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Progress in Chemistry 2012, Vol. 24 Issue (01): 144-156 Previous Articles   Next Articles

• Review •

Cobalt Catalyzed Peroxymonosulfate Oxidation: A Review of Mechanisms and Applications on Degradating Organic Pollutants in Water

Han Qiang1,2, Yang Shiying1,2,3*, Yang Xin1,2, Shao Xueting1,2, Niu Rui1,2, Wang Leilei1,2   

  1. 1. Key Laboratory of Marine Environment and Ecology, Ministry of Education, Qingdao 266100, China;
    2. College of Environmental Science and Engineering, Ocean University of China, Qingdao 266100, China;
    3. Department of Civil and Structural Engineering, The Hong Kong Polytechnic University, Kowloon, Hong Kong, China
  • Received: Revised: Online: Published:
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Cobalt/peroxymonosulfate (Co/PMS) system is a recently emerging advanced oxidation technology, established on the idea of transition metal-mediated decomposition of peroxide to overcome the limitations of the Fentons reagent. It is gaining prominence, owing to some excellent properties such as high decontamination efficiency with low concentration of cobalt (μg/L levels), ability to produce sulfate radical (SO4-·) and wide pH range (2—9) flexibility. They could easily degrade the complex organic contaminants into small molecules or even deeply mineralize them into CO2 and H2O, besides almost does not produce any sludge after the reaction under mild temperature and pressure conditions. All of these make it a promising alternative in pollution remediation. The paper reviews the research progress of Co/PMS system in degrading organic pollutants from two aspects, homogeneous and heterogeneous, basing on expounding the mechanisms such as SO4-· chain reaction mechanism, pH influence, anion effect, photo-promotion mechanism, atmosphere effect and heterogeneous mechanism. The prospects of Co/PMS technology are also discussed.

Contents
1 Introduction
2 Reaction mechanisms in degrading organic contaminants by Co/PMS
2.1 SO4-· chain reaction mechanism
2.2 pH effect
2.3 Anion participant
2.4 Photo-promotion
2.5 Atmosphere effect
2.6 Heterogeneous Co/PMS mechanism
3 Homogeneous Co/PMS system
3.1 Co/PMS(dark condition)
3.2 UV/Co/PMS
3.3 Vis/Co/PMS
4 Heterogeneous Co/PMS system
4.1 Cobalt oxide catalysts
4.2 Supported heterogeneous Co/PMS
5 Conclusions and outlook

Key words: peroxymonosulfate oxidation, cobalt-based catalysis, free radicals, degradation of organic contaminants, advanced oxidation technology

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