*   

  1. 1. Beijing Key Laboratory of Environmental Science and Engineering, School of Chemical Engineering and the Environment, Beijing Institute of Technology, Beijing 100081, China;
    2. National Development Center of High Technology Green Materials, Beijing 100081, China
  • Received: Revised: Online: Published:
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A considerable amount of effort has been invested to find new cathode materials suitable for rechargeable lithium batteries, and lithium transition metal phosphates have attracted wide attention because of their high structural stability, reliability and abundant resources. Lithium vanadium phosphate (LVP) has high energy density of 500mWh/g, high electron and ionic conductivity, high theoretical charge and discharge capacity, and high charge and discharge voltage plateau. It is considered as one of the most promising cathode materials for power lithium batteries. Lithium vanadium phosphate has been prepared by some traditional synthetic methods such as solid-state reaction route, carbon thermal reduction, sol-gel method and hydrothermal synthetic method, while in recent years several new synthetic methods, such as wet coordination method, microwave solid-state synthetic method, rheological phase method, have drawn researchers’ attention. In this paper, the structure and the characters of lithium vanadium phosphate are introduced. The recent research progress on synthesis study of lithium vanadium phosphate is systematically reviewed, and the results of our research team focused on the exploration of new preparation technology for lithium vanadium phosphate in recent years are elaborated. Furthermore, the preparing techniques and the material properties for each method are compared, and the current problems as well as the corresponding research directions are discussed.

Contents
1 Introduction
2 Struture and charge/discharge principle of LVP
3 Traditional synthetic method
3.1 Solid-state reaction route
3.2 Carbon thermal reduction
3.3 Sol-gel method
3.4 Hydrothermal synthesis method
4 New synthetic method
4.1 Wet coordination method
4.2 Microwave solid-state synthetic method
4.3 Rheological phase method
4.4 Other synthetic methods
5 Conclusion

Key words: power Li-ion batteries, cathode materials, lithium vanadium phosphate, synthetic method

CLC Number: 

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