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Progress in Chemistry 2012, Vol. 24 Issue (01): 31-38 Previous Articles   Next Articles

• Review •

Preparation of Silica/Polymer Core-Shell Hybrid Particles and Their Hollow Structures

Huang Ping, Chai Shigan, Yuan Jianjun, Lu Guohong, Yang Tingting*, Cheng Shiyuan*   

  1. Faculty of Materials Science and Engineering, Hubei University, Wuhan 430062, China
  • Received: Revised: Online: Published:
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Core-shell silica/polymer hybrid micro- or nanoparticles and their corresponding hollow structures with unique morphology are of great interest because of their potential applications in drug delivery, catalysis carrier and nano-medicine. Their novel preparation procedures are still actively being studied. In this paper the recent progresses of their preparation in terms of emulsion polymerization and in situ biomimetic mineralization have been reviewed. Emulsion polymerization is a facile approach to design the complex structures of the core-shell SiO2/polymer particles, but requires to pre-prepare silica nanoparticles under environmentally unfriendly conditions, such as Stber method. Furthermore, the pre-prepared SiO2 nanoparticles can not completely match with polymer, thus some pure polymer particles are always obtained. In contrast, in situ biomimetic mineralization occurs in water under ambient conditions, producing exquisite hierarchical structures and multiple morphologies with precise nanoscale. It is still a big challenge for materials scientists to achieve the SiO2/polymer hybrid particles with excellent performance like the natural biological silicon.

Contents
1 Introduction
2 Emulsion polymerization
3 Biomimetic mineralization
4 Outlook

Key words: core-shell, hollow structure, SiO2 hybrid micro- or nanoparticles, emulsion polymerization, biomimetic mineralization

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