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Progress in Chemistry 2012, Vol. 24 Issue (01): 163-172 Previous Articles   Next Articles

• Review •

Dense Dual-Phase Oxygen Permeation Membranes

Chen Ting1, Zhao Hailei1,2*, Xie Zhixiang1, Xu Jingcan1, Xu Nansheng1, Li Fushen1,2   

  1. 1. School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing 100083, China;
    2. Beijing Key Laboratory of New Energy Materials and Technology, Beijing 100083, China
  • Received: Revised: Online: Published:
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Mixed conducting membranes that exhibit oxygen ion conduction at elevated temperature are of significant interest due to their potential applications for oxygen production, partial oxidation of methane to syngas (POM), and oxygen-enriched combustion. Well-investigated single-phase conductors show some disadvantages, such as poor long-term stability and low mechanical strength, limiting their practical applications. The dual phase membrane made from ionic and electronic conducting phases could improve the performance of long-term stability and chemical stability at elevated temperature and high oxygen partial pressure gradient. In this paper, the oxygen permeation mechanism and the research progress in dual-phase membranes are reviewed, including ion-conducting phase/noble metal, ion-conducting phase/electron-conducting oxides, and ion-conducting phase/mixed conducting phase. The emphasis is focused on the effect of composition, lattice structure, and the chemical compatibility and mixing ratio of the two phases on the oxygen permeability and operation stability of the dual phase membrane. Their applications in POM and oxygen-enriched combustion are introduced. The present problems concerned with dual phase membrane are concluded and the main future research directions are proposed.

Contents
1 Introduction
2 Biocathode types
2.1 Aerobic biocathodes
2.2 Anaerobic biocathodes
3 Biofilm
4 Electrode materials
5 Separation
6 Biocathode applications
6.1 Dye decolouration
6.2 Biohydrogen production
6.3 Heavy metal removal
6.4 Denitrification of wastewater
6.5 Dechlorination of wastewater
7 Outlook

Key words: mixed conductor, ion-conducting phase, electron-conducting phase, ceramic membrane, oxygen separation

CLC Number: 

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[1] Shao Zongping,Xiong Guoxing*. Mixed Conducting Oxygen Permeative Membranes and Their Applications in Partial Oxidation of Methane to Syngas Process [J]. Progress in Chemistry, 1999, 11(01): 30-.