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Progress in Chemistry 2012, Vol. Issue (9): 1751-1764 Previous Articles   Next Articles

• Review •

Synthesis of Functional Polymers via Combination of Thiol-Based Click Reactions with RAFT Polymerization

Xiong Xingquan, Tang Zhongke, Cai Lei   

  1. The Key Laboratory for Functional Materials of Fujian Higher Education, College of Materials Science & Engineering, Huaqiao University, Xiamen 361021, China
  • Received: Revised: Online: Published:
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Due to wide range of monomers, mild polymerization conditions and various established polymerization methods, reversible-addition-fragmentation chain transfer (RAFT) polymerization is a useful living polymerization technique for the design and synthesis of polymers. Click chemistry has been demonstrated as a powerful tool in numerous scientific fields including drugs, polymers and functional materials because of its superior selectivity, modularity and functional group tolerance. At the same time, a series of novel thiol-based click reactions thus emerged. Herein, recent tactics that combine thiol-based click reactions, such as thiol-ene, thiol-yne, thiol-icocyanate, thiol-oxirane and thiol-halo with RAFT technique toward the construction and modification of useful functional polymers are reviewed. The combined thiol-based click reaction/RAFT technique is believed to play a positive role in the design and synthesis of functional polymers. Contents 1 Introduction
2 Combination of thiol-based click reactions with RAFT polymerization
2.1 Thiol-ene click chemistry and RAFT polymerization
2.2 Thiol-yne chemistry and RAFT polymerization
2.3 Thiol-icocyanate chemistry and RAFT polymerization
2.4 Thiol-oxirane chemistry and RAFT polymerization
2.5 Thiol-halo chemistry and RAFT polymerization
3 Combination of thiol-disulfide exchange reaction with RAFT polymerization
4 Conclusions and outlook
Key words: thiol group, click chemistry, RAFT polymerization, functional polymers, modification

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