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Progress in Chemistry 2012, Vol. 24 Issue (01): 1-7   Next Articles

Interfacial Supramolecular Chemistry for Stimuli-Responsive Functional Surfaces

Wan Pengbo1, Hill Eric H.2, Zhang Xi1   

  1. 1. Key Lab of Organic Optoelectronics and Molecular Engineering of Ministry of Education, Department of Chemistry, Tsinghua University, Beijing 100084, China;
    2. Department of Chemical and Nuclear Engineering, Center for Biomedical Engineering, University of New Mexico, Albuquerque, New Mexico 87131-1341, United States
  • Received: Online: Published:
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The combination of supramolecular chemistry with interfaces enhances the development of supramolecular chemistry as well as colloid and interface science. Supramolecular chemistry at interfaces allows for the construction of various smart and soft surfaces that can adapt to environmental changes, such as biomimetic surfaces and self-cleaning surfaces. In this article, we discuss strategies for the transfer of supramolecular complexes of azobenzene and cyclodextrin from solution to surfaces for the fabrication of stimuli-responsive surfaces with novel interfacial functions including tunable surface wettability, reversible protein adsorption and resistance, and photo-switchable bioelectrocatalysis. It is anticipated that these concepts can be extended to other supramolecular systems in order to engineer functional surfaces with designed structures and functions. Contents
1 Introduction
2 Photocontrolled interfacial molecular shuttle for tunable surface wettabiloty
3 Dual-controlled reactivated biointerface for reversible protein immobilization
4 Nearly complete and reversible interfacial resistance of cytochrome c
5 Host-guest chemistry ar interfaces for photoswitchable bioelectrocatalysis
6 Conclusions
Key words: inter facial supramolecula r assembly, stimuli-responsive biosurface, host-guest interaction, protein immobilization and release, bioelectrocatalysis
[1] Zhang X, Whitten D G. Langmuir, 2011, 27: 1245-1245

[2] Jiang Y G, Wan P B, Smet M, Wang Z Q, Zhang X. Adv. Mater., 2008, 20: 1972-1977

[3] Jiang Y G, Wang Z Q, Yu X, Shi F, Xu H P, Zhang X, Smet M, Dehaen W. Langmuir, 2005, 21: 1986-1990

[4] Shi F, Niu J, Liu J L, Liu F, Wang Z Q, Feng X Q, Zhang X. Adv. Mater., 2007, 19: 2257-2261

[5] Yu X, Wang Z Q, Jiang Y Q, Shi F, Zhang X. Adv. Mater., 2005, 17: 1289-1293

[6] Zhang X, Shi F, Niu J, Jiang Y Q, Wang Z Q. J. Mater. Chem., 2008, 18: 621-633

[7] Blodgett K B, Langmuir I. Phys. Rev., 1937, 51: 964-982

[8] Decher G. Science, 1997, 277:1232-1237

[9] Nuzzo R G, Fusco F A, Allara D L. J. Am. Chem. Soc., 1987, 109: 2358-2368

[10] Wang Y P, Xu H P, Zhang X. Adv. Mater., 2009, 21: 2849-2864

[11] Liao X J, Chen G S, Liu X X, Chen W X, Chen F E, Jiang M. Angew. Chem. Int. Ed., 2010, 49: 4409-4413

[12] Liu Y, Chen Y. Acc. Chem. Res., 2006, 39： 681-691

[13] Zhang X, Wang C. Chem. Soc. Rev., 2011, 40: 94-101

[14] Wang Y P, Zhang M, Moers C, Chen S L, Xu H P, Wang Z Q, Zhang X, Li Z B. Polymer, 2009, 50: 4821-4828

[15] Wang C, Wang Z Q, Zhang X. Small, 2011, 7: 1379-1383

[16] Klajn R, Stoddart J F, Grzybowski B A. Chem. Soc. Rev., 2010, 39: 2203-2237

[17] Wang Y P, Ma N, Wang Z Q, Zhang X. Angew. Chem. Int. Ed., 2007, 46: 2823-2826

[18] Wan P B. Doctoral Dissertation of Tsinghua University, 2011

[19] Wan P B, Jiang Y G, Wang Y P, Wang Z Q, Zhang X. Chem. Commun., 2008, 5710-5712

[20] Wan P B, Wang Y P, Jiang Y G, Xu H P, Zhang X. Adv. Mater., 2009, 21: 4362-4365

[21] Wan P B, Chen Y Y, Xing Y B, Chi L F, Zhang X. Langmuir, 2010, 26: 12515-12517

[22] Wan P B, Xing Y B, Chen Y Y, Chi L F, Zhang X. Chem. Commun., 2011, 47: 5994-5996

[23] Tian H, Wang Q C. Chem. Soc. Rev., 2006, 35: 361-374

[24] Coronado E, Gavina P, Tatay S. Chem. Soc. Rev., 2009, 38: 1674-1689

[25] Willner I, PardoYissar V. J. Electroanal. Chem., 2001, 497: 172-177

[26] Wenz G, Han B H, Müller A. Chem. Rev., 2006, 106: 782-817

[27] Kawaguchi Y, Harada A. J. Am. Chem. Soc., 2000, 122: 3797-3798

[28] Mahan E J, Dennis J A. Org. Lett., 2006, 8: 5085-5088

[29] Jiao H, Goh S H, Valiyaveettil S. Macromolecules, 2003, 36: 4241-4243

[30] Mendes P M. Chem. Soc. Rev., 2008, 37: 2512-2529

[31] Xu J S, Bowden E F. J. Am. Chem. Soc., 2006, 128: 6813-6822

[32] Zhou J H, Lu X B, Hu J Q, Li J H. Chem. Eur. J., 2007, 13: 2847-2853

[33] Jiang S Y, Cao Z Q. Adv. Mater., 2010, 22: 920-932

[34] Ma H W, Wells M, Beebe T P, Chilkoti A. Adv. Funct. Mater., 2006, 16: 640-648

[35] Mohammed J S, Murphy W L. Adv. Mater., 2009, 21: 2361-2374

[36] Shipway A N, Willner I. Acc. Chem. Res., 2001, 34: 421-432

[37] Niazov T, Shlyahovsky B, Willner I. J. Am. Chem. Soc., 2007, 129: 6374-6375
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